NH4+

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

NH4+ + Hydrogen cyanide = (NH4+ • Hydrogen cyanide)

By formula: H4N+ + CHN = (H4N+ • CHN)

Quantity Value Units Method Reference Comment
ΔrH°91.6kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase
ΔrH°85.8kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
ΔrS°97.9J/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase
ΔrS°84.5J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

(NH4+ • Hydrogen cyanide) + Hydrogen cyanide = (NH4+ • 2Hydrogen cyanide)

By formula: (H4N+ • CHN) + CHN = (H4N+ • 2CHN)

Quantity Value Units Method Reference Comment
ΔrH°72.8kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°97.9J/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase

(NH4+ • 2Hydrogen cyanide) + Hydrogen cyanide = (NH4+ • 3Hydrogen cyanide)

By formula: (H4N+ • 2CHN) + CHN = (H4N+ • 3CHN)

Quantity Value Units Method Reference Comment
ΔrH°57.3kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°90.0J/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase

(NH4+ • 3Hydrogen cyanide) + Hydrogen cyanide = (NH4+ • 4Hydrogen cyanide)

By formula: (H4N+ • 3CHN) + CHN = (H4N+ • 4CHN)

Quantity Value Units Method Reference Comment
ΔrH°46.0kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°87.4J/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase

(NH4+ • 4Hydrogen cyanide) + Hydrogen cyanide = (NH4+ • 5Hydrogen cyanide)

By formula: (H4N+ • 4CHN) + CHN = (H4N+ • 5CHN)

Quantity Value Units Method Reference Comment
ΔrH°33.kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°79.1J/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase

(NH4+ • 5Hydrogen cyanide) + Hydrogen cyanide = (NH4+ • 6Hydrogen cyanide)

By formula: (H4N+ • 5CHN) + CHN = (H4N+ • 6CHN)

Quantity Value Units Method Reference Comment
ΔrH°31.kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°83.3J/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase

(NH4+ • Hydrogen cyanide) + Ammonia = (NH4+ • Ammonia • Hydrogen cyanide)

By formula: (H4N+ • CHN) + H3N = (H4N+ • H3N • CHN)

Quantity Value Units Method Reference Comment
ΔrH°78.7kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
39.429.PHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated

(NH4+ • Hydrogen cyanide • Ammonia) + Hydrogen cyanide = (NH4+ • 2Hydrogen cyanide • Ammonia)

By formula: (H4N+ • CHN • H3N) + CHN = (H4N+ • 2CHN • H3N)

Quantity Value Units Method Reference Comment
ΔrH°51.0kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°81.2J/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase

(NH4+ • Hydrogen cyanide • 2Ammonia) + Hydrogen cyanide = (NH4+ • 2Hydrogen cyanide • 2Ammonia)

By formula: (H4N+ • CHN • 2H3N) + CHN = (H4N+ • 2CHN • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°46.9kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.315.PHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated

(NH4+ • 2Hydrogen cyanide • Ammonia) + Hydrogen cyanide = (NH4+ • 3Hydrogen cyanide • Ammonia)

By formula: (H4N+ • 2CHN • H3N) + CHN = (H4N+ • 3CHN • H3N)

Quantity Value Units Method Reference Comment
ΔrH°53.6kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°101.J/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase

(NH4+ • 3Hydrogen cyanide • Ammonia) + Hydrogen cyanide = (NH4+ • 4Hydrogen cyanide • Ammonia)

By formula: (H4N+ • 3CHN • H3N) + CHN = (H4N+ • 4CHN • H3N)

Quantity Value Units Method Reference Comment
ΔrH°36.kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated, T = 392 in paper is error
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated, T = 392 in paper is error

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
11.292.PHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated, T = 392 in paper is error

NH4+ + Methane = (NH4+ • Methane)

By formula: H4N+ + CH4 = (H4N+ • CH4)

Quantity Value Units Method Reference Comment
ΔrH°15.kJ/molHPMSBennet and Field, 1972gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
ΔrS°64.9J/mol*KHPMSBennet and Field, 1972gas phase; Entropy change is questionable

NH4+ + Carbon dioxide = (NH4+ • Carbon dioxide)

By formula: H4N+ + CO2 = (H4N+ • CO2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
9.6296.FASpears and Fehsenfeld, 1972gas phase

NH4+ + Acetonitrile = (NH4+ • Acetonitrile)

By formula: H4N+ + C2H3N = (H4N+ • C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°115.kJ/molPHPMSLiebman, Romm, et al., 1991gas phase
Quantity Value Units Method Reference Comment
ΔrS°101.J/mol*KPHPMSLiebman, Romm, et al., 1991gas phase

(NH4+ • Acetonitrile) + Acetonitrile = (NH4+ • 2Acetonitrile)

By formula: (H4N+ • C2H3N) + C2H3N = (H4N+ • 2C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°88.7kJ/molPHPMSLiebman, Romm, et al., 1991gas phase
Quantity Value Units Method Reference Comment
ΔrS°106.J/mol*KPHPMSLiebman, Romm, et al., 1991gas phase

(NH4+ • 2Acetonitrile) + Acetonitrile = (NH4+ • 3Acetonitrile)

By formula: (H4N+ • 2C2H3N) + C2H3N = (H4N+ • 3C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°59.4kJ/molPHPMSLiebman, Romm, et al., 1991gas phase
Quantity Value Units Method Reference Comment
ΔrS°81.6J/mol*KPHPMSLiebman, Romm, et al., 1991gas phase

(NH4+ • 3Acetonitrile) + Acetonitrile = (NH4+ • 4Acetonitrile)

By formula: (H4N+ • 3C2H3N) + C2H3N = (H4N+ • 4C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°49.0kJ/molPHPMSLiebman, Romm, et al., 1991gas phase
Quantity Value Units Method Reference Comment
ΔrS°92.9J/mol*KPHPMSLiebman, Romm, et al., 1991gas phase

NH4+ + Ethylene = (NH4+ • Ethylene)

By formula: H4N+ + C2H4 = (H4N+ • C2H4)

Quantity Value Units Method Reference Comment
ΔrH°42.kJ/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/ADeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.294.PHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated

NH4+ + Cyanogen = (NH4+ • Cyanogen)

By formula: H4N+ + C2N2 = (H4N+ • C2N2)

Quantity Value Units Method Reference Comment
ΔrH°43.5kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, DG<, ΔrH<
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/ASpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, DG<, ΔrH<

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.315.PHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, DG<, ΔrH<

NH4+ + Propiolonitrile = (NH4+ • Propiolonitrile)

By formula: H4N+ + C3HN = (H4N+ • C3HN)

Quantity Value Units Method Reference Comment
ΔrH°95.8kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
ΔrS°94.6J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

NH4+ + Acetone = (NH4+ • Acetone)

By formula: H4N+ + C3H6O = (H4N+ • C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°118.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase

(NH4+ • Acetone) + Acetone = (NH4+ • 2Acetone)

By formula: (H4N+ • C3H6O) + C3H6O = (H4N+ • 2C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°84.9kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase
Quantity Value Units Method Reference Comment
ΔrS°104.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase

(NH4+ • 2Acetone) + Acetone = (NH4+ • 3Acetone)

By formula: (H4N+ • 2C3H6O) + C3H6O = (H4N+ • 3C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°66.1kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase
Quantity Value Units Method Reference Comment
ΔrS°109.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase

(NH4+ • 3Acetone) + Acetone = (NH4+ • 4Acetone)

By formula: (H4N+ • 3C3H6O) + C3H6O = (H4N+ • 4C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°54.8kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase
Quantity Value Units Method Reference Comment
ΔrS°102.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase

(NH4+ • 4Acetone) + Acetone = (NH4+ • 5Acetone)

By formula: (H4N+ • 4C3H6O) + C3H6O = (H4N+ • 5C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°42.3kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KN/AMeot-Ner (Mautner), Sieck, et al., 1996gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.215.PHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; Entropy change calculated or estimated

NH4+ + Methylal = (NH4+ • Methylal)

By formula: H4N+ + C3H8O2 = (H4N+ • C3H8O2)

Quantity Value Units Method Reference Comment
ΔrH°122.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase
Quantity Value Units Method Reference Comment
ΔrS°105.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase

NH4+ + Butanenitrile = (NH4+ • Butanenitrile)

By formula: H4N+ + C4H7N = (H4N+ • C4H7N)

Quantity Value Units Method Reference Comment
ΔrH°119.kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
ΔrS°90.4J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

NH4+ + 1-Propene, 2-methyl- = (NH4+ • 1-Propene, 2-methyl-)

By formula: H4N+ + C4H8 = (H4N+ • C4H8)

Quantity Value Units Method Reference Comment
ΔrH°146.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation
ΔrH°146.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1990gas phase; forms t-C4H9NH3+
Quantity Value Units Method Reference Comment
ΔrS°155.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation
ΔrS°164.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1990gas phase; forms t-C4H9NH3+

NH4+ + Ethane, 1,2-dimethoxy- = (NH4+ • Ethane, 1,2-dimethoxy-)

By formula: H4N+ + C4H10O2 = (H4N+ • C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°160. ± 10.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; possible ether decomposition
Quantity Value Units Method Reference Comment
ΔrS°150.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; possible ether decomposition

(NH4+ • Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (NH4+ • 2Ethane, 1,2-dimethoxy-)

By formula: (H4N+ • C4H10O2) + C4H10O2 = (H4N+ • 2C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°97.1kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase
Quantity Value Units Method Reference Comment
ΔrS°140.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase

(NH4+ • 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (NH4+ • 3Ethane, 1,2-dimethoxy-)

By formula: (H4N+ • 2C4H10O2) + C4H10O2 = (H4N+ • 3C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°60. ± 10.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase
Quantity Value Units Method Reference Comment
ΔrS°114.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase

(NH4+ • Ethane, 1,2-dimethoxy-) + Ammonia = (NH4+ • Ammonia • Ethane, 1,2-dimethoxy-)

By formula: (H4N+ • C4H10O2) + H3N = (H4N+ • H3N • C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°58.6kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase
Quantity Value Units Method Reference Comment
ΔrS°81.2J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase

NH4+ + Benzene, 1,4-difluoro- = (NH4+ • Benzene, 1,4-difluoro-)

By formula: H4N+ + C6H4F2 = (H4N+ • C6H4F2)

Quantity Value Units Method Reference Comment
ΔrH°54.kJ/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/ADeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.395.PHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated

NH4+ + Benzene, fluoro- = (NH4+ • Benzene, fluoro-)

By formula: H4N+ + C6H5F = (H4N+ • C6H5F)

Quantity Value Units Method Reference Comment
ΔrH°60.2kJ/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
ΔrS°75.3J/mol*KPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase

NH4+ + Benzene = (NH4+ • Benzene)

By formula: H4N+ + C6H6 = (H4N+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°80.8kJ/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
ΔrS°97.5J/mol*KPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase

(NH4+ • Benzene) + Benzene = (NH4+ • 2Benzene)

By formula: (H4N+ • C6H6) + C6H6 = (H4N+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°71.1kJ/molPHPMSLiebman, Romm, et al., 1991gas phase
Quantity Value Units Method Reference Comment
ΔrS°128.J/mol*KPHPMSLiebman, Romm, et al., 1991gas phase

(NH4+ • 2Benzene) + Benzene = (NH4+ • 3Benzene)

By formula: (H4N+ • 2C6H6) + C6H6 = (H4N+ • 3C6H6)

Quantity Value Units Method Reference Comment
ΔrH°59.4kJ/molPHPMSLiebman, Romm, et al., 1991gas phase
Quantity Value Units Method Reference Comment
ΔrS°138.J/mol*KPHPMSLiebman, Romm, et al., 1991gas phase

NH4+ + Cyclohexane = (NH4+ • Cyclohexane)

By formula: H4N+ + C6H12 = (H4N+ • C6H12)

Quantity Value Units Method Reference Comment
ΔrH°40.kJ/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, DG<, ΔrH<
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/ADeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, DG<, ΔrH<

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
12.317.PHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, DG<, ΔrH<

NH4+ + Mesitylene = (NH4+ • Mesitylene)

By formula: H4N+ + C9H12 = (H4N+ • C9H12)

Quantity Value Units Method Reference Comment
ΔrH°91.2kJ/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
ΔrS°88.7J/mol*KPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase

NH4+ + Water = (NH4+ • Water)

By formula: H4N+ + H2O = (H4N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°86.2kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase
ΔrH°83.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase
ΔrH°72.4kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°103.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase
ΔrS°96.7J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
ΔrS°82.4J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • 2Water) + Carbon dioxide = (NH4+ • Carbon dioxide • 2Water)

By formula: (H4N+ • 2H2O) + CO2 = (H4N+ • CO2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrG°5.4kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields

(NH4+ • Water) + Water = (NH4+ • 2Water)

By formula: (H4N+ • H2O) + H2O = (H4N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°72.8kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; ΔrH?, Entropy change is questionable, appear out of line
ΔrH°57.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; ΔrH of 51.9 kJ/mol from plot is too small
ΔrH°61.5kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; ΔrH?, Entropy change is questionable, appear out of line
ΔrS°92.0J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; ΔrH of 51.9 kJ/mol from plot is too small
ΔrS°91.6J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrG°37.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.414.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; ΔrH of 51.9 kJ/mol from plot is too small

(NH4+ • 2Water) + Water = (NH4+ • 3Water)

By formula: (H4N+ • 2H2O) + H2O = (H4N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°57.3kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase
ΔrH°56.1kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
ΔrH°51.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
ΔrS°104.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase
ΔrS°105.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase
ΔrS°88.7J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
ΔrG°27.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields

(NH4+ • 3Water) + Water = (NH4+ • 4Water)

By formula: (H4N+ • 3H2O) + H2O = (H4N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°45.2kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase
ΔrH°51.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°96.2J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
ΔrS°114.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrG°21.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields

(NH4+ • 4Water) + Water = (NH4+ • 5Water)

By formula: (H4N+ • 4H2O) + H2O = (H4N+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°44.4kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase
ΔrH°41.kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°113.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
ΔrS°93.7J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • 5Water) + Water = (NH4+ • 6Water)

By formula: (H4N+ • 5H2O) + H2O = (H4N+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°38.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.266.PHPMSMeot-Ner (Mautner), 1984gas phase

(NH4+ • 6Water) + Water = (NH4+ • 7Water)

By formula: (H4N+ • 6H2O) + H2O = (H4N+ • 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°35.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
12.254.PHPMSMeot-Ner (Mautner), 1984gas phase

(NH4+ • Water) + Ammonia = (NH4+ • Ammonia • Water)

By formula: (H4N+ • H2O) + H3N = (H4N+ • H3N • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°77.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°96.2J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • 2Water) + Ammonia = (NH4+ • Ammonia • 2Water)

By formula: (H4N+ • 2H2O) + H3N = (H4N+ • H3N • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°76.1kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°127.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • 3Water) + Ammonia = (NH4+ • Ammonia • 3Water)

By formula: (H4N+ • 3H2O) + H3N = (H4N+ • H3N • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°72.4kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°147.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • Water • Ammonia) + Water = (NH4+ • 2Water • Ammonia)

By formula: (H4N+ • H2O • H3N) + H2O = (H4N+ • 2H2O • H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°53.1kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°105.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • Water • 2Ammonia) + Water = (NH4+ • 2Water • 2Ammonia)

By formula: (H4N+ • H2O • 2H3N) + H2O = (H4N+ • 2H2O • 2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°49.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°116.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • 2Water • Ammonia) + Water = (NH4+ • 3Water • Ammonia)

By formula: (H4N+ • 2H2O • H3N) + H2O = (H4N+ • 3H2O • H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°51.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°119.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • Water) + Sulfur dioxide = (NH4+ • Sulfur dioxide • Water)

By formula: (H4N+ • H2O) + O2S = (H4N+ • O2S • H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
27.300.HPMSBanic and Iribarne, 1985gas phase; electric fields

(NH4+ • 2Water) + Sulfur dioxide = (NH4+ • Sulfur dioxide • 2Water)

By formula: (H4N+ • 2H2O) + O2S = (H4N+ • O2S • 2H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.300.HPMSBanic and Iribarne, 1985gas phase; electric fields

(NH4+ • 3Water) + Sulfur dioxide = (NH4+ • Sulfur dioxide • 3Water)

By formula: (H4N+ • 3H2O) + O2S = (H4N+ • O2S • 3H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.300.HPMSBanic and Iribarne, 1985gas phase; electric fields

(NH4+ • Water • Sulfur dioxide) + Water = (NH4+ • 2Water • Sulfur dioxide)

By formula: (H4N+ • H2O • O2S) + H2O = (H4N+ • 2H2O • O2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrG°31.kJ/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields

(NH4+ • 2Water • Sulfur dioxide) + Water = (NH4+ • 3Water • Sulfur dioxide)

By formula: (H4N+ • 2H2O • O2S) + H2O = (H4N+ • 3H2O • O2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrG°22.kJ/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields

NH4+ + Hydrogen sulfide = (NH4+ • Hydrogen sulfide)

By formula: H4N+ + H2S = (H4N+ • H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°47.7kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
ΔrS°69.9J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

NH4+ + Ammonia = (NH4+ • Ammonia)

By formula: H4N+ + H3N = (H4N+ • H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°107. ± 6.kJ/molAVGN/AAverage of 4 out of 9 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°111. ± 10.J/mol*KAVGN/AAverage of 4 out of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.400.HPMSWincel, 1972gas phase

(NH4+ • Ammonia) + Hydrogen cyanide = (NH4+ • Hydrogen cyanide • Ammonia)

By formula: (H4N+ • H3N) + CHN = (H4N+ • CHN • H3N)

Quantity Value Units Method Reference Comment
ΔrH°59.4kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°77.4J/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase

(NH4+ • 2Ammonia) + Hydrogen cyanide = (NH4+ • Hydrogen cyanide • 2Ammonia)

By formula: (H4N+ • 2H3N) + CHN = (H4N+ • CHN • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°56.1kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
ΔrS°76.6J/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated

(NH4+ • Ammonia • 2Hydrogen cyanide) + Ammonia = (NH4+ • 2Ammonia • 2Hydrogen cyanide)

By formula: (H4N+ • H3N • 2CHN) + H3N = (H4N+ • 2H3N • 2CHN)

Quantity Value Units Method Reference Comment
ΔrH°54.0kJ/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.315.PHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated

(NH4+ • Ammonia • Acetonitrile) + Ammonia = (NH4+ • 2Ammonia • Acetonitrile)

By formula: (H4N+ • H3N • C2H3N) + H3N = (H4N+ • 2H3N • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°64.9kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph

(NH4+ • 2Ammonia • Acetonitrile) + Ammonia = (NH4+ • 3Ammonia • Acetonitrile)

By formula: (H4N+ • 2H3N • C2H3N) + H3N = (H4N+ • 3H3N • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°56.9kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph

(NH4+ • 3Ammonia • Acetonitrile) + Ammonia = (NH4+ • 4Ammonia • Acetonitrile)

By formula: (H4N+ • 3H3N • C2H3N) + H3N = (H4N+ • 4H3N • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°31.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph

(NH4+ • 4Ammonia • Acetonitrile) + Ammonia = (NH4+ • 5Ammonia • Acetonitrile)

By formula: (H4N+ • 4H3N • C2H3N) + H3N = (H4N+ • 5H3N • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°29.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph

(NH4+ • 5Ammonia • Acetonitrile) + Ammonia = (NH4+ • 6Ammonia • Acetonitrile)

By formula: (H4N+ • 5H3N • C2H3N) + H3N = (H4N+ • 6H3N • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°25.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph

(NH4+ • 6Ammonia • Acetonitrile) + Ammonia = (NH4+ • 7Ammonia • Acetonitrile)

By formula: (H4N+ • 6H3N • C2H3N) + H3N = (H4N+ • 7H3N • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°23.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph

(NH4+ • 7Ammonia • Acetonitrile) + Ammonia = (NH4+ • 8Ammonia • Acetonitrile)

By formula: (H4N+ • 7H3N • C2H3N) + H3N = (H4N+ • 8H3N • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°25.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph

(NH4+ • 8Ammonia • Acetonitrile) + Ammonia = (NH4+ • 9Ammonia • Acetonitrile)

By formula: (H4N+ • 8H3N • C2H3N) + H3N = (H4N+ • 9H3N • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°23.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph

(NH4+ • Ammonia) + Water = (NH4+ • Water • Ammonia)

By formula: (H4N+ • H3N) + H2O = (H4N+ • H2O • H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°54.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°84.9J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • 2Ammonia) + Water = (NH4+ • Water • 2Ammonia)

By formula: (H4N+ • 2H3N) + H2O = (H4N+ • H2O • 2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°51.9kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°103.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • 3Ammonia) + Water = (NH4+ • Water • 3Ammonia)

By formula: (H4N+ • 3H3N) + H2O = (H4N+ • H2O • 3H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°49.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°117.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • Ammonia • Water) + Ammonia = (NH4+ • 2Ammonia • Water)

By formula: (H4N+ • H3N • H2O) + H3N = (H4N+ • 2H3N • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°71.5kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°133.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • Ammonia • 2Water) + Ammonia = (NH4+ • 2Ammonia • 2Water)

By formula: (H4N+ • H3N • 2H2O) + H3N = (H4N+ • 2H3N • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°65.7kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°142.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • 2Ammonia • Water) + Ammonia = (NH4+ • 3Ammonia • Water)

By formula: (H4N+ • 2H3N • H2O) + H3N = (H4N+ • 3H3N • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°62.8kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°144.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase

(NH4+ • Ammonia) + Ammonia = (NH4+ • 2Ammonia)

By formula: (H4N+ • H3N) + H3N = (H4N+ • 2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°70. ± 5.kJ/molAVGN/AAverage of 5 out of 8 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KHPMSTang and Castleman, 1975gas phase
ΔrS°99.2J/mol*KPHPMSArshadi and Futrell, 1974gas phase
ΔrS°104.J/mol*KDTLong and Franklin, 1973gas phase
ΔrS°112.J/mol*KPHPMSSearles and Kebarle, 1968gas phase
ΔrS°95.8J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; typographical error in ΔrH

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.296.FAFehsenfeld and Ferguson, 1973gas phase; DG>
42.3296.SAMSPuckett and Teague, 1971gas phase
23.400.HPMSWincel, 1972gas phase

(NH4+ • 2Ammonia) + Ammonia = (NH4+ • 3Ammonia)

By formula: (H4N+ • 2H3N) + H3N = (H4N+ • 3H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°50. ± 20.kJ/molAVGN/AAverage of 6 out of 9 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°105. ± 5.J/mol*KAVGN/AAverage of 4 out of 7 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
27.296.FAFehsenfeld and Ferguson, 1973gas phase
27.296.SAMSPuckett and Teague, 1971gas phase

(NH4+ • 3Ammonia) + Ammonia = (NH4+ • 4Ammonia)

By formula: (H4N+ • 3H3N) + H3N = (H4N+ • 4H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°51. ± 4.kJ/molAVGN/AAverage of 5 out of 10 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°118. ± 8.J/mol*KAVGN/AAverage of 3 out of 7 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
14.296.FAFehsenfeld and Ferguson, 1973gas phase

(NH4+ • 4Ammonia) + Ammonia = (NH4+ • 5Ammonia)

By formula: (H4N+ • 4H3N) + H3N = (H4N+ • 5H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°29.kJ/molPHPMSArshadi and Futrell, 1974gas phase
ΔrH°31.kJ/molPHPMSSearles and Kebarle, 1968gas phase
ΔrH°30.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph
ΔrH°12.kJ/molTPEPICOKamke, Herrmann, et al., 1988gas phase
ΔrH°40.kJ/molDTLong and Franklin, 1973gas phase
Quantity Value Units Method Reference Comment
ΔrS°90.0J/mol*KPHPMSArshadi and Futrell, 1974gas phase
ΔrS°100.J/mol*KPHPMSSearles and Kebarle, 1968gas phase
ΔrS°130.J/mol*KDTLong and Franklin, 1973gas phase
Quantity Value Units Method Reference Comment
ΔrG°2.kJ/molHPMSHogg, Haynes, et al., 1966gas phase

(NH4+ • 5Ammonia) + Ammonia = (NH4+ • 6Ammonia)

By formula: (H4N+ • 5H3N) + H3N = (H4N+ • 6H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°27.kJ/molPHPMSArshadi and Futrell, 1974gas phase
ΔrH°30.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph
Quantity Value Units Method Reference Comment
ΔrS°91.6J/mol*KPHPMSArshadi and Futrell, 1974gas phase

(NH4+ • 6Ammonia) + Ammonia = (NH4+ • 7Ammonia)

By formula: (H4N+ • 6H3N) + H3N = (H4N+ • 7H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph

(NH4+ • 7Ammonia) + Ammonia = (NH4+ • 8Ammonia)

By formula: (H4N+ • 7H3N) + H3N = (H4N+ • 8H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph

(NH4+ • 8Ammonia) + Ammonia = (NH4+ • 9Ammonia)

By formula: (H4N+ • 8H3N) + H3N = (H4N+ • 9H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph

(NH4+ • 9Ammonia) + Ammonia = (NH4+ • 10Ammonia)

By formula: (H4N+ • 9H3N) + H3N = (H4N+ • 10H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph

(NH4+ • 10Ammonia) + Ammonia = (NH4+ • 11Ammonia)

By formula: (H4N+ • 10H3N) + H3N = (H4N+ • 11H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph

(NH4+ • 11Ammonia) + Ammonia = (NH4+ • 12Ammonia)

By formula: (H4N+ • 11H3N) + H3N = (H4N+ • 12H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph

(NH4+ • 12Ammonia) + Ammonia = (NH4+ • 13Ammonia)

By formula: (H4N+ • 12H3N) + H3N = (H4N+ • 13H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph

(NH4+ • 13Ammonia) + Ammonia = (NH4+ • 14Ammonia)

By formula: (H4N+ • 13H3N) + H3N = (H4N+ • 14H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph

(NH4+ • 14Ammonia) + Ammonia = (NH4+ • 15Ammonia)

By formula: (H4N+ • 14H3N) + H3N = (H4N+ • 15H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph

(NH4+ • 15Ammonia) + Ammonia = (NH4+ • 16Ammonia)

By formula: (H4N+ • 15H3N) + H3N = (H4N+ • 16H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molMKERWei, Tzeng, et al., 1990gas phase; from graph

NH4+ + Nitrogen = (NH4+ • Nitrogen)

By formula: H4N+ + N2 = (H4N+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°50. ± 20.kJ/molDTGheno and Fitaire, 1987gas phase
Quantity Value Units Method Reference Comment
ΔrS°130.J/mol*KDTGheno and Fitaire, 1987gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Deakyne, Knuth, et al., 1994
Deakyne, C.A.; Knuth, D.M.; Speller, C.V.; Meot-Ner (Mautner), M.; Sieck, L.W., Filling of Solvent Shells about Ions. Part 3. Isomeric Clusters of (HCN)n(NH3)mH+, J. Mol. Structure (Theochem), 1994, 307, 217, https://doi.org/10.1016/0166-1280(94)80130-4 . [all data]

Speller and Meot-Ner (Mautner), 1985
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Notes

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