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Oxygen anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

O- + Carbon dioxide = (O- bullet Carbon dioxide)

By formula: O- + CO2 = (O- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar48. ± 10.kcal/molAVGN/AAverage of 8 out of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar48.0 ± 5.0kcal/molIMREAdams and Bohme, 1970gas phase; O3- + CO2 <=> CO3- + O2; B

O- + Water = (O- bullet Water)

By formula: O- + H2O = (O- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar26.5 ± 1.8kcal/molPDisDeyerl, Clements, et al., 2001gas phase; B
Deltar0.52kcal/molN/AArnold, Xu, et al., 1995gas phase; Vertical Detachment Energy: 1.45 eV. Affinity is difference between EA of O-. and HOH..O-.; B
Deltar30.0kcal/molPDissRoehl, Snodgrass, et al., 1991gas phase; «DELTA»rH<; M
Deltar30.kcal/molFAFehsenfeld and Ferguson, 1974gas phase; bracketing, «DELTA»rH<; M

O- + Hydrogen cation = Hydroxyl radical

By formula: O- + H+ = HO

Quantity Value Units Method Reference Comment
Deltar382.600 ± 0.010kcal/molD-EANeumark, Lykke, et al., 1985gas phase; Given: 1.461122(3) eV; revised to 1.4611107(17) eV, 95BLO, based on missing term+86CODATA; B
Quantity Value Units Method Reference Comment
Deltar376.73 ± 0.15kcal/molH-TSNeumark, Lykke, et al., 1985gas phase; Given: 1.461122(3) eV; revised to 1.4611107(17) eV, 95BLO, based on missing term+86CODATA; B

O- + Oxygen = (O- bullet Oxygen)

By formula: O- + O2 = (O- bullet O2)

Quantity Value Units Method Reference Comment
Deltar32.kcal/molPDissHiller and Vestal, 1981gas phase; From thermochemical cycle, «DELTA»rH<; M
Deltar39.0kcal/molPESNovich, Engelking, et al., 1979gas phase; From thermochemical cycle, from EA(O3), D(O-O2) AND EA(O); M
Deltar38.kcal/molPDissCosby, Moseley, et al., 1978gas phase; M
Deltar42.kcal/molCIDLifschitz, Wu, et al., 1978gas phase; M

(O- bullet 2Nitrous oxide) + Nitrous oxide = (O- bullet 3Nitrous oxide)

By formula: (O- bullet 2N2O) + N2O = (O- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar5.40 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar-0.9 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- bullet 3Nitrous oxide) + Nitrous oxide = (O- bullet 4Nitrous oxide)

By formula: (O- bullet 3N2O) + N2O = (O- bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar5.20 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.0 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- bullet 4Nitrous oxide) + Nitrous oxide = (O- bullet 5Nitrous oxide)

By formula: (O- bullet 4N2O) + N2O = (O- bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar5.20 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- bullet 5Nitrous oxide) + Nitrous oxide = (O- bullet 6Nitrous oxide)

By formula: (O- bullet 5N2O) + N2O = (O- bullet 6N2O)

Quantity Value Units Method Reference Comment
Deltar5.10 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.7 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- bullet 6Nitrous oxide) + Nitrous oxide = (O- bullet 7Nitrous oxide)

By formula: (O- bullet 6N2O) + N2O = (O- bullet 7N2O)

Quantity Value Units Method Reference Comment
Deltar5.10 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar28.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar-3.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- bullet Nitrous oxide) + Nitrous oxide = (O- bullet 2Nitrous oxide)

By formula: (O- bullet N2O) + N2O = (O- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar5.40 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar-0.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- bullet 10Argon) + Argon = (O- bullet 11Argon)

By formula: (O- bullet 10Ar) + Ar = (O- bullet 11Ar)

Quantity Value Units Method Reference Comment
Deltar0.4 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 11Argon) + Argon = (O- bullet 12Argon)

By formula: (O- bullet 11Ar) + Ar = (O- bullet 12Ar)

Quantity Value Units Method Reference Comment
Deltar0.8 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 12Argon) + Argon = (O- bullet 13Argon)

By formula: (O- bullet 12Ar) + Ar = (O- bullet 13Ar)

Quantity Value Units Method Reference Comment
Deltar0.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 13Argon) + Argon = (O- bullet 14Argon)

By formula: (O- bullet 13Ar) + Ar = (O- bullet 14Ar)

Quantity Value Units Method Reference Comment
Deltar0.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 14Argon) + Argon = (O- bullet 15Argon)

By formula: (O- bullet 14Ar) + Ar = (O- bullet 15Ar)

Quantity Value Units Method Reference Comment
Deltar0.4 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 15Argon) + Argon = (O- bullet 16Argon)

By formula: (O- bullet 15Ar) + Ar = (O- bullet 16Ar)

Quantity Value Units Method Reference Comment
Deltar0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 16Argon) + Argon = (O- bullet 17Argon)

By formula: (O- bullet 16Ar) + Ar = (O- bullet 17Ar)

Quantity Value Units Method Reference Comment
Deltar0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 17Argon) + Argon = (O- bullet 18Argon)

By formula: (O- bullet 17Ar) + Ar = (O- bullet 18Ar)

Quantity Value Units Method Reference Comment
Deltar0.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 18Argon) + Argon = (O- bullet 19Argon)

By formula: (O- bullet 18Ar) + Ar = (O- bullet 19Ar)

Quantity Value Units Method Reference Comment
Deltar0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 19Argon) + Argon = (O- bullet 20Argon)

By formula: (O- bullet 19Ar) + Ar = (O- bullet 20Ar)

Quantity Value Units Method Reference Comment
Deltar0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 20Argon) + Argon = (O- bullet 21Argon)

By formula: (O- bullet 20Ar) + Ar = (O- bullet 21Ar)

Quantity Value Units Method Reference Comment
Deltar0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 21Argon) + Argon = (O- bullet 22Argon)

By formula: (O- bullet 21Ar) + Ar = (O- bullet 22Ar)

Quantity Value Units Method Reference Comment
Deltar0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 22Argon) + Argon = (O- bullet 23Argon)

By formula: (O- bullet 22Ar) + Ar = (O- bullet 23Ar)

Quantity Value Units Method Reference Comment
Deltar0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 23Argon) + Argon = (O- bullet 24Argon)

By formula: (O- bullet 23Ar) + Ar = (O- bullet 24Ar)

Quantity Value Units Method Reference Comment
Deltar0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 24Argon) + Argon = (O- bullet 25Argon)

By formula: (O- bullet 24Ar) + Ar = (O- bullet 25Ar)

Quantity Value Units Method Reference Comment
Deltar0.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 25Argon) + Argon = (O- bullet 26Argon)

By formula: (O- bullet 25Ar) + Ar = (O- bullet 26Ar)

Quantity Value Units Method Reference Comment
Deltar0.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 9Argon) + Argon = (O- bullet 10Argon)

By formula: (O- bullet 9Ar) + Ar = (O- bullet 10Ar)

Quantity Value Units Method Reference Comment
Deltar0.7 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 2Argon) + Argon = (O- bullet 3Argon)

By formula: (O- bullet 2Ar) + Ar = (O- bullet 3Ar)

Quantity Value Units Method Reference Comment
Deltar1.6 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 3Argon) + Argon = (O- bullet 4Argon)

By formula: (O- bullet 3Ar) + Ar = (O- bullet 4Ar)

Quantity Value Units Method Reference Comment
Deltar1.4 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 4Argon) + Argon = (O- bullet 5Argon)

By formula: (O- bullet 4Ar) + Ar = (O- bullet 5Ar)

Quantity Value Units Method Reference Comment
Deltar1.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 5Argon) + Argon = (O- bullet 6Argon)

By formula: (O- bullet 5Ar) + Ar = (O- bullet 6Ar)

Quantity Value Units Method Reference Comment
Deltar1.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 6Argon) + Argon = (O- bullet 7Argon)

By formula: (O- bullet 6Ar) + Ar = (O- bullet 7Ar)

Quantity Value Units Method Reference Comment
Deltar1.0 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 7Argon) + Argon = (O- bullet 8Argon)

By formula: (O- bullet 7Ar) + Ar = (O- bullet 8Ar)

Quantity Value Units Method Reference Comment
Deltar0.9 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet 8Argon) + Argon = (O- bullet 9Argon)

By formula: (O- bullet 8Ar) + Ar = (O- bullet 9Ar)

Quantity Value Units Method Reference Comment
Deltar0.9 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet Argon) + Argon = (O- bullet 2Argon)

By formula: (O- bullet Ar) + Ar = (O- bullet 2Ar)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

O- + Argon = (O- bullet Argon)

By formula: O- + Ar = (O- bullet Ar)

Quantity Value Units Method Reference Comment
Deltar2.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- bullet Sulfur dioxide) + Sulfur dioxide = (O- bullet 2Sulfur dioxide)

By formula: (O- bullet O2S) + O2S = (O- bullet 2O2S)

Quantity Value Units Method Reference Comment
Deltar13.3kcal/molHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.9cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M

(O- bullet Carbon dioxide) + Carbon dioxide = (O- bullet 2Carbon dioxide)

By formula: (O- bullet CO2) + CO2 = (O- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar7.1kcal/molHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M

O- + Sulfur dioxide = (O- bullet Sulfur dioxide)

By formula: O- + O2S = (O- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar60.kcal/molFAFehsenfeld and Ferguson, 1974gas phase; switching reaction(O-)CO2, «DELTA»rH>; Hiller and Vestal, 1980, Keesee and Castleman, 1986; M

(O- bullet Water) + Carbon dioxide = (O- bullet Carbon dioxide bullet Water)

By formula: (O- bullet H2O) + CO2 = (O- bullet CO2 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar36.4kcal/molPDissRoehl, Snodgrass, et al., 1991gas phase; «DELTA»rH>; M

O- + Deuterium oxide = D2O2-

By formula: O- + D2O = D2O2-

Quantity Value Units Method Reference Comment
Deltar24.2 ± 1.8kcal/molPDisDeyerl, Clements, et al., 2001gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Adams and Bohme, 1970
Adams, N.G.; Bohme, D., Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O2+, O2-, and O-, J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449 . [all data]

Deyerl, Clements, et al., 2001
Deyerl, H.J.; Clements, T.G.; Luong, A.K.; Continetti, R.E., Transition state dynamics of the OH+OH - O+H2O reaction studied by dissociative photodetachment of H2O2-, J. Chem. Phys., 2001, 115, 15, 6931-6940, https://doi.org/10.1063/1.1404148 . [all data]

Arnold, Xu, et al., 1995
Arnold, D.W.; Xu, C.S.; Neumark, D.M., Spectroscopy of the transition state: Elementary reactions of the hydroxyl radical studied by photoelectron spectroscopy of O-(H2O) and H3O2, J. Chem. Phys., 1995, 102, 15, 6088, https://doi.org/10.1063/1.469343 . [all data]

Roehl, Snodgrass, et al., 1991
Roehl, C.M.; Snodgrass, J.T.; Deakyne, C.A.; Bowers, M.T., Photodissociation of CO3-.H2O: Observation of the O-.H2O + CO2 Product Channel, J. Chem. Phys., 1991, 94, 10, 6546, https://doi.org/10.1063/1.460281 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Neumark, Lykke, et al., 1985
Neumark, D.M.; Lykke, K.R.; Andersen, T.; Lineberger, W.C., Laser photodetachment measurement of the electron affinity of atomic oxygen, Phys. Rev. A:, 1985, 32, 1890. [all data]

Hiller and Vestal, 1981
Hiller, J.F.; Vestal, M.L., Laser Photodissociation of O3- by Triple Quadrupole Mass Spectrometry, J. Chem. Phys., 1981, 74, 11, 6096, https://doi.org/10.1063/1.441053 . [all data]

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O3-, J. Chem. Phys., 1979, 70, 2652. [all data]

Cosby, Moseley, et al., 1978
Cosby, P.C.; Moseley, J.T.; Peterson, J.R.; Ling, J.H., Photodissociation spectroscopy of O3, J. Chem. Phys., 1978, 69, 2771. [all data]

Lifschitz, Wu, et al., 1978
Lifschitz, C.; Wu, R.L.C.; Tiernan, T.O.; Terwillinger, D.T., Negative Ion - Molecule Reactions of Ozone and Their Implications on the Thermochemistry of O3-, J. Chem. Phys., 1978, 68, 1, 247, https://doi.org/10.1063/1.435489 . [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Gas-phase clustering reactions of O2(-), NO-, and O- with N2O: Isomeric structures for (NO-N2O)(-), J. Phys. Chem., 1994, 98, 34, 8295, https://doi.org/10.1021/j100085a006 . [all data]

Arnold, Hendricks, et al., 1995
Arnold, S.T.; Hendricks, J.H.; Bowen, K.H., Photoelectron spectroscopy of the solvated anion clusters O-(Ar)(n=1-26,34): Energetics and structure, J. Chem. Phys., 1995, 102, 1, 39, https://doi.org/10.1063/1.469415 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Hiller and Vestal, 1980
Hiller, J.F.; Vestal, M.L., Tandem quadrupole study of laser photodissociation of CO3-, J. Chem. Phys., 1980, 72, 4713. [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]


Notes

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