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Silane,(4-chlorophenyl)dimethyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C7H8SiCl+8.84CH3EIDube and Chvalovsky, 1974LLK

De-protonation reactions

C8H10ClSi- + Hydrogen cation = C8H11ClSi

By formula: C8H10ClSi- + H+ = C8H11ClSi

Quantity Value Units Method Reference Comment
Deltar1576. ± 9.2kJ/molG+TSIrie, Kikukawa, et al., 2001gas phase; The anion may be ArSiH(Me)CH2-, based on LFER size and ab initio calculations - JEB; B
Quantity Value Units Method Reference Comment
Deltar1544. ± 8.4kJ/molIMREIrie, Kikukawa, et al., 2001gas phase; The anion may be ArSiH(Me)CH2-, based on LFER size and ab initio calculations - JEB; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dube and Chvalovsky, 1974
Dube, G.; Chvalovsky, V., Electron impact fragmentation of substituted phenyldimethylsilanes, Collect. Czech. Chem. Commun., 1974, 39, 2621. [all data]

Irie, Kikukawa, et al., 2001
Irie, M.; Kikukawa, K.; Shimizu, N.; Mishima, M., Gas-phase acidities of aryldimethylsilanes, J. Chem. Soc. Perkin Trans., 2001, 2, 6, 923-928, https://doi.org/10.1039/b100488n . [all data]


Notes

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