H3SiOH


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

H3OSi- + Hydrogen cation = H4OSi

By formula: H3OSi- + H+ = H4OSi

Quantity Value Units Method Reference Comment
Δr358.4 ± 4.3kcal/molG+TSDamrauer, Simon, et al., 1991gas phase; Between CF3CH2OH, MeNO2
Quantity Value Units Method Reference Comment
Δr352.0 ± 4.2kcal/molIMRBDamrauer, Simon, et al., 1991gas phase; Between CF3CH2OH, MeNO2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Si-O stretch 859 Ar IR Withnall and Andrews, 1985

Additional references: Jacox, 1994, page 311


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M., Effect of Substituents on the Gas-Phase Acidity of Silanols, J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009 . [all data]

Withnall and Andrews, 1985
Withnall, R.; Andrews, L., Matrix reactions of silane and oxygen atoms. Infrared spectroscopic evidence for the silanol, silanone, and silanoic and silicic acid molecules, J. Phys. Chem., 1985, 89, 15, 3261, https://doi.org/10.1021/j100261a019 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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