Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

NOTICE: Due to scheduled maintenance at our Gaithersburg campus, this site will not be available from 5:00 pm EDT (21:00 UTC) on Friday October 25 until 5:00 pm (21:00 UTC) on Sunday October 27. We apologize for any inconvenience this outage may cause.

Sulfur cation


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar39.109cal/mol*KReviewChase, 1998Data last reviewed in September, 1982

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Sulfur cation bullet 2F6S-) + F6S- = (Sulfur cation bullet 3F6S-)

By formula: (S+ bullet 2F6S-) + F6S- = (S+ bullet 3F6S-)

Quantity Value Units Method Reference Comment
Deltar3.0kcal/molPHPMSHiraoka, Shimizu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar11.cal/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase

(Sulfur cation bullet F6S-) + F6S- = (Sulfur cation bullet 2F6S-)

By formula: (S+ bullet F6S-) + F6S- = (S+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar3.4kcal/molPHPMSHiraoka, Shimizu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar11.cal/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase

Sulfur cation + F6S- = (Sulfur cation bullet F6S-)

By formula: S+ + F6S- = (S+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar9.4kcal/molPHPMSHiraoka, Shimizu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase

Sulfur cation + Carbon disulfide = (Sulfur cation bullet Carbon disulfide)

By formula: S+ + CS2 = (S+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar39.7kcal/molPIGress, Linn, et al., 1980gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hiraoka, Shimizu, et al., 1995
Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M. Fujimaki, Gas-Phase Stability of Cluster Ions SFm+(SF6)n with m = 0-5 and n = 1-3, J. Am. Soc. Mass Spectrom., 1995, 6, 12, 1137, https://doi.org/10.1016/1044-0305(95)00583-8 . [all data]

Gress, Linn, et al., 1980
Gress, M.E.; Linn, S.H.; Ono, Y.; Prest, H.F.; Ng, C.Y., A Study of the Chemiionization Process CS2*(n) + CS2 ---> CS3+ + CS + e- Using the Molecular Beam Photoionization Method, J. Chem. Phys., 1980, 72, 7, 4242, https://doi.org/10.1063/1.439656 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References