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Silver ion (1+)


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Silver ion (1+) + Carbon monoxide = (Silver ion (1+) bullet Carbon monoxide)

By formula: Ag+ + CO = (Ag+ bullet CO)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
21.2 (+1.2,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Silver ion (1+) bullet 2Carbon monoxide)

By formula: (Ag+ bullet CO) + CO = (Ag+ bullet 2CO)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
26.1 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Silver ion (1+) bullet 3Carbon monoxide)

By formula: (Ag+ bullet 2CO) + CO = (Ag+ bullet 3CO)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
13.1 (+1.8,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Silver ion (1+) bullet 4Carbon monoxide)

By formula: (Ag+ bullet 3CO) + CO = (Ag+ bullet 4CO)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
10.8 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) bullet Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar36.3 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000RCD

Silver ion (1+) + Acetonitrile = (Silver ion (1+) bullet Acetonitrile)

By formula: Ag+ + C2H3N = (Ag+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar38.7kcal/molCIDTShoieb, Aribi, et al., 2001RCD

(Silver ion (1+) bullet Acetonitrile) + Acetonitrile = (Silver ion (1+) bullet 2Acetonitrile)

By formula: (Ag+ bullet C2H3N) + C2H3N = (Ag+ bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar34.7kcal/molCIDTShoieb, Aribi, et al., 2001RCD

Silver ion (1+) + Acetaldehyde = (Silver ion (1+) bullet Acetaldehyde)

By formula: Ag+ + C2H4O = (Ag+ bullet C2H4O)

Quantity Value Units Method Reference Comment
Deltar43.5 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Ethylene = (Silver ion (1+) bullet Ethylene)

By formula: Ag+ + C2H4 = (Ag+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar33.7kcal/molHPMSGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.1cal/mol*KN/AGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.1750.HPMSGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M

(Silver ion (1+) bullet Ethylene) + Ethylene = (Silver ion (1+) bullet 2Ethylene)

By formula: (Ag+ bullet C2H4) + C2H4 = (Ag+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar32.4kcal/molHPMSGuo and Castleman, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.2cal/mol*KHPMSGuo and Castleman, 1991gas phase; M

Silver ion (1+) + Acetone = (Silver ion (1+) bullet Acetone)

By formula: Ag+ + C3H6O = (Ag+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar38.2 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

(Silver ion (1+) bullet 2Pyridine) + Pyridine = (Silver ion (1+) bullet 3Pyridine)

By formula: (Ag+ bullet 2C5H5N) + C5H5N = (Ag+ bullet 3C5H5N)

Quantity Value Units Method Reference Comment
Deltar16.7kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar28.0cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 3Pyridine) + Pyridine = (Silver ion (1+) bullet 4Pyridine)

By formula: (Ag+ bullet 3C5H5N) + C5H5N = (Ag+ bullet 4C5H5N)

Quantity Value Units Method Reference Comment
Deltar17.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar40.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

Silver ion (1+) + Isoprene = (Silver ion (1+) bullet Isoprene)

By formula: Ag+ + C5H8 = (Ag+ bullet C5H8)

Quantity Value Units Method Reference Comment
Deltar39.2 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + 2-Pentene, (E)- = (Silver ion (1+) bullet 2-Pentene, (E)-)

By formula: Ag+ + C5H10 = (Ag+ bullet C5H10)

Quantity Value Units Method Reference Comment
Deltar37.8 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Benzene = (Silver ion (1+) bullet Benzene)

By formula: Ag+ + C6H6 = (Ag+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar37.3 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar39.9 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

(Silver ion (1+) bullet Benzene) + Benzene = (Silver ion (1+) bullet 2Benzene)

By formula: (Ag+ bullet C6H6) + C6H6 = (Ag+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar39.9 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Water = (Silver ion (1+) bullet Water)

By formula: Ag+ + H2O = (Ag+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar33.3kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar28.4cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet Water) + Water = (Silver ion (1+) bullet 2Water)

By formula: (Ag+ bullet H2O) + H2O = (Ag+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar25.4kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 2Water) + Water = (Silver ion (1+) bullet 3Water)

By formula: (Ag+ bullet 2H2O) + H2O = (Ag+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar15.0kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.6cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 3Water) + Water = (Silver ion (1+) bullet 4Water)

By formula: (Ag+ bullet 3H2O) + H2O = (Ag+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar14.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.5cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 4Water) + Water = (Silver ion (1+) bullet 5Water)

By formula: (Ag+ bullet 4H2O) + H2O = (Ag+ bullet 5H2O)

Quantity Value Units Method Reference Comment
Deltar13.7kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 5Water) + Water = (Silver ion (1+) bullet 6Water)

By formula: (Ag+ bullet 5H2O) + H2O = (Ag+ bullet 6H2O)

Quantity Value Units Method Reference Comment
Deltar13.3kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.2cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet Ammonia) + Ammonia = (Silver ion (1+) bullet 2Ammonia)

By formula: (Ag+ bullet H3N) + H3N = (Ag+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar36.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.7cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 2Ammonia) + Ammonia = (Silver ion (1+) bullet 3Ammonia)

By formula: (Ag+ bullet 2H3N) + H3N = (Ag+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar14.6kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.6cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 3Ammonia) + Ammonia = (Silver ion (1+) bullet 4Ammonia)

By formula: (Ag+ bullet 3H3N) + H3N = (Ag+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar13.0kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.0cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 4Ammonia) + Ammonia = (Silver ion (1+) bullet 5Ammonia)

By formula: (Ag+ bullet 4H3N) + H3N = (Ag+ bullet 5H3N)

Quantity Value Units Method Reference Comment
Deltar12.8kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar34.1cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meyer, Chen, et al., 1995
Meyer, F.; Chen, Y.M.; Armentrout, P.B., Sequential Bond Energies of Cu(CO)x+ and Ag(CO)x+ (x = 1-4), J. Am. Chem. Soc., 1995, 117, 14, 4071, https://doi.org/10.1021/ja00119a023 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Shoieb, Aribi, et al., 2001
Shoieb, T.; Aribi, H.; Siu, K.W.M.; Hopkinson, A.C., A Study of Silver(I) Ion-Organometallic Complexes: Ion Structures, Binding Energies, and Substituent Effects, J. Phys. Chem. A, 2001, 105, 4, 710, https://doi.org/10.1021/jp002676m . [all data]

Ho, Yang, et al., 1997
Ho, Y.-P.; Yang, Y.-C.; Klippenstein, S.J.; Dunbar, R.C., Binding Energies of Ag+ and Cd+ Complexes from Analysis of Radiative Association Kinetics, J. Phys. Chem. A, 1997, 101, 18, 3338, https://doi.org/10.1021/jp9637284 . [all data]

Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W., The Bonding Strength of Ag+(C2H4) and Ag+(C2H4)2 Complexes, Chem. Phys. Lett., 1991, 181, 1, 16, https://doi.org/10.1016/0009-2614(91)90214-T . [all data]

Holland and Castleman, 1982
Holland, P.M.; Castleman, A.W., The Thermochemical Properties of Gas - Phase Transition Metal Ion Complexes, J. Chem. Phys., 1982, 76, 8, 4195, https://doi.org/10.1063/1.443497 . [all data]


Notes

Go To: Top, Ion clustering data, References