Cyclopentanol, 1-methyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil408.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil409.65KN/AWalling and Padwa, 1963Uncertainty assigned by TRC = 2. K; TRC
Tboil406.KN/ALutz, Bearse, et al., 1948Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Tfus306.KN/ABrown and Borkowski, 1952Uncertainty assigned by TRC = 3. K; TRC
Tfus309.KN/ALutz, Bearse, et al., 1948Uncertainty assigned by TRC = 3. K; TRC
Tfus297.8KN/AWhite and Bishop, 1940Uncertainty assigned by TRC = 0.6 K; TRC
Tfus308.65KN/ATimmermans and Hennaut-Roland, 1937Uncertainty assigned by TRC = 0.2 K; TRC
Tfus309.KN/AZelinskii and Namjetkin, 1902Uncertainty assigned by TRC = 4. K; TRC
Quantity Value Units Method Reference Comment
Deltasub66.99 ± 0.15kJ/molVBlokhin, Kabo, et al., 1997ALS
Deltasub67.0kJ/molN/ABlokhin, Kabo, et al., 1997DRB

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
45.7369.AStephenson and Malanowski, 1987Based on data from 354. - 407. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
8.41310.2Wiberg, Wasserman, et al., 1985AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Walling and Padwa, 1963
Walling, C.; Padwa, A., Positive Halogen Compounds VI. Effects of Structure and Medium on the «beta»-Scission of Alkoxy Radicals, J. Am. Chem. Soc., 1963, 85, 1593. [all data]

Lutz, Bearse, et al., 1948
Lutz, G.A.; Bearse, A.E.; Leonard, J.E.; Croxton, F.C., Studies in the Methylcyclopentane Series. I. Preparation and Reactions of Methylcyclopentyl Monochlorides, J. Am. Chem. Soc., 1948, 70, 4135-38. [all data]

Brown and Borkowski, 1952
Brown, H.C.; Borkowski, M., 1-Chloro-1-methylcycloalkanes, J. Am. Chem. Soc., 1952, 74, 1894. [all data]

White and Bishop, 1940
White, A.H.; Bishop, W.S., Dielectric Evidence of Molecular Rotation in the Crystals of Certain Non-aromatic Compounds, J. Am. Chem. Soc., 1940, 62, 8-16. [all data]

Timmermans and Hennaut-Roland, 1937
Timmermans, J.; Hennaut-Roland, M., Works from International Bureau at Physical-Chemical Standards. VIII. Physical constants of 20 organic compounds, J. Chim. Phys. Phys.-Chim. Biol., 1937, 34, 693. [all data]

Zelinskii and Namjetkin, 1902
Zelinskii, N.D.; Namjetkin, S., Synthesis of 1-Methylcyclopentanol, Ber. Dtsch. Chem. Ges., 1902, 35, 2683. [all data]

Blokhin, Kabo, et al., 1997
Blokhin, A.V.; Kabo, G.J.; Kozyro, A.A.; Ivashkevich, L.S.; Krasulin, A.P.; Diky, V.V.; Maksimuk, Yu.V., Thermodynamic properties of 1-methylcyclopentanol and 1-chloro-1-methylcyclopentane in the ideal gas state, Thermochim. Acta, 1997, 292, 19-29. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Wiberg, Wasserman, et al., 1985
Wiberg, K.B.; Wasserman, D.J.; Martin, E.J.; Murcko, M.A., Enthalpies of hydration of alkenes. 3. Cycloalkenes, J. Am. Chem. Soc., 1985, 107, 6019-6022. [all data]


Notes

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