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Nickel hydride (NiH)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman

Electron affinity determinations

EA (eV) Method Reference Comment
0.4810 ± 0.0070LPESMiller, Feigerle, et al., 1987B

Ionization energy determinations

IE (eV) Method Reference Comment
8.50 ± 0.10END/DERKickel and Armentrout, 1995LL
8.40 ± 0.12END/DERArmentrout and Kicket, 1995LL
<=9.0DERLias, Bartmess, et al., 1988LL

De-protonation reactions

Ni- + Hydrogen cation = HNi

By formula: Ni- + H+ = HNi

Quantity Value Units Method Reference Comment
Deltar1452. ± 7.9kJ/molD-EAScheer, Brodie, et al., 1998gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Feigerle, et al., 1987
Miller, A.E.S.; Feigerle, C.S.; Lineberger, W.C., Laser photoelectron spectroscopy of CrH-, CoH-, and NiH-: Periodic trends in the electronic structure of the transition-metal hydrides, J. Chem. Phys., 1987, 86, 1549. [all data]

Kickel and Armentrout, 1995
Kickel, B.L.; Armentrout, P.B., Reactions of Fe+, Co+, and Ni+ with silane. Electronic state effects, comparison to reactions with methane, and M+-SiHx (x = 0-3) bond energies, J. Am. Chem. Soc., 1995, 117, 764. [all data]

Armentrout and Kicket, 1995
Armentrout, P.B.; Kicket, B.L., Reactions of Fe+, Co+, and Ni+ with silane. Electronic state effects, comparison to reactions with methane, and M+-SiHx (x = 0-3) bond energies, J. Am. Chem. Soc., 1995, 117, 764. [all data]

Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G., Gas-phase ion and neutral thermochemistry, J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]

Scheer, Brodie, et al., 1998
Scheer, M.; Brodie, C.A.; Bilodeau, R.C.; Haugen, H.K., Laser spectroscopic measurements of binding energies and fine-structure splittings of Co-, Ni-, Rh-, and Pd-, Phys. Rev. A, 1998, 58, 3, 2051-2062, https://doi.org/10.1103/PhysRevA.58.2051 . [all data]


Notes

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