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H2PF


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 PH2 s-stretch 2283.12 gas IR Beckers, 1993
Beckers, Burger, et al., 1994
Beckers, Burger, et al., 1995
1 PH2 s-stretch 2304 Ar IR Andrews and Withnall, 1989
2 PH2 deform. 1109.24 gas IR Beckers, 1993
Beckers, Burger, et al., 1994
2 PH2 deform. 1090 Ar IR Andrews and Withnall, 1989
3 PH2 deform. 976.50 gas IR Beckers, Burger, et al., 1994
3 PH2 deform. 934 Ar IR Andrews and Withnall, 1989
4 PF stretch 807.36 gas IR Beckers, 1993
Beckers, Burger, et al., 1994
4 PF stretch 795 vs Ar IR Andrews and Withnall, 1989
a 5 PH2 a-stretch 2286.97 gas IR Beckers, 1993
Beckers, Burger, et al., 1994
Beckers, Burger, et al., 1995
5 PH2 a-stretch 2310 Ar IR Andrews and Withnall, 1989

Additional references: Jacox, 1994, page 153; Jacox, 1998, page 228; Drean, Paplewski, et al., 1996

Notes

vsVery strong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Beckers, 1993
Beckers, H., Gasphasenreaktionen von H3PF2: Darstellung der Monohalogenphosphane H2PF und H2PCl, Z. Anorg. Allg. Chem., 1993, 619, 11, 1880, https://doi.org/10.1002/zaac.19936191111 . [all data]

Beckers, Burger, et al., 1994
Beckers, H.; Burger, H.; Kuna, R.; Paplewski, M.; Thiel, W., Ab initio calculations on monohalogenophosphanes PH2X (X=F,Cl,Br,I), and experimental detection and characterization of PH2F and PH2Cl by high resolution infrared spectroscopy, J. Chem. Phys., 1994, 101, 7, 5585, https://doi.org/10.1063/1.468460 . [all data]

Beckers, Burger, et al., 1995
Beckers, H.; Burger, H.; Paplewski, M., High-Resolution FTIR Study of the PH Stretching Bands «nu»1 and «nu»5 of PH2F and PH2Cl, J. Mol. Spectrosc., 1995, 171, 2, 546, https://doi.org/10.1006/jmsp.1995.1141 . [all data]

Andrews and Withnall, 1989
Andrews, L.; Withnall, R., Cocondensation reaction between phosphine and fluorine: matrix infrared spectra of difluorophosphorane, difluorophosphine and fluorophosphine, Inorg. Chem., 1989, 28, 3, 494, https://doi.org/10.1021/ic00302a023 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Drean, Paplewski, et al., 1996
Drean, P.; Paplewski, M.; Demaison, J.; Breidung, J.; Thiel, W.; Beckers, H.; Burger, H., Millimeter-Wave Spectra,, Inorg. Chem., 1996, 35, 26, 7671, https://doi.org/10.1021/ic960546f . [all data]


Notes

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