Magnesium ion (1+)
- Formula: Mg+
- Molecular weight: 24.3045
- IUPAC Standard InChI:
- InChI=1S/Mg/q+1
- Download the identifier in a file.
- IUPAC Standard InChIKey: XYAGEBWLYIDCRX-UHFFFAOYSA-N
- CAS Registry Number: 14581-92-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Magnesium cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
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Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°gas,1 bar | 36.905 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in September, 1983 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: (Mg+ 2H2O) + H2O = (Mg+
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.3 ± 2.1 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
17.3 (+2.1,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Mg+ (3s1); M |
By formula: (Mg+ 3H2O) + H2O = (Mg+
4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.5 ± 2.1 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
11.5 (+2.1,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Mg+ (3s1); M |
By formula: (Mg+ H2O) + H2O = (Mg+
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22.3 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
22.4 (+1.6,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Mg+ (3s1); M |
By formula: Mg+ + H2O = (Mg+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28.3 ± 3.0 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
28.4 (+3.0,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Mg+ (3s1); M |
By formula: Mg+ + CH4O = (Mg+ CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 34.7 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
![]() | 61. ± 5. | kcal/mol | PDiss | Operti, Tews, et al., 1988 | gas phase; M |
By formula: Mg+ + C4H8O = (Mg+ C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C3H6O = (Mg+ C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C4H8O = (Mg+ C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C4H10O = (Mg+ C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C2H6O = (Mg+ C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 63. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C3H8O = (Mg+ C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C3H6O = (Mg+ C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 67. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C3H8O = (Mg+ C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C4H10O = (Mg+ C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C2H4O = (Mg+ C2H4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 63. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C4H8O = (Mg+ C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(CH3OH); M |
By formula: Mg+ + C6H6 = (Mg+ C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32.0 ± 2.3 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
![]() | 37.0 | kcal/mol | RAK | Gapeev and Dunbar, 2000 | RCD |
By formula: (Mg+ 4H3N) + H3N = (Mg+
5H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.3 ± 2.8 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | 5th ligand is NH3; RCD |
By formula: (Mg+ 2H3N) + H3N = (Mg+
3H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22.8 ± 2.1 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ 3H3N) + H3N = (Mg+
4H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.4 ± 2.5 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ H3N) + H3N = (Mg+
2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29.2 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ 2CO2) + CO2 = (Mg+
3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.6 ± 1.4 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ CO2) + CO2 = (Mg+
2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.5 ± 0.7 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ CO) + CO = (Mg+
2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.2 ± 0.7 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ 2CH4O) + CH4O = (Mg+
3CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 21.9 ± 2.1 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ CH4O) + CH4O = (Mg+
2CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28.8 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ CH4) + CH4 = (Mg+
2CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 3.5 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + C5H5N = (Mg+ C5H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.8 ± 1.6 | kcal/mol | CIDT | Rodgers, Stanley, et al., 2000 | RCD |
By formula: Mg+ + H3N = (Mg+ H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36.8 ± 2.8 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + C4H4N2 = (Mg+ C4H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41.5 ± 1.4 | kcal/mol | CIDT | Amunugama and Rodgers, 2001 | RCD |
By formula: Mg+ + Ar = (Mg+ Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 2.3 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + Xe = (Mg+ Xe)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.4 ± 2.8 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + CO2 = (Mg+ CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.8 ± 1.4 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + CO = (Mg+ CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.9 ± 1.4 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + CH4 = (Mg+ CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + C4H5N = (Mg+ C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 44.0 | kcal/mol | RAK | Gapeev and Yang, 2000 | RCD |
Ion clustering data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: Mg+ + Ar = (Mg+ Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 2.3 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + CH4O = (Mg+ CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 34.7 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
![]() | 61. ± 5. | kcal/mol | PDiss | Operti, Tews, et al., 1988 | gas phase; M |
By formula: (Mg+ CH4O) + CH4O = (Mg+
2CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28.8 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ 2CH4O) + CH4O = (Mg+
3CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 21.9 ± 2.1 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + CH4 = (Mg+ CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ CH4) + CH4 = (Mg+
2CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 3.5 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + CO = (Mg+ CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.9 ± 1.4 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ CO) + CO = (Mg+
2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.2 ± 0.7 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + CO2 = (Mg+ CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.8 ± 1.4 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ CO2) + CO2 = (Mg+
2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.5 ± 0.7 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ 2CO2) + CO2 = (Mg+
3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.6 ± 1.4 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: Mg+ + C2H4O = (Mg+ C2H4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 63. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C2H6O = (Mg+ C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 63. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C3H6O = (Mg+ C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 67. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C3H6O = (Mg+ C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C3H8O = (Mg+ C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C3H8O = (Mg+ C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C4H4N2 = (Mg+ C4H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41.5 ± 1.4 | kcal/mol | CIDT | Amunugama and Rodgers, 2001 | RCD |
By formula: Mg+ + C4H5N = (Mg+ C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 44.0 | kcal/mol | RAK | Gapeev and Yang, 2000 | RCD |
By formula: Mg+ + C4H8O = (Mg+ C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(CH3OH); M |
By formula: Mg+ + C4H8O = (Mg+ C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C4H8O = (Mg+ C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C4H10O = (Mg+ C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C4H10O = (Mg+ C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65. ± 5. | kcal/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Mg+ + C5H5N = (Mg+ C5H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.8 ± 1.6 | kcal/mol | CIDT | Rodgers, Stanley, et al., 2000 | RCD |
By formula: Mg+ + C6H6 = (Mg+ C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32.0 ± 2.3 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
![]() | 37.0 | kcal/mol | RAK | Gapeev and Dunbar, 2000 | RCD |
By formula: Mg+ + H2O = (Mg+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28.3 ± 3.0 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
28.4 (+3.0,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Mg+ (3s1); M |
By formula: (Mg+ H2O) + H2O = (Mg+
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22.3 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
22.4 (+1.6,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Mg+ (3s1); M |
By formula: (Mg+ 2H2O) + H2O = (Mg+
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.3 ± 2.1 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
17.3 (+2.1,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Mg+ (3s1); M |
By formula: (Mg+ 3H2O) + H2O = (Mg+
4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.5 ± 2.1 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
11.5 (+2.1,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Mg+ (3s1); M |
By formula: Mg+ + H3N = (Mg+ H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36.8 ± 2.8 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ H3N) + H3N = (Mg+
2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29.2 ± 1.6 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ 2H3N) + H3N = (Mg+
3H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22.8 ± 2.1 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ 3H3N) + H3N = (Mg+
4H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.4 ± 2.5 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
By formula: (Mg+ 4H3N) + H3N = (Mg+
5H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.3 ± 2.8 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | 5th ligand is NH3; RCD |
By formula: Mg+ + Xe = (Mg+ Xe)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.4 ± 2.8 | kcal/mol | CIDT | Andersen, Muntean, et al., 2000 | RCD |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Andersen, Muntean, et al., 2000
Andersen, A.; Muntean, F.; Walter, D.; Rue, C.; Armentrout, P.B.,
Collision-Induced Dissociation and Theoretical Studies of Mg+ Complexes with CO, CO2, NH3, CH4, CH3OH, and C6H6,
J. Phys. Chem. A, 2000, 104, 4, 692, https://doi.org/10.1021/jp993031t
. [all data]
Dalleska, Tjelta, et al., 1994
Dalleska, N.F.; Tjelta, B.L.; Armentrout, P.B.,
Sequential Bond Energies of Water to Na+ (3s0), Mg+ (3s1), and Al+ (3s2),
J. Phys. Chem., 1994, 98, 15, 4191, https://doi.org/10.1021/j100066a045
. [all data]
Operti, Tews, et al., 1988
Operti, L.; Tews, E.C.; Freiser, B.S.,
Determination of Gas-Phase Ligand Binding Energies to Mg+ by FTMS Techniques,
J. Am. Chem. Soc., 1988, 110, 12, 3847, https://doi.org/10.1021/ja00220a020
. [all data]
Gapeev and Dunbar, 2000
Gapeev, A.; Dunbar, R.C.,
Binding of Alkaline Earth Halide Ions MX+ to Benzene and Mesitylene,
J. Am. Soc. Mass Spectrom., 2000, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2
. [all data]
Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R.,
Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory,
J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923
. [all data]
Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T.,
Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory,
J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i
. [all data]
Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N.,
Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results,
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Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) T Temperature rH°
Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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