bis(1,1,1-trifluoropentane-2,4-dionato-O,O')copper
- Formula: C10H8CuF6O4
- Molecular weight: 369.705
- CAS Registry Number: 14324-82-4
- Information on this page:
- Other data available:
- Options:
Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 27.70 ± 0.57 | kcal/mol | N/A | Ribeiro da Silva, 1995 | |
| ΔsubH° | 27.96 ± 0.38 | kcal/mol | N/A | Ribeiro da Silva, 1995 | |
| ΔsubH° | 26.8 ± 0.72 | kcal/mol | C | Ribeiro da Silva and Ferrão, 1988 |
Enthalpy of sublimation
| ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 26.8 | 373. - 403. | TGA | Fahlman and Barron, 2000 | |
| 27.08 ± 0.57 | 350. | TE | Ribeiro da Silva, 1995 | Based on data from 342. - 359. K. |
| 27.34 ± 0.38 | 350. | ME | Ribeiro da Silva, 1995 | Based on data from 342. - 359. K. |
| 26.3 ± 0.2 | 383. - 463. | GS | Matsubara and Kuwamoto, 1985 |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ribeiro da Silva, 1995
Ribeiro da Silva, M.,
Vapour pressures and standard molar enthalpies of sublimation of seven crystalline copper(II) β-diketonates. The mean molar (Cu-O) bond-dissociation enthalpies,
The Journal of Chemical Thermodynamics, 1995, 27, 2, 175-190, https://doi.org/10.1006/jcht.1995.0014
. [all data]
Ribeiro da Silva and Ferrão, 1988
Ribeiro da Silva, Manuel A.V.; Ferrão, Maria Luisa C.C.H.,
Standard enthalpies of formation of bis(trifluoroacetylacetonato)copper(II) and bis(hexafluoroacetylacetonato)copper(II): the mean (Cu«58872»O) bond-dissociation enthalpies,
The Journal of Chemical Thermodynamics, 1988, 20, 3, 359-361, https://doi.org/10.1016/0021-9614(88)90132-2
. [all data]
Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R.,
Substituent effects on the volatility of metal ?-diketonates,
Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M
. [all data]
Matsubara and Kuwamoto, 1985
Matsubara, Norio; Kuwamoto, Tooru,
Vapor pressures and enthalpies of sublimation and evaporation of trifluoroacetylacetonates in helium and helium containing the ligand vapor,
Inorg. Chem., 1985, 24, 17, 2697-2701, https://doi.org/10.1021/ic00211a022
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.