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OClO3


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 19847 Ne Kopitzky, Grothe, et al., 2002


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

300 Ne AB Kopitzky, Grothe, et al., 2002

State:   X'


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 ClO2 s-stretch 1292.5 T Ne IR Kopitzky, Grothe, et al., 2002
1 ClO2 s-stretch 1252 T Ar IR Kopitzky, Grothe, et al., 2002

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 ClO2 s-stretch 1160.8 vs Ne IR Grothe and Willner, 1996
Kopitzky, Grothe, et al., 2002
1 ClO2 s-stretch 1154 Ar IR Kopitzky, Grothe, et al., 2002
2 ClO2 s-stretch 873.0 w Ne IR Grothe and Willner, 1996
Kopitzky, Grothe, et al., 2002
2 ClO2 s-stretch 872 T Ar IR Kopitzky, Grothe, et al., 2002
3 Deformation 573.0 w m Ne IR Grothe and Willner, 1996
Kopitzky, Grothe, et al., 2002
3 Deformation 570 Ar IR Kopitzky, Grothe, et al., 2002
4 Deformation 337.2 w Ne IR Kopitzky, Grothe, et al., 2002
b1 6 Deformation 644.3 w m Ne IR Grothe and Willner, 1996
Kopitzky, Grothe, et al., 2002
6 Deformation 641 Ar IR Kopitzky, Grothe, et al., 2002
7 Deformation 354.0 w Ne IR Kopitzky, Grothe, et al., 2002
b2 8 ClO2 a-stretch 1233.6 vs Ne IR Grothe and Willner, 1996
Kopitzky, Grothe, et al., 2002
8 ClO2 a-stretch 1227 Ar IR Kopitzky, Grothe, et al., 2002
9 Deformation 544.3 w Ne IR Kopitzky, Grothe, et al., 2002

Additional references: Jacox, 1998, page 306

Notes

wWeak
mMedium
vsVery strong
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kopitzky, Grothe, et al., 2002
Kopitzky, R.; Grothe, H.; Willner, H., Chlorine Oxide Radicals ClOx (x=1-4) Studied by Matrix Isolation Spectroscopy, Chem. Eur. J., 2002, 8, 24, 5601, https://doi.org/10.1002/1521-3765(20021216)8:24<5601::AID-CHEM5601>3.0.CO;2-Z . [all data]

Grothe and Willner, 1996
Grothe, H.; Willner, H., Chlortetraoxid, Angew. Chem., 1996, 108, 7, 816, https://doi.org/10.1002/ange.19961080715 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

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