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Carbon anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Carbon anion + Hydrogen cation = Methylidyne

By formula: C- + H+ = CH

Quantity Value Units Method Reference Comment
Deltar1529.4 ± 0.71kJ/molD-EAScheer, Bilodeau, et al., 1998gas phase; Given: 1.262119(20) eV; B
Quantity Value Units Method Reference Comment
Deltar1506.2 ± 1.1kJ/molH-TSScheer, Bilodeau, et al., 1998gas phase; Given: 1.262119(20) eV; B

(Carbon anion bullet 2carbon) + carbon = (Carbon anion bullet 3carbon)

By formula: (C- bullet 2C) + C = (C- bullet 3C)

Quantity Value Units Method Reference Comment
Deltar703. ± 8.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 3carbon) + carbon = (Carbon anion bullet 4carbon)

By formula: (C- bullet 3C) + C = (C- bullet 4C)

Quantity Value Units Method Reference Comment
Deltar630. ± 20.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet carbon) + carbon = (Carbon anion bullet 2carbon)

By formula: (C- bullet C) + C = (C- bullet 2C)

Quantity Value Units Method Reference Comment
Deltar628. ± 8.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 4carbon) + carbon = (Carbon anion bullet 5carbon)

By formula: (C- bullet 4C) + C = (C- bullet 5C)

Quantity Value Units Method Reference Comment
Deltar715.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 5carbon) + carbon = (Carbon anion bullet 6carbon)

By formula: (C- bullet 5C) + C = (C- bullet 6C)

Quantity Value Units Method Reference Comment
Deltar649.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 6carbon) + carbon = (Carbon anion bullet 7carbon)

By formula: (C- bullet 6C) + C = (C- bullet 7C)

Quantity Value Units Method Reference Comment
Deltar686.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 7carbon) + carbon = (Carbon anion bullet 8carbon)

By formula: (C- bullet 7C) + C = (C- bullet 8C)

Quantity Value Units Method Reference Comment
Deltar657.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

(Carbon anion bullet 8carbon) + carbon = (Carbon anion bullet 9carbon)

By formula: (C- bullet 8C) + C = (C- bullet 9C)

Quantity Value Units Method Reference Comment
Deltar665.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

Carbon anion + carbon = (Carbon anion bullet carbon)

By formula: C- + C = (C- bullet C)

Quantity Value Units Method Reference Comment
Deltar812. ± 8.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Scheer, Bilodeau, et al., 1998
Scheer, M.; Bilodeau, R.C.; Brodie, C.A.; Haugen, H.K., Systematic study of the stable states of C-, Si-, Ge-, and Sn- via infrared laser spectroscopy, Phys. Rev. A, 1998, 58, 4, 2844-2856, https://doi.org/10.1103/PhysRevA.58.2844 . [all data]

Pargellis, 1990
Pargellis, A.N., Estimating Carbon Cluster Binding Energies from Measured Cn Distributions, n <= 10, J. Chem. Phys., 1990, 93, 3, 2099, https://doi.org/10.1063/1.459035 . [all data]


Notes

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