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Magnesium ion (1+)


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar36.905cal/mol*KReviewChase, 1998Data last reviewed in September, 1983

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Magnesium ion (1+) bullet 2Water) + Water = (Magnesium ion (1+) bullet 3Water)

By formula: (Mg+ bullet 2H2O) + H2O = (Mg+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar17.3 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
17.3 (+2.1,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) bullet 3Water) + Water = (Magnesium ion (1+) bullet 4Water)

By formula: (Mg+ bullet 3H2O) + H2O = (Mg+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
11.5 (+2.1,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) bullet Water) + Water = (Magnesium ion (1+) bullet 2Water)

By formula: (Mg+ bullet H2O) + H2O = (Mg+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar22.3 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
22.4 (+1.6,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

Magnesium ion (1+) + Water = (Magnesium ion (1+) bullet Water)

By formula: Mg+ + H2O = (Mg+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar28.3 ± 3.0kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.4 (+3.0,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

Magnesium ion (1+) + Methyl Alcohol = (Magnesium ion (1+) bullet Methyl Alcohol)

By formula: Mg+ + CH4O = (Mg+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar34.7 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD
Deltar61. ± 5.kcal/molPDissOperti, Tews, et al., 1988gas phase; M

Magnesium ion (1+) + Tetrahydrofuran = (Magnesium ion (1+) bullet Tetrahydrofuran)

By formula: Mg+ + C4H8O = (Mg+ bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar66. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Propanal = (Magnesium ion (1+) bullet Propanal)

By formula: Mg+ + C3H6O = (Mg+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar65. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Butanal = (Magnesium ion (1+) bullet Butanal)

By formula: Mg+ + C4H8O = (Mg+ bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar66. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Ethyl ether = (Magnesium ion (1+) bullet Ethyl ether)

By formula: Mg+ + C4H10O = (Mg+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar66. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Ethanol = (Magnesium ion (1+) bullet Ethanol)

By formula: Mg+ + C2H6O = (Mg+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar63. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Isopropyl Alcohol = (Magnesium ion (1+) bullet Isopropyl Alcohol)

By formula: Mg+ + C3H8O = (Mg+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar65. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Acetone = (Magnesium ion (1+) bullet Acetone)

By formula: Mg+ + C3H6O = (Mg+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar67. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 1-Propanol = (Magnesium ion (1+) bullet 1-Propanol)

By formula: Mg+ + C3H8O = (Mg+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar64. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 1-Butanol = (Magnesium ion (1+) bullet 1-Butanol)

By formula: Mg+ + C4H10O = (Mg+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar65. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Acetaldehyde = (Magnesium ion (1+) bullet Acetaldehyde)

By formula: Mg+ + C2H4O = (Mg+ bullet C2H4O)

Quantity Value Units Method Reference Comment
Deltar63. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 2-Butanone = (Magnesium ion (1+) bullet 2-Butanone)

By formula: Mg+ + C4H8O = (Mg+ bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar68.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(CH3OH); M

Magnesium ion (1+) + Benzene = (Magnesium ion (1+) bullet Benzene)

By formula: Mg+ + C6H6 = (Mg+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar32.0 ± 2.3kcal/molCIDTAndersen, Muntean, et al., 2000RCD
Deltar37.0kcal/molRAKGapeev and Dunbar, 2000RCD

(Magnesium ion (1+) bullet 4Ammonia) + Ammonia = (Magnesium ion (1+) bullet 5Ammonia)

By formula: (Mg+ bullet 4H3N) + H3N = (Mg+ bullet 5H3N)

Quantity Value Units Method Reference Comment
Deltar13.3 ± 2.8kcal/molCIDTAndersen, Muntean, et al., 20005th ligand is NH3; RCD

(Magnesium ion (1+) bullet 2Ammonia) + Ammonia = (Magnesium ion (1+) bullet 3Ammonia)

By formula: (Mg+ bullet 2H3N) + H3N = (Mg+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar22.8 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 3Ammonia) + Ammonia = (Magnesium ion (1+) bullet 4Ammonia)

By formula: (Mg+ bullet 3H3N) + H3N = (Mg+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar10.4 ± 2.5kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Ammonia) + Ammonia = (Magnesium ion (1+) bullet 2Ammonia)

By formula: (Mg+ bullet H3N) + H3N = (Mg+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar29.2 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 2Carbon dioxide) + Carbon dioxide = (Magnesium ion (1+) bullet 3Carbon dioxide)

By formula: (Mg+ bullet 2CO2) + CO2 = (Mg+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar10.6 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Carbon dioxide) + Carbon dioxide = (Magnesium ion (1+) bullet 2Carbon dioxide)

By formula: (Mg+ bullet CO2) + CO2 = (Mg+ bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 0.7kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Magnesium ion (1+) bullet 2Carbon monoxide)

By formula: (Mg+ bullet CO) + CO = (Mg+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar9.2 ± 0.7kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 2Methyl Alcohol) + Methyl Alcohol = (Magnesium ion (1+) bullet 3Methyl Alcohol)

By formula: (Mg+ bullet 2CH4O) + CH4O = (Mg+ bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar21.9 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Magnesium ion (1+) bullet 2Methyl Alcohol)

By formula: (Mg+ bullet CH4O) + CH4O = (Mg+ bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar28.8 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Methane) + Methane = (Magnesium ion (1+) bullet 2Methane)

By formula: (Mg+ bullet CH4) + CH4 = (Mg+ bullet 2CH4)

Quantity Value Units Method Reference Comment
Deltar3.5 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Pyridine = (Magnesium ion (1+) bullet Pyridine)

By formula: Mg+ + C5H5N = (Mg+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar47.8 ± 1.6kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Magnesium ion (1+) + Ammonia = (Magnesium ion (1+) bullet Ammonia)

By formula: Mg+ + H3N = (Mg+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 2.8kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + 1,3-Diazine = (Magnesium ion (1+) bullet 1,3-Diazine)

By formula: Mg+ + C4H4N2 = (Mg+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar41.5 ± 1.4kcal/molCIDTAmunugama and Rodgers, 2001RCD

Magnesium ion (1+) + Argon = (Magnesium ion (1+) bullet Argon)

By formula: Mg+ + Ar = (Mg+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Xenon = (Magnesium ion (1+) bullet Xenon)

By formula: Mg+ + Xe = (Mg+ bullet Xe)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 2.8kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Carbon dioxide = (Magnesium ion (1+) bullet Carbon dioxide)

By formula: Mg+ + CO2 = (Mg+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar13.8 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Carbon monoxide = (Magnesium ion (1+) bullet Carbon monoxide)

By formula: Mg+ + CO = (Mg+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar9.9 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Methane = (Magnesium ion (1+) bullet Methane)

By formula: Mg+ + CH4 = (Mg+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Pyrrole = (Magnesium ion (1+) bullet Pyrrole)

By formula: Mg+ + C4H5N = (Mg+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar44.0kcal/molRAKGapeev and Yang, 2000RCD

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Magnesium ion (1+) + Argon = (Magnesium ion (1+) bullet Argon)

By formula: Mg+ + Ar = (Mg+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Methyl Alcohol = (Magnesium ion (1+) bullet Methyl Alcohol)

By formula: Mg+ + CH4O = (Mg+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar34.7 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD
Deltar61. ± 5.kcal/molPDissOperti, Tews, et al., 1988gas phase; M

(Magnesium ion (1+) bullet Methyl Alcohol) + Methyl Alcohol = (Magnesium ion (1+) bullet 2Methyl Alcohol)

By formula: (Mg+ bullet CH4O) + CH4O = (Mg+ bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar28.8 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 2Methyl Alcohol) + Methyl Alcohol = (Magnesium ion (1+) bullet 3Methyl Alcohol)

By formula: (Mg+ bullet 2CH4O) + CH4O = (Mg+ bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar21.9 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Methane = (Magnesium ion (1+) bullet Methane)

By formula: Mg+ + CH4 = (Mg+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Methane) + Methane = (Magnesium ion (1+) bullet 2Methane)

By formula: (Mg+ bullet CH4) + CH4 = (Mg+ bullet 2CH4)

Quantity Value Units Method Reference Comment
Deltar3.5 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Carbon monoxide = (Magnesium ion (1+) bullet Carbon monoxide)

By formula: Mg+ + CO = (Mg+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar9.9 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Magnesium ion (1+) bullet 2Carbon monoxide)

By formula: (Mg+ bullet CO) + CO = (Mg+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar9.2 ± 0.7kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Carbon dioxide = (Magnesium ion (1+) bullet Carbon dioxide)

By formula: Mg+ + CO2 = (Mg+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar13.8 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Carbon dioxide) + Carbon dioxide = (Magnesium ion (1+) bullet 2Carbon dioxide)

By formula: (Mg+ bullet CO2) + CO2 = (Mg+ bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 0.7kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 2Carbon dioxide) + Carbon dioxide = (Magnesium ion (1+) bullet 3Carbon dioxide)

By formula: (Mg+ bullet 2CO2) + CO2 = (Mg+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar10.6 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Acetaldehyde = (Magnesium ion (1+) bullet Acetaldehyde)

By formula: Mg+ + C2H4O = (Mg+ bullet C2H4O)

Quantity Value Units Method Reference Comment
Deltar63. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Ethanol = (Magnesium ion (1+) bullet Ethanol)

By formula: Mg+ + C2H6O = (Mg+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar63. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Acetone = (Magnesium ion (1+) bullet Acetone)

By formula: Mg+ + C3H6O = (Mg+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar67. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Propanal = (Magnesium ion (1+) bullet Propanal)

By formula: Mg+ + C3H6O = (Mg+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar65. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Isopropyl Alcohol = (Magnesium ion (1+) bullet Isopropyl Alcohol)

By formula: Mg+ + C3H8O = (Mg+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar65. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 1-Propanol = (Magnesium ion (1+) bullet 1-Propanol)

By formula: Mg+ + C3H8O = (Mg+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar64. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 1,3-Diazine = (Magnesium ion (1+) bullet 1,3-Diazine)

By formula: Mg+ + C4H4N2 = (Mg+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar41.5 ± 1.4kcal/molCIDTAmunugama and Rodgers, 2001RCD

Magnesium ion (1+) + Pyrrole = (Magnesium ion (1+) bullet Pyrrole)

By formula: Mg+ + C4H5N = (Mg+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar44.0kcal/molRAKGapeev and Yang, 2000RCD

Magnesium ion (1+) + 2-Butanone = (Magnesium ion (1+) bullet 2-Butanone)

By formula: Mg+ + C4H8O = (Mg+ bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar68.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(CH3OH); M

Magnesium ion (1+) + Tetrahydrofuran = (Magnesium ion (1+) bullet Tetrahydrofuran)

By formula: Mg+ + C4H8O = (Mg+ bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar66. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Butanal = (Magnesium ion (1+) bullet Butanal)

By formula: Mg+ + C4H8O = (Mg+ bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar66. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Ethyl ether = (Magnesium ion (1+) bullet Ethyl ether)

By formula: Mg+ + C4H10O = (Mg+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar66. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 1-Butanol = (Magnesium ion (1+) bullet 1-Butanol)

By formula: Mg+ + C4H10O = (Mg+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar65. ± 5.kcal/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Pyridine = (Magnesium ion (1+) bullet Pyridine)

By formula: Mg+ + C5H5N = (Mg+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar47.8 ± 1.6kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Magnesium ion (1+) + Benzene = (Magnesium ion (1+) bullet Benzene)

By formula: Mg+ + C6H6 = (Mg+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar32.0 ± 2.3kcal/molCIDTAndersen, Muntean, et al., 2000RCD
Deltar37.0kcal/molRAKGapeev and Dunbar, 2000RCD

Magnesium ion (1+) + Water = (Magnesium ion (1+) bullet Water)

By formula: Mg+ + H2O = (Mg+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar28.3 ± 3.0kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.4 (+3.0,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) bullet Water) + Water = (Magnesium ion (1+) bullet 2Water)

By formula: (Mg+ bullet H2O) + H2O = (Mg+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar22.3 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
22.4 (+1.6,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) bullet 2Water) + Water = (Magnesium ion (1+) bullet 3Water)

By formula: (Mg+ bullet 2H2O) + H2O = (Mg+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar17.3 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
17.3 (+2.1,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) bullet 3Water) + Water = (Magnesium ion (1+) bullet 4Water)

By formula: (Mg+ bullet 3H2O) + H2O = (Mg+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
11.5 (+2.1,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

Magnesium ion (1+) + Ammonia = (Magnesium ion (1+) bullet Ammonia)

By formula: Mg+ + H3N = (Mg+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 2.8kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet Ammonia) + Ammonia = (Magnesium ion (1+) bullet 2Ammonia)

By formula: (Mg+ bullet H3N) + H3N = (Mg+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar29.2 ± 1.6kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 2Ammonia) + Ammonia = (Magnesium ion (1+) bullet 3Ammonia)

By formula: (Mg+ bullet 2H3N) + H3N = (Mg+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar22.8 ± 2.1kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 3Ammonia) + Ammonia = (Magnesium ion (1+) bullet 4Ammonia)

By formula: (Mg+ bullet 3H3N) + H3N = (Mg+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar10.4 ± 2.5kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) bullet 4Ammonia) + Ammonia = (Magnesium ion (1+) bullet 5Ammonia)

By formula: (Mg+ bullet 4H3N) + H3N = (Mg+ bullet 5H3N)

Quantity Value Units Method Reference Comment
Deltar13.3 ± 2.8kcal/molCIDTAndersen, Muntean, et al., 20005th ligand is NH3; RCD

Magnesium ion (1+) + Xenon = (Magnesium ion (1+) bullet Xenon)

By formula: Mg+ + Xe = (Mg+ bullet Xe)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 2.8kcal/molCIDTAndersen, Muntean, et al., 2000RCD

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Andersen, Muntean, et al., 2000
Andersen, A.; Muntean, F.; Walter, D.; Rue, C.; Armentrout, P.B., Collision-Induced Dissociation and Theoretical Studies of Mg+ Complexes with CO, CO2, NH3, CH4, CH3OH, and C6H6, J. Phys. Chem. A, 2000, 104, 4, 692, https://doi.org/10.1021/jp993031t . [all data]

Dalleska, Tjelta, et al., 1994
Dalleska, N.F.; Tjelta, B.L.; Armentrout, P.B., Sequential Bond Energies of Water to Na+ (3s0), Mg+ (3s1), and Al+ (3s2), J. Phys. Chem., 1994, 98, 15, 4191, https://doi.org/10.1021/j100066a045 . [all data]

Operti, Tews, et al., 1988
Operti, L.; Tews, E.C.; Freiser, B.S., Determination of Gas-Phase Ligand Binding Energies to Mg+ by FTMS Techniques, J. Am. Chem. Soc., 1988, 110, 12, 3847, https://doi.org/10.1021/ja00220a020 . [all data]

Gapeev and Dunbar, 2000
Gapeev, A.; Dunbar, R.C., Binding of Alkaline Earth Halide Ions MX+ to Benzene and Mesitylene, J. Am. Soc. Mass Spectrom., 2000, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References