Manganese pentacarbonyl bromide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.97 ± 0.03EIJunk, Svec, et al., 1968RDSH
8.83 ± 0.05PEHigginson, Lloyd, et al., 1975Vertical value; LLK
8.86PELichtenberger, Sarapu, et al., 1973Vertical value; LLK
8.76PEEvans, Green, et al., 1969Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
MnBr+12.45COEIJunk, Svec, et al., 1968RDSH
COBrMn+11.724COEIJunk, Svec, et al., 1968RDSH
MnCO+15.13?EIJunk, Svec, et al., 1968RDSH
C2O2BrMn+10.473COEIJunk, Svec, et al., 1968RDSH
C3O3BrMn+9.552COEIJunk, Svec, et al., 1968RDSH
MnC3O3+9.9?EIJunk, Svec, et al., 1968RDSH
Mn+16.5?EIJunk, Svec, et al., 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Junk, Svec, et al., 1968
Junk, G.A.; Svec, H.J.; Angelici, R.J., Electron impact studies of manganese and rhenium pentacarbonyl halides, J. Am. Chem. Soc., 1968, 90, 5758. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Lichtenberger, Sarapu, et al., 1973
Lichtenberger, D.L.; Sarapu, A.C.; Fenske, R.F., Photoelectron spectra and electronic structure of pentacarbonylmanganese halides, Inorg. Chem., 1973, 12, 702. [all data]

Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W., Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]


Notes

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