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Silver ion (1+)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Silver ion (1+) + Ethylene = (Silver ion (1+) bullet Ethylene)

By formula: Ag+ + C2H4 = (Ag+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar33.7kcal/molHPMSGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.1cal/mol*KN/AGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.1750.HPMSGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M

(Silver ion (1+) bullet 2Ammonia) + Ammonia = (Silver ion (1+) bullet 3Ammonia)

By formula: (Ag+ bullet 2H3N) + H3N = (Ag+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar14.6kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.6cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 2Water) + Water = (Silver ion (1+) bullet 3Water)

By formula: (Ag+ bullet 2H2O) + H2O = (Ag+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar15.0kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.6cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 3Ammonia) + Ammonia = (Silver ion (1+) bullet 4Ammonia)

By formula: (Ag+ bullet 3H3N) + H3N = (Ag+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar13.0kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.0cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 3Water) + Water = (Silver ion (1+) bullet 4Water)

By formula: (Ag+ bullet 3H2O) + H2O = (Ag+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar14.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.5cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 4Ammonia) + Ammonia = (Silver ion (1+) bullet 5Ammonia)

By formula: (Ag+ bullet 4H3N) + H3N = (Ag+ bullet 5H3N)

Quantity Value Units Method Reference Comment
Deltar12.8kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar34.1cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 4Water) + Water = (Silver ion (1+) bullet 5Water)

By formula: (Ag+ bullet 4H2O) + H2O = (Ag+ bullet 5H2O)

Quantity Value Units Method Reference Comment
Deltar13.7kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 5Water) + Water = (Silver ion (1+) bullet 6Water)

By formula: (Ag+ bullet 5H2O) + H2O = (Ag+ bullet 6H2O)

Quantity Value Units Method Reference Comment
Deltar13.3kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.2cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet Ammonia) + Ammonia = (Silver ion (1+) bullet 2Ammonia)

By formula: (Ag+ bullet H3N) + H3N = (Ag+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar36.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.7cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet Water) + Water = (Silver ion (1+) bullet 2Water)

By formula: (Ag+ bullet H2O) + H2O = (Ag+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar25.4kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 2Pyridine) + Pyridine = (Silver ion (1+) bullet 3Pyridine)

By formula: (Ag+ bullet 2C5H5N) + C5H5N = (Ag+ bullet 3C5H5N)

Quantity Value Units Method Reference Comment
Deltar16.7kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar28.0cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 3Pyridine) + Pyridine = (Silver ion (1+) bullet 4Pyridine)

By formula: (Ag+ bullet 3C5H5N) + C5H5N = (Ag+ bullet 4C5H5N)

Quantity Value Units Method Reference Comment
Deltar17.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar40.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet Ethylene) + Ethylene = (Silver ion (1+) bullet 2Ethylene)

By formula: (Ag+ bullet C2H4) + C2H4 = (Ag+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar32.4kcal/molHPMSGuo and Castleman, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.2cal/mol*KHPMSGuo and Castleman, 1991gas phase; M

Silver ion (1+) + Water = (Silver ion (1+) bullet Water)

By formula: Ag+ + H2O = (Ag+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar33.3kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar28.4cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Silver ion (1+) bullet 3Carbon monoxide)

By formula: (Ag+ bullet 2CO) + CO = (Ag+ bullet 3CO)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
13.1 (+1.8,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Silver ion (1+) bullet 4Carbon monoxide)

By formula: (Ag+ bullet 3CO) + CO = (Ag+ bullet 4CO)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
10.8 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Silver ion (1+) bullet 2Carbon monoxide)

By formula: (Ag+ bullet CO) + CO = (Ag+ bullet 2CO)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
26.1 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

Silver ion (1+) + Benzene = (Silver ion (1+) bullet Benzene)

By formula: Ag+ + C6H6 = (Ag+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar37.3 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar39.9 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Carbon monoxide = (Silver ion (1+) bullet Carbon monoxide)

By formula: Ag+ + CO = (Ag+ bullet CO)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
21.2 (+1.2,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) bullet Benzene) + Benzene = (Silver ion (1+) bullet 2Benzene)

By formula: (Ag+ bullet C6H6) + C6H6 = (Ag+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar39.9 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) bullet Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar36.3 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000RCD

(Silver ion (1+) bullet Acetonitrile) + Acetonitrile = (Silver ion (1+) bullet 2Acetonitrile)

By formula: (Ag+ bullet C2H3N) + C2H3N = (Ag+ bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar34.7kcal/molCIDTShoieb, Aribi, et al., 2001RCD

Silver ion (1+) + 2-Pentene, (E)- = (Silver ion (1+) bullet 2-Pentene, (E)-)

By formula: Ag+ + C5H10 = (Ag+ bullet C5H10)

Quantity Value Units Method Reference Comment
Deltar37.8 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Acetone = (Silver ion (1+) bullet Acetone)

By formula: Ag+ + C3H6O = (Ag+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar38.2 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Acetaldehyde = (Silver ion (1+) bullet Acetaldehyde)

By formula: Ag+ + C2H4O = (Ag+ bullet C2H4O)

Quantity Value Units Method Reference Comment
Deltar43.5 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Isoprene = (Silver ion (1+) bullet Isoprene)

By formula: Ag+ + C5H8 = (Ag+ bullet C5H8)

Quantity Value Units Method Reference Comment
Deltar39.2 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Acetonitrile = (Silver ion (1+) bullet Acetonitrile)

By formula: Ag+ + C2H3N = (Ag+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar38.7kcal/molCIDTShoieb, Aribi, et al., 2001RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W., The Bonding Strength of Ag+(C2H4) and Ag+(C2H4)2 Complexes, Chem. Phys. Lett., 1991, 181, 1, 16, https://doi.org/10.1016/0009-2614(91)90214-T . [all data]

Holland and Castleman, 1982
Holland, P.M.; Castleman, A.W., The Thermochemical Properties of Gas - Phase Transition Metal Ion Complexes, J. Chem. Phys., 1982, 76, 8, 4195, https://doi.org/10.1063/1.443497 . [all data]

Meyer, Chen, et al., 1995
Meyer, F.; Chen, Y.M.; Armentrout, P.B., Sequential Bond Energies of Cu(CO)x+ and Ag(CO)x+ (x = 1-4), J. Am. Chem. Soc., 1995, 117, 14, 4071, https://doi.org/10.1021/ja00119a023 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Ho, Yang, et al., 1997
Ho, Y.-P.; Yang, Y.-C.; Klippenstein, S.J.; Dunbar, R.C., Binding Energies of Ag+ and Cd+ Complexes from Analysis of Radiative Association Kinetics, J. Phys. Chem. A, 1997, 101, 18, 3338, https://doi.org/10.1021/jp9637284 . [all data]

Shoieb, Aribi, et al., 2001
Shoieb, T.; Aribi, H.; Siu, K.W.M.; Hopkinson, A.C., A Study of Silver(I) Ion-Organometallic Complexes: Ion Structures, Binding Energies, and Substituent Effects, J. Phys. Chem. A, 2001, 105, 4, 710, https://doi.org/10.1021/jp002676m . [all data]


Notes

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