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Magnesium ion (1+)


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Magnesium ion (1+) + Argon = (Magnesium ion (1+) bullet Argon)

By formula: Mg+ + Ar = (Mg+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Methyl Alcohol = (Magnesium ion (1+) bullet Methyl Alcohol)

By formula: Mg+ + CH4O = (Mg+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar34.7 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD
Deltar61. ± 5.kcal/molPDissOperti, Tews, et al., 1988gas phase; M

(Magnesium ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Magnesium ion (1+) bullet 2Methyl Alcohol)

By formula: (Mg+ bullet CH4O) + CH4O = (Mg+ bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar28.8 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 2Methyl Alcohol) + Methyl Alcohol = (Magnesium ion (1+) bullet 3Methyl Alcohol)

By formula: (Mg+ bullet 2CH4O) + CH4O = (Mg+ bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar21.9 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Methane = (Magnesium ion (1+) bullet Methane)

By formula: Mg+ + CH4 = (Mg+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Methane) + Methane = (Magnesium ion (1+) bullet 2Methane)

By formula: (Mg+ bullet CH4) + CH4 = (Mg+ bullet 2CH4)

Quantity Value Units Method Reference Comment
Deltar3.5 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Carbon monoxide = (Magnesium ion (1+) bullet Carbon monoxide)

By formula: Mg+ + CO = (Mg+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar9.9 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Magnesium ion (1+) bullet 2Carbon monoxide)

By formula: (Mg+ bullet CO) + CO = (Mg+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar9.2 ± 0.7kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Carbon dioxide = (Magnesium ion (1+) bullet Carbon dioxide)

By formula: Mg+ + CO2 = (Mg+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar13.8 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Carbon dioxide) + Carbon dioxide = (Magnesium ion (1+) bullet 2Carbon dioxide)

By formula: (Mg+ bullet CO2) + CO2 = (Mg+ bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 0.7kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 2Carbon dioxide) + Carbon dioxide = (Magnesium ion (1+) bullet 3Carbon dioxide)

By formula: (Mg+ bullet 2CO2) + CO2 = (Mg+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar10.6 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Acetaldehyde = (Magnesium ion (1+) bullet Acetaldehyde)

By formula: Mg+ + C2H4O = (Mg+ bullet C2H4O)

Quantity Value Units Method Reference Comment
Deltar63. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Ethanol = (Magnesium ion (1+) bullet Ethanol)

By formula: Mg+ + C2H6O = (Mg+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar63. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Acetone = (Magnesium ion (1+) bullet Acetone)

By formula: Mg+ + C3H6O = (Mg+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar67. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Propanal = (Magnesium ion (1+) bullet Propanal)

By formula: Mg+ + C3H6O = (Mg+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar65. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Isopropyl Alcohol = (Magnesium ion (1+) bullet Isopropyl Alcohol)

By formula: Mg+ + C3H8O = (Mg+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar65. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 1-Propanol = (Magnesium ion (1+) bullet 1-Propanol)

By formula: Mg+ + C3H8O = (Mg+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar64. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 1,3-Diazine = (Magnesium ion (1+) bullet 1,3-Diazine)

By formula: Mg+ + C4H4N2 = (Mg+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar41.5 ± 1.4kcal/molCIDTAmunugama and Rodgers, 2001RCD

Magnesium ion (1+) + Pyrrole = (Magnesium ion (1+) bullet Pyrrole)

By formula: Mg+ + C4H5N = (Mg+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar44.0kcal/molRAKGapeev and Yang, 2000RCD

Magnesium ion (1+) + 2-Butanone = (Magnesium ion (1+) bullet 2-Butanone)

By formula: Mg+ + C4H8O = (Mg+ bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar68.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(CH3OH); M

Magnesium ion (1+) + Tetrahydrofuran = (Magnesium ion (1+) bullet Tetrahydrofuran)

By formula: Mg+ + C4H8O = (Mg+ bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar66. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Butanal = (Magnesium ion (1+) bullet Butanal)

By formula: Mg+ + C4H8O = (Mg+ bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar66. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Ethyl ether = (Magnesium ion (1+) bullet Ethyl ether)

By formula: Mg+ + C4H10O = (Mg+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar66. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 1-Butanol = (Magnesium ion (1+) bullet 1-Butanol)

By formula: Mg+ + C4H10O = (Mg+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar65. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Pyridine = (Magnesium ion (1+) bullet Pyridine)

By formula: Mg+ + C5H5N = (Mg+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar47.8 ± 1.6kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Magnesium ion (1+) + Benzene = (Magnesium ion (1+) bullet Benzene)

By formula: Mg+ + C6H6 = (Mg+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar32.0 ± 2.3kcal/molCIDTAndersen, Muntean, et al., 2000RCD
Deltar37.0kcal/molRAKGapeev and Dunbar, 2000RCD

Magnesium ion (1+) + Water = (Magnesium ion (1+) bullet Water)

By formula: Mg+ + H2O = (Mg+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar28.3 ± 3.0kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.4 (+3.0,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) bullet Water) + Water = (Magnesium ion (1+) bullet 2Water)

By formula: (Mg+ bullet H2O) + H2O = (Mg+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar22.3 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
22.4 (+1.6,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) bullet 2Water) + Water = (Magnesium ion (1+) bullet 3Water)

By formula: (Mg+ bullet 2H2O) + H2O = (Mg+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar17.3 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
17.3 (+2.1,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) bullet 3Water) + Water = (Magnesium ion (1+) bullet 4Water)

By formula: (Mg+ bullet 3H2O) + H2O = (Mg+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
11.5 (+2.1,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

Magnesium ion (1+) + Ammonia = (Magnesium ion (1+) bullet Ammonia)

By formula: Mg+ + H3N = (Mg+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 2.8kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Ammonia) + Ammonia = (Magnesium ion (1+) bullet 2Ammonia)

By formula: (Mg+ bullet H3N) + H3N = (Mg+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar29.2 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 2Ammonia) + Ammonia = (Magnesium ion (1+) bullet 3Ammonia)

By formula: (Mg+ bullet 2H3N) + H3N = (Mg+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar22.8 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 3Ammonia) + Ammonia = (Magnesium ion (1+) bullet 4Ammonia)

By formula: (Mg+ bullet 3H3N) + H3N = (Mg+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar10.4 ± 2.5kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 4Ammonia) + Ammonia = (Magnesium ion (1+) bullet 5Ammonia)

By formula: (Mg+ bullet 4H3N) + H3N = (Mg+ bullet 5H3N)

Quantity Value Units Method Reference Comment
Deltar13.3 ± 2.8kcal/molCIDTAndersen, Muntean, et al., 20005th ligand is NH3; RCD

Magnesium ion (1+) + Xenon = (Magnesium ion (1+) bullet Xenon)

By formula: Mg+ + Xe = (Mg+ bullet Xe)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 2.8kcal/molCIDTAndersen, Muntean, et al., 2000RCD

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Andersen, Muntean, et al., 2000
Andersen, A.; Muntean, F.; Walter, D.; Rue, C.; Armentrout, P.B., Collision-Induced Dissociation and Theoretical Studies of Mg+ Complexes with CO, CO2, NH3, CH4, CH3OH, and C6H6, J. Phys. Chem. A, 2000, 104, 4, 692, https://doi.org/10.1021/jp993031t . [all data]

Operti, Tews, et al., 1988
Operti, L.; Tews, E.C.; Freiser, B.S., Determination of Gas-Phase Ligand Binding Energies to Mg+ by FTMS Techniques, J. Am. Chem. Soc., 1988, 110, 12, 3847, https://doi.org/10.1021/ja00220a020 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Gapeev and Dunbar, 2000
Gapeev, A.; Dunbar, R.C., Binding of Alkaline Earth Halide Ions MX+ to Benzene and Mesitylene, J. Am. Soc. Mass Spectrom., 2000, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Dalleska, Tjelta, et al., 1994
Dalleska, N.F.; Tjelta, B.L.; Armentrout, P.B., Sequential Bond Energies of Water to Na+ (3s0), Mg+ (3s1), and Al+ (3s2), J. Phys. Chem., 1994, 98, 15, 4191, https://doi.org/10.1021/j100066a045 . [all data]


Notes

Go To: Top, Ion clustering data, References