Stannane, tetrabutyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-218.6 ± 7.4kJ/molReviewMartinho Simões 
Δfgas-216.1 ± 4.2kJ/molReviewMartinho Simões 
Δfgas-217.4 ± 4.5kJ/molReviewMartinho SimõesSelected data. Average of the values from Davies, Pope, et al., 1963 and Lautsch, Tröber, et al., 1963.
Δfgas-154. ± 17.kJ/molReviewMartinho Simões 
Δfgas-333.7kJ/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap82.8 ± 2.1kJ/molCC-SBDavies, Pope, et al., 1963MS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
67.8 ± 0.5425.Baev, 2001Based on data from 389. to 462. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
373.8 to 573.84.957522882.0446.532Umilin and Tsinovoi, 1968Coefficents calculated by NIST from author's data.

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1998.
NIST MS number 290891

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedApiezon L190.1599.Putnam and Pu, 1965Celite; Column length: 1. m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
PackedApiezon L1588.Putnam and Pu, 1965, 2Celite, 10. K/min; Column length: 3. m; Tstart: 60. C
PackedApiezon L1594.Putnam and Pu, 1965, 2Celite, 15. K/min; Column length: 3. m; Tstart: 60. C
PackedApiezon L1593.Putnam and Pu, 1965, 2Celite, 6. K/min; Column length: 3. m; Tstart: 60. C

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin, Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233 . [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Umilin and Tsinovoi, 1968
Umilin, V.A.; Tsinovoi, Y.N., Vapor Pressure of Tetrabutyltin, Zh. Fiz. Khim., 1968, 42, 2320-2322. [all data]

Putnam and Pu, 1965
Putnam, R.C.; Pu, H., Retention indices of organotins, J. Gas Chromatogr., 1965, 3, 5, 160-164, https://doi.org/10.1093/chromsci/3.5.160 . [all data]

Putnam and Pu, 1965, 2
Putnam, R.C.; Pu, H., Retention indices of organotins (II), J. Gas Chromatogr., 1965, 3, 9, 289-293, https://doi.org/10.1093/chromsci/3.9.289 . [all data]


Notes

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