Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)aluminum

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference
21.413. - 443.TGAFahlman and Barron, 2000

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference
10.9 ± 0.5EIMcDonald and Margrave, 1968

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C22H38O4Al+13.6 ± 0.5?EIMcDonald and Margrave, 1968 
C29H48O6Al+12.2 ± 0.5C4H9EIMcDonald and Margrave, 1968 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R., Substituent effects on the volatility of metal ?-diketonates, Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M . [all data]

McDonald and Margrave, 1968
McDonald, J.D.; Margrave, J.L., Mass-spectrometric studies of volatile Al, Sc, Co, Y, Zr and rare-earth chelates, J. Less-Common Metals, 1968, 14, 236. [all data]


Notes

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