Aluminum, tris(1,1,1-trifluoro-2,4-pentanedionato-O,O')-


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
14.0 ± 0.2380.BGLazarev, Greenberg, et al., 1988Based on data from 349. to 411. K.
16.6 ± 0.1438.N/AIgumenov, Chumachenko, et al., 1978Based on data from 392. to 484. K.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
17.7373. to 403.TGAFahlman and Barron, 2000 
27.10 ± 0.31363. to 423.GSMatsubara and Kuwamoto, 1985 
24.55 ± 0.76369. to 392.N/AIgumenov, Chumachenko, et al., 1978 
10.3443.N/AVolkov, Mazurenko, et al., 1978 
22.4 ± 1.6375.N/AFontaine, Pommier, et al., 1972Based on data from 354. to 396. K.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lazarev, Greenberg, et al., 1988
Lazarev, V.B.; Greenberg, J.H.; Ozerova, Z.P.; Sharpataya, G.A., DSC and vapour pressure investigation of some β-diketonates, Journal of Thermal Analysis, 1988, 33, 3, 797-799, https://doi.org/10.1007/BF02138589 . [all data]

Igumenov, Chumachenko, et al., 1978
Igumenov, I.K.; Chumachenko, Yu.V.; Zemskov, S.V., Saturated vapor pressure of aluminum, gallium, and indium tris(trifluoroacetylacetonates), Zh. Fiz. Khim., 1978, 52, 10, 2664. [all data]

Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R., Substituent effects on the volatility of metal ?-diketonates, Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M . [all data]

Matsubara and Kuwamoto, 1985
Matsubara, Norio; Kuwamoto, Tooru, Vapor pressures and enthalpies of sublimation and evaporation of trifluoroacetylacetonates in helium and helium containing the ligand vapor, Inorg. Chem., 1985, 24, 17, 2697-2701, https://doi.org/10.1021/ic00211a022 . [all data]

Volkov, Mazurenko, et al., 1978
Volkov, S.V.; Mazurenko, E.A.; Bublik, Z.N., Effect of the nature of substituents in β-diketonates on their thermodynamic characteristics, Str., Svoistva Primen. β [Beta]-Diketonatov Met., [Mater. Vses. Semin.], 3rd, V.I. Spitsyn, ed(s)., 1978, 119-122. [all data]

Fontaine, Pommier, et al., 1972
Fontaine, R.; Pommier, C.; Guiochon, G., Bull. Soc. Chim. Fr., 1972, 8, 3011. [all data]


Notes

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