Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Yttrium ion (1+)


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Yttrium ion (1+) + Ethylene = (Yttrium ion (1+) bullet Ethylene)

By formula: Y+ + C2H4 = (Y+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar52. ± 3.kcal/molPDissRanashinge and Freiser, 1992gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
26.1 CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

Yttrium ion (1+) + Acetylene = (Yttrium ion (1+) bullet Acetylene)

By formula: Y+ + C2H2 = (Y+ bullet C2H2)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
60.5 (+7.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Yttrium ion (1+) + Methyl radical = (Yttrium ion (1+) bullet Methyl radical)

By formula: Y+ + CH3 = (Y+ bullet CH3)

Quantity Value Units Method Reference Comment
Deltar59.5 ± 1.1kcal/molCIDTSunderlin and Armentrout, 1989RCD

Yttrium ion (1+) + Methylene = (Yttrium ion (1+) bullet Methylene)

By formula: Y+ + CH2 = (Y+ bullet CH2)

Quantity Value Units Method Reference Comment
Deltar95.2 ± 3.0kcal/molCIDTSunderlin and Armentrout, 1989RCD

Yttrium ion (1+) + Carbon monosulfide = (Yttrium ion (1+) bullet Carbon monosulfide)

By formula: Y+ + CS = (Y+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar32.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ranashinge and Freiser, 1992
Ranashinge, Y.A.; Freiser, B.S., Gas-Phase Photodissociation of MC2H2+ (M = Sc, Y, La). Determination of D0(M+ - C2H2), Chem. Phys. Let., 1992, 200, 1-2, 135, https://doi.org/10.1016/0009-2614(92)87058-W . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Sunderlin and Armentrout, 1989
Sunderlin, L.S.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with Methane and Ethane, J. Am. Chem. Soc., 1989, 111, 11, 3845, https://doi.org/10.1021/ja00193a015 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References