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Boron hydride sulfide


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 BH stretch 2735.80 gas IR Maki and Sams, 1975
1 BH stretch 2724 Ar IR Carpenter and Ault, 1992
3 BS stretch 1172.39 gas IR Turner and Mills, 1982
3 BS stretch 1168 Ar IR Carpenter and Ault, 1992

Additional references: Jacox, 1994, page 35; Pearson and McCormick, 1973; Bizzocchi, Degli Esposti, et al., 2002; Bizzocchi and Degli Esposti, 2007; Bizzocchi, Degli Esposti, et al., 2008


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maki and Sams, 1975
Maki, A.G.; Sams, R.L., High-resolution infrared measurements of v1 and force field calculations for thioborine (HBS), J. Mol. Struct., 1975, 26, 1, 107, https://doi.org/10.1016/0022-2860(75)80071-8 . [all data]

Carpenter and Ault, 1992
Carpenter, J.D.; Ault, B.S., Matrix isolation study of the reaction of diborane with hydrogen sulfide: spectroscopic characterization of mercaptoborane, H2BSH, J. Phys. Chem., 1992, 96, 20, 7913, https://doi.org/10.1021/j100199a018 . [all data]

Turner and Mills, 1982
Turner, P.; Mills, I.M., The infrared spectrum, equilibrium structure and harmonic and anharmonic force field of thioborine, HBS, Mol. Phys., 1982, 46, 1, 161, https://doi.org/10.1080/00268978200101151 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Pearson and McCormick, 1973
Pearson, E.F.; McCormick, V., Rotational spectrum and structure of thioborine: HBS, J. Chem. Phys., 1973, 58, 4, 1619, https://doi.org/10.1063/1.1679403 . [all data]

Bizzocchi, Degli Esposti, et al., 2002
Bizzocchi, L.; Degli Esposti, C.; Dore, L., Rotational Spectroscopy of HB33S: The Quadrupole Coupling Constant of 33S in Thioborine, J. Mol. Spectrosc., 2002, 215, 2, 228, https://doi.org/10.1006/jmsp.2002.8649 . [all data]

Bizzocchi and Degli Esposti, 2007
Bizzocchi, L.; Degli Esposti, C., Millimeter- and submillimeter-wave spectroscopy of HBS and DBS in vibrationally excited states, J. Mol. Spectrosc., 2007, 241, 1, 67, https://doi.org/10.1016/j.jms.2006.11.002 . [all data]

Bizzocchi, Degli Esposti, et al., 2008
Bizzocchi, L.; Degli Esposti, D.; Dore, L., Sub-Doppler millimetre-wave spectroscopy of DBS and HBS: accurate values of nuclear electric and magnetic hyperfine structure constants, Phys. Chem. Chem. Phys., 2008, 10, 5, 658, https://doi.org/10.1039/b710356e . [all data]


Notes

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