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n-Butyl ether

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-334. ± 2.kJ/molCcbColomina, Pell, et al., 1965 
Deltafgas-334.kJ/molCcbMurrin and Goldhagen, 1957 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-378.0 ± 1.0kJ/molCcbColomina, Pell, et al., 1965ALS
Deltafliquid-377.6 ± 2.8kJ/molCcbMurrin and Goldhagen, 1957ALS
Quantity Value Units Method Reference Comment
Deltacliquid-5342.63 ± 0.92kJ/molCcbColomina, Pell, et al., 1965Corresponding «DELTA»fliquid = -377.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-5343.1 ± 2.8kJ/molCcbMurrin and Goldhagen, 1957Corresponding «DELTA»fliquid = -377.4 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-5343.4 ± 3.3kJ/molCcbSkuratov, Strepikheev, et al., 1957Reanalyzed by Cox and Pilcher, 1970, Original value = -5345. ± 3. kJ/mol; Combustion at 293 K; Corresponding «DELTA»fliquid = -377.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
278.16298.15Cobos, Casanova, et al., 1987Average of two measurements.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH6N+ + n-Butyl ether = (CH6N+ bullet n-Butyl ether)

By formula: CH6N+ + C8H18O = (CH6N+ bullet C8H18O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar105.kJ/molPHPMSMeot-Ner, 1984gas phase
Deltar105.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar117.J/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar117.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Colomina, Pell, et al., 1965
Colomina, M.; Pell, A.S.; Skinner, H.A.; Coleman, D.J., Heats of combustion of four dialkylethers, Trans. Faraday Soc., 1965, 61, 2641. [all data]

Murrin and Goldhagen, 1957
Murrin, J.W.; Goldhagen, S., Determination of the C-O bond energy from the heats of combustion of four aliphatic ethers, NAVORD Report No. 5491, U.S. Naval Powder Factory Res. & Dev. Dept., 1957, 1-14. [all data]

Skuratov, Strepikheev, et al., 1957
Skuratov, S.M.; Strepikheev, A.A.; Kozina, M.P., About the reaction activity of five and six-membered heterocyclic compounds, Dokl. Akad. Nauk SSSR, 1957, 117, 452-454. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Cobos, Casanova, et al., 1987
Cobos, J.C.; Casanova, C.; Roux-Desgranges, G.; Grolier, J.-P.E., Excess properties of mixtures of some n-alkoxyethanols with organic solvents. II. VEm and CEp,m with di-n-butylether at 298.15 K, J. Chem. Thermodynam., 1987, 19, 791-796. [all data]

Meot-Ner, 1984
Meot-Ner, (Mautner)M., The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects, J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015 . [all data]

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]


Notes

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