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Trimethylgermane


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
~10.0PEDrake, Glavincevski, et al., 1979LLK
10.93PEDrake, Glavincevski, et al., 1979Vertical value; LLK

De-protonation reactions

C3H9Ge- + Hydrogen cation = C3H10Ge

By formula: C3H9Ge- + H+ = C3H10Ge

Quantity Value Units Method Reference Comment
Deltar368.7 ± 2.1kcal/molD-EABrinkman, Salomon, et al., 1995gas phase; D-EA cycle implies BDE(Me3Ge-H) = 80.2; B
Deltar361.9 ± 3.1kcal/molG+TSBrinkman, Salomon, et al., 1995gas phase; Acidity between mF- and oF-aniline.; B
Quantity Value Units Method Reference Comment
Deltar361.4 ± 2.2kcal/molH-TSBrinkman, Salomon, et al., 1995gas phase; D-EA cycle implies BDE(Me3Ge-H) = 80.2; B
Deltar354.6 ± 3.0kcal/molIMRBBrinkman, Salomon, et al., 1995gas phase; Acidity between mF- and oF-aniline.; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Drake, Glavincevski, et al., 1979
Drake, J.E.; Glavincevski, B.M.; Gorzelska, K., The photoelectron spectra of trimethylgermane, chloro- and fluoro-trimethylgermane, J. Electron Spectrosc. Relat. Phenom., 1979, 16, 331. [all data]

Brinkman, Salomon, et al., 1995
Brinkman, E.A.; Salomon, K.; Tumas, W.; Brauman, J.I., Electron affinities and gas-phase acidities of organogermanium and organotin compounds, J. Am. Chem. Soc., 1995, 117, 17, 4905, https://doi.org/10.1021/ja00122a022 . [all data]


Notes

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