2-Butene, 1,4-dichloro-, (Z)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil425.7KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus231.2KN/AAnonymous, 1968Uncertainty assigned by TRC = 2. K; source of data not stated; TRC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
425.20.997Aldrich Chemical Company Inc., 1990BS
295.70.004Weast and Grasselli, 1989BS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2-Butene, 1,4-dichloro-, (Z)- = 1-Butene, 3,4 dichloro, (±)-

By formula: C4H6Cl2 = C4H6Cl2

Quantity Value Units Method Reference Comment
Δr0.399kcal/molEqkZakharova, Gul'neva, et al., 1991gas phase; Heat of isomerization at 383 K

2-Butene, 1,4-dichloro-, (Z)- = 2-Butene, 1,4-dichloro-, (E)-

By formula: C4H6Cl2 = C4H6Cl2

Quantity Value Units Method Reference Comment
Δr-0.17kcal/molEqkZakharova, Gul'neva, et al., 1991gas phase; Heat of isomerization at 383 K

2-Butene, 1,4-dichloro-, (E)- = 2-Butene, 1,4-dichloro-, (Z)-

By formula: C4H6Cl2 = C4H6Cl2

Quantity Value Units Method Reference Comment
Δr-1.0kcal/molEqkLevanova, Yanshevskaya, et al., 1986liquid phase; solvent: Naphtha

2-Butene, 1,4-dichloro-, (Z)- = 1-Butene, 3,4-dichloro-

By formula: C4H6Cl2 = C4H6Cl2

Quantity Value Units Method Reference Comment
Δr0.5kcal/molEqkLevanova, Yanshevskaya, et al., 1986liquid phase; solvent: Naphtha

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Anonymous, 1968
Anonymous, R., Properties of hydrocarbon of high molecular weight, Am. Pet. Inst. Res. Proj. 42, Penn. State Univ., 1968. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Zakharova, Gul'neva, et al., 1991
Zakharova, L.A.; Gul'neva, I.V.; Shestakov, G.K.; Temkin, O.N.; Levanova, S.V.; Martirosyan, G.T.; Malkhasyan, A.Ts.; Asatryan, E.M., Isomerization of dichlorobutenes, Kinet. Catal., 1991, 32, 1190-1194, In original 1332. [all data]

Levanova, Yanshevskaya, et al., 1986
Levanova, S.V.; Yanshevskaya, I.V.; Asatryan, E.M.; Saakyan, N.L.; Kostand'yan, V.A.; Malkhasyan, A.Ts.; Martirosyan, G.T., Relationships of isomerization of the allylic type, J. Appl. Chem. USSR, 1986, 59, 790-793. [all data]


Notes

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