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Scandium ion (1+)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Scandium ion (1+) + Ethylene = (Scandium ion (1+) bullet Ethylene)

By formula: Sc+ + C2H4 = (Sc+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar52. ± 3.kcal/molPDissRanashinge and Freiser, 1992gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
31.3 CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH >=, guided ion beam CID; M

Scandium ion (1+) + Acetylene = (Scandium ion (1+) bullet Acetylene)

By formula: Sc+ + C2H2 = (Sc+ bullet C2H2)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
57.4 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Scandium ion (1+) + Water = (Scandium ion (1+) bullet Water)

By formula: Sc+ + H2O = (Sc+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar31. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M

Scandium ion (1+) + Methylene = (Scandium ion (1+) bullet Methylene)

By formula: Sc+ + CH2 = (Sc+ bullet CH2)

Quantity Value Units Method Reference Comment
Deltar98.3 ± 5.3kcal/molCIDTSunderlin and Armentrout, 1989RCD

Scandium ion (1+) + Pyridine = (Scandium ion (1+) bullet Pyridine)

By formula: Sc+ + C5H5N = (Sc+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar55.3 ± 2.5kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) bullet Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar31.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Scandium ion (1+) + 1,3-Diazine = (Scandium ion (1+) bullet 1,3-Diazine)

By formula: Sc+ + C4H4N2 = (Sc+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar51.2 ± 2.2kcal/molCIDTAmunugama and Rodgers, 2001RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ranashinge and Freiser, 1992
Ranashinge, Y.A.; Freiser, B.S., Gas-Phase Photodissociation of MC2H2+ (M = Sc, Y, La). Determination of D0(M+ - C2H2), Chem. Phys. Let., 1992, 200, 1-2, 135, https://doi.org/10.1016/0009-2614(92)87058-W . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Sunderlin and Armentrout, 1989
Sunderlin, L.S.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with Methane and Ethane, J. Am. Chem. Soc., 1989, 111, 11, 3845, https://doi.org/10.1021/ja00193a015 . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]


Notes

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