Aluminum, tris(1,1,1-trifluoro-2,4-pentanedionato-O,O')-

• Formula: C₁₅H₁₂AlF₉O₆
• Molecular weight: 486.2193
• IUPAC Standard InChI: InChI=1S/3C5H5F3O2.Al/c3*1-3(9)2-4(10)5(6,7)8;/h3*2,9H,1H3;/q;;;+3/p-3/b3-2+;2*3-2-; Copy

  
• IUPAC Standard InChIKey: NSAWTIQLFWITEH-PJFPACTGSA-K Copy
• CAS Registry Number: 14354-59-7
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Aluminum trifluoroacetylacetonate; Aluminum tris(trifluoroacetylacetonate); Aluminum, tris(1,1,1-trifluoro-2,4-pentanedionato)-; Tris(1,1,1-trifluoro-2,4-pentanedionato)aluminum
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Phase change data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
• Options:
  • Switch to calorie-based units

Phase change data

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Enthalpy of sublimation

Mass spectrum (electron ionization)

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

For Zoom

1.) Enter the desired X axis range (e.g., 100, 200)

2.) Check here for automatic Y scaling

3.) Press here to zoom

Additional Data

References

Go To: Top, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lazarev, Greenberg, et al., 1988
Lazarev, V.B.; Greenberg, J.H.; Ozerova, Z.P.; Sharpataya, G.A., DSC and vapour pressure investigation of some β-diketonates, Journal of Thermal Analysis, 1988, 33, 3, 797-799, https://doi.org/10.1007/BF02138589 . [all data]

Igumenov, Chumachenko, et al., 1978
Igumenov, I.K.; Chumachenko, Yu.V.; Zemskov, S.V., Saturated vapor pressure of aluminum, gallium, and indium tris(trifluoroacetylacetonates), Zh. Fiz. Khim., 1978, 52, 10, 2664. [all data]

Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R., Substituent effects on the volatility of metal ?-diketonates, Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M . [all data]

Matsubara and Kuwamoto, 1985
Matsubara, Norio; Kuwamoto, Tooru, Vapor pressures and enthalpies of sublimation and evaporation of trifluoroacetylacetonates in helium and helium containing the ligand vapor, Inorg. Chem., 1985, 24, 17, 2697-2701, https://doi.org/10.1021/ic00211a022 . [all data]

Volkov, Mazurenko, et al., 1978
Volkov, S.V.; Mazurenko, E.A.; Bublik, Z.N., Effect of the nature of substituents in β-diketonates on their thermodynamic characteristics, Str., Svoistva Primen. β [Beta]-Diketonatov Met., [Mater. Vses. Semin.], 3rd, V.I. Spitsyn, ed(s)., 1978, 119-122. [all data]

Fontaine, Pommier, et al., 1972
Fontaine, R.; Pommier, C.; Guiochon, G., Bull. Soc. Chim. Fr., 1972, 8, 3011. [all data]

Notes

Go To: Top, Phase change data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  ΔsubH	Enthalpy of sublimation
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.