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hexatetracontafluorohexatetracontahydro[5,6]fullerene (C60F46)

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
3.33 ± 0.10LPESWang, Chi, et al., 2010Reverse Coulombic barrier estimated as 1.0±0.1 eV
3.20 ± 0.10LPESIoffe, Avdoshenko, et al., 2005 
4.06 ± 0.25IMRBHettich, Jin, et al., 1994EA between NO3-, CF3CO2-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Chi, et al., 2010
Wang, X.B.; Chi, C.X.; Zhou, M.F.; Kuvychko, I.V.; Seppelt, K.; Popov, A.A.; Strauss, S.H.; Boltalina, O.V.; Wang, L.S., Photoelectron Spectroscopy of C60Fn- and C60Fm2- (n=17, 33, 35, 43, 45, 47; m=34, 46) in the Gas Phase and the Generation and Characterization of C-1-C60F47- and D-2-C60F44 in Solution, J. Phys. Chem. A, 2010, 114, 4, 1756-1765, https://doi.org/10.1021/jp9097364 . [all data]

Ioffe, Avdoshenko, et al., 2005
Ioffe, I.N.; Avdoshenko, S.M.; Boltalina, O.V.; Sidorov, L.N.; Berndt, K.; Weber, J.M., Mass spectrometry, photoelectron spectroscopy, and quantum chemical studies of fluorofullerene dianions, Int. J. Mass Spectrom., 2005, 243, 3, 223-230, https://doi.org/10.1016/j.ijms.2005.03.005 . [all data]

Hettich, Jin, et al., 1994
Hettich, R.; Jin, C.M.; Compton, R., Determination of the electron affinities of fluorinated fullerenes (C60F44,46, C70F52,54) by Fourier transform mass spectrometry, Int. J. Mass Spectrom. Ion Proc., 1994, 138, 263, https://doi.org/10.1016/0168-1176(94)04059-1 . [all data]


Notes

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