Vanadium ion (1+)

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Vanadium ion (1+) + Carbon monoxide = (Vanadium ion (1+) • Carbon monoxide)

By formula: V+ + CO = (V+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°120. ± 14.kJ/molCIDArmentrout and Kickel, 1994gas phase; ΔrH(0 K0, guided ion beam CID; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
113. (+3.,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 2Carbon monoxide)

By formula: (V+ • CO) + CO = (V+ • 2CO)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
91. (+3.,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
106. (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 3Carbon monoxide)

By formula: (V+ • 2CO) + CO = (V+ • 3CO)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
69. (+4.,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
61. (+12.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 4Carbon monoxide)

By formula: (V+ • 3CO) + CO = (V+ • 4CO)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
85.8 (+9.6,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
95. (+14.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 5Carbon monoxide)

By formula: (V+ • 4CO) + CO = (V+ • 5CO)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
91. (+3.,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
92.9 (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 5Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 6Carbon monoxide)

By formula: (V+ • 5CO) + CO = (V+ • 6CO)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
99.6 (+6.7,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
124. (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 6Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 7Carbon monoxide)

By formula: (V+ • 6CO) + CO = (V+ • 7CO)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
50.2 (+8.8,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

Vanadium ion (1+) + Carbon monosulfide = (Vanadium ion (1+) • Carbon monosulfide)

By formula: V+ + CS = (V+ • CS)

Quantity Value Units Method Reference Comment
ΔrH°164. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Vanadium ion (1+) + Carbon disulfide = (Vanadium ion (1+) • Carbon disulfide)

By formula: V+ + CS2 = (V+ • CS2)

Quantity Value Units Method Reference Comment
ΔrH°114. ± 13.kJ/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

Vanadium ion (1+) + Acetylene = (Vanadium ion (1+) • Acetylene)

By formula: V+ + C2H2 = (V+ • C2H2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
205. (+20.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Ethylene = (Vanadium ion (1+) • Ethylene)

By formula: V+ + C2H4 = (V+ • C2H4)

Quantity Value Units Method Reference Comment
ΔrH°125. ± 7.9kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
117. CIDArmentrout and Kickel, 1994gas phase; ΔrH>=, guided ion beam CID; M

(Vanadium ion (1+) • Ethylene) + Ethylene = (Vanadium ion (1+) • 2Ethylene)

By formula: (V+ • C2H4) + C2H4 = (V+ • 2C2H4)

Quantity Value Units Method Reference Comment
ΔrH°127. ± 14.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Vanadium ion (1+) + 1,3-Diazine = (Vanadium ion (1+) • 1,3-Diazine)

By formula: V+ + C4H4N2 = (V+ • C4H4N2)

Quantity Value Units Method Reference Comment
ΔrH°204. ± 7.1kJ/molCIDTAmunugama and Rodgers, 2001RCD

Vanadium ion (1+) + Pyrrole = (Vanadium ion (1+) • Pyrrole)

By formula: V+ + C4H5N = (V+ • C4H5N)

Quantity Value Units Method Reference Comment
ΔrH°>170.kJ/molRAKGapeev and Yang, 2000RCD

Vanadium ion (1+) + Pyridine = (Vanadium ion (1+) • Pyridine)

By formula: V+ + C5H5N = (V+ • C5H5N)

Quantity Value Units Method Reference Comment
ΔrH°218. ± 13.kJ/molCIDTRodgers, Stanley, et al., 2000RCD

Vanadium ion (1+) + Adenine = (Vanadium ion (1+) • Adenine)

By formula: V+ + C5H5N5 = (V+ • C5H5N5)

Quantity Value Units Method Reference Comment
ΔrH°≤265. ± 10.kJ/molCIDTRodgers and Armentrout, 2002RCD

Vanadium ion (1+) + Benzene = (Vanadium ion (1+) • Benzene)

By formula: V+ + C6H6 = (V+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°>230.kJ/molRAKGapeev and Dunbar, 2002RCD
ΔrH°234. ± 10.kJ/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
233. (+9.6,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Benzene) + Benzene = (Vanadium ion (1+) • 2Benzene)

By formula: (V+ • C6H6) + C6H6 = (V+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°246. ± 18.kJ/molCIDMeyer, Khan, et al., 1995gas phase; ΔrH(0k), guided ion beam CID; M,RCD

Vanadium ion (1+) + Water = (Vanadium ion (1+) • Water)

By formula: V+ + H2O = (V+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°150. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
ΔrH°147.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
147. (+35.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Water) + Water = (Vanadium ion (1+) • 2Water)

By formula: (V+ • H2O) + H2O = (V+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°149.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
151. (+10.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2Water) + Water = (Vanadium ion (1+) • 3Water)

By formula: (V+ • 2H2O) + H2O = (V+ • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°51.0kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
68.2 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 3Water) + Water = (Vanadium ion (1+) • 4Water)

By formula: (V+ • 3H2O) + H2O = (V+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
67.8 (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Ammonia = (Vanadium ion (1+) • Ammonia)

By formula: V+ + H3N = (V+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°190. ± 11.kJ/molCIDTWalter and Armentrout, 1998RCD
ΔrH°217.kJ/molCIDMarinelli and Squires, 1989gas phase; M

(Vanadium ion (1+) • Ammonia) + Ammonia = (Vanadium ion (1+) • 2Ammonia)

By formula: (V+ • H3N) + H3N = (V+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°164. ± 9.2kJ/molCIDTWalter and Armentrout, 1998RCD
ΔrH°188.kJ/molCIDMarinelli and Squires, 1989gas phase; M

(Vanadium ion (1+) • 2Ammonia) + Ammonia = (Vanadium ion (1+) • 3Ammonia)

By formula: (V+ • 2H3N) + H3N = (V+ • 3H3N)

Quantity Value Units Method Reference Comment
ΔrH°104. ± 11.kJ/molCIDTWalter and Armentrout, 1998RCD
ΔrH°94.6kJ/molCIDMarinelli and Squires, 1989gas phase; M

(Vanadium ion (1+) • 3Ammonia) + Ammonia = (Vanadium ion (1+) • 4Ammonia)

By formula: (V+ • 3H3N) + H3N = (V+ • 4H3N)

Quantity Value Units Method Reference Comment
ΔrH°95. ± 11.kJ/molCIDTWalter and Armentrout, 1998RCD
ΔrH°78.2kJ/molCIDMarinelli and Squires, 1989gas phase; M

Vanadium ion (1+) + Sulfur dimer = (Vanadium ion (1+) • Sulfur dimer)

By formula: V+ + S2 = (V+ • S2)

Quantity Value Units Method Reference Comment
ΔrH°313. ± 13.kJ/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

(Vanadium ion (1+) • Sulfur dimer) + Sulfur dimer = (Vanadium ion (1+) • 2Sulfur dimer)

By formula: (V+ • S2) + S2 = (V+ • 2S2)

Quantity Value Units Method Reference Comment
ΔrH°286. ± 18.kJ/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

Vanadium ion (1+) + vanadium = (Vanadium ion (1+) • vanadium)

By formula: V+ + V = (V+ • V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
303. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • vanadium) + vanadium = (Vanadium ion (1+) • 2vanadium)

By formula: (V+ • V) + V = (V+ • 2V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
219. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2vanadium) + vanadium = (Vanadium ion (1+) • 3vanadium)

By formula: (V+ • 2V) + V = (V+ • 3V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
341. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 3vanadium) + vanadium = (Vanadium ion (1+) • 4vanadium)

By formula: (V+ • 3V) + V = (V+ • 4V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
313. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 4vanadium) + vanadium = (Vanadium ion (1+) • 5vanadium)

By formula: (V+ • 4V) + V = (V+ • 5V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
398. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 5vanadium) + vanadium = (Vanadium ion (1+) • 6vanadium)

By formula: (V+ • 5V) + V = (V+ • 6V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
372. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 6vanadium) + vanadium = (Vanadium ion (1+) • 7vanadium)

By formula: (V+ • 6V) + V = (V+ • 7V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
385. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 7vanadium) + vanadium = (Vanadium ion (1+) • 8vanadium)

By formula: (V+ • 7V) + V = (V+ • 8V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
354. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 8vanadium) + vanadium = (Vanadium ion (1+) • 9vanadium)

By formula: (V+ • 8V) + V = (V+ • 9V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
382. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 9vanadium) + vanadium = (Vanadium ion (1+) • 10vanadium)

By formula: (V+ • 9V) + V = (V+ • 10V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
382. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 10vanadium) + vanadium = (Vanadium ion (1+) • 11vanadium)

By formula: (V+ • 10V) + V = (V+ • 11V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
398. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 11vanadium) + vanadium = (Vanadium ion (1+) • 12vanadium)

By formula: (V+ • 11V) + V = (V+ • 12V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
448.9 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 12vanadium) + vanadium = (Vanadium ion (1+) • 13vanadium)

By formula: (V+ • 12V) + V = (V+ • 13V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
388. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 13vanadium) + vanadium = (Vanadium ion (1+) • 14vanadium)

By formula: (V+ • 13V) + V = (V+ • 14V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
451.9 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 14vanadium) + vanadium = (Vanadium ion (1+) • 15vanadium)

By formula: (V+ • 14V) + V = (V+ • 15V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
376. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 15vanadium) + vanadium = (Vanadium ion (1+) • 16vanadium)

By formula: (V+ • 15V) + V = (V+ • 16V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
404. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 16vanadium) + vanadium = (Vanadium ion (1+) • 17vanadium)

By formula: (V+ • 16V) + V = (V+ • 17V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
381. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 17vanadium) + vanadium = (Vanadium ion (1+) • 18vanadium)

By formula: (V+ • 17V) + V = (V+ • 18V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
408. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 18vanadium) + vanadium = (Vanadium ion (1+) • 19vanadium)

By formula: (V+ • 18V) + V = (V+ • 19V)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
442.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Xenon = (Vanadium ion (1+) • Xenon)

By formula: V+ + Xe = (V+ • Xe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
33. (+5.9,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Sievers and Armentrout, 1995
Sievers, M.R.; Armentrout, P.B., Collision-Induced Dissociation Studies of V(CO)x+, x = 1-7: Sequential Bond Energies and the Heat of Formation of V(CO)6, J. Phys. Chem., 1995, 99, 20, 8135, https://doi.org/10.1021/j100020a041 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Schroeder, Kretzschmar, et al., 2003
Schroeder, D.; Kretzschmar, I.; Schwarz; Armentrout, P.B., Structure, Thermochemistry, and Reactivityof MSn+ Cations (M=V,Mo; n=1-3) in the Gas Phase, Int. J. Mass Spectrom., 2003, 228, 2-3, 439, https://doi.org/10.1016/S1387-3806(03)00137-4 . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Gapeev and Dunbar, 2002
Gapeev, A.; Dunbar, R.C., Reactivity and Binding Energies of Transition Metal Halide Ions with Benzene, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Notes

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