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Bis(trimethylsilyl)acetylene


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C8H18Si2+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
9.2PEMatsumoto, Akaiwa, et al., 1986LBLHLM
9.63PEMatsumoto, Akaiwa, et al., 1986Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C8H18Si2+9.63 ± 0.04?EIBock and Seidl, 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Matsumoto, Akaiwa, et al., 1986
Matsumoto, H.; Akaiwa, K.; Nagai, Y.; Ohno, K.; Imai, K.; Masuda, S.; Harada, Y., Analysis of stereochemical properties of molecular orbitals of (trimethylsilyl)acetylenes by penning ionization electron spectroscopy, Organometallics, 1986, 5, 1526. [all data]

Bock and Seidl, 1968
Bock, H.; Seidl, H., d-Orbital effects in siliconsubstituted «pi»-electron systems. Part XII. Some spectroscopic properties of alkyl and silyl acetylenes and polyacetylenes, J. Chem. Soc. B, 1968, 1158. [all data]


Notes

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