Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Dirhenium decacarbonyl


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-1557.1 ± 9.1kJ/molReviewMartinho Simões 
Deltafgas-1544.1 ± 6.4kJ/molReviewMartinho Simões 
Deltafgas-1556.7 ± 3.9kJ/molReviewMartinho Simões 
Deltafgas-1560. ± 14.kJ/molReviewMartinho Simões 
Deltafgas-1554.4 ± 7.3kJ/molReviewMartinho SimõesSelected data. Average of the values from Chernova, Sheiman, et al., 1973, Connor, Skinner, et al., 1973, and Al-Takhin, Connor, et al., 1983

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid-1658.0 ± 8.9kJ/molReviewMartinho Simões 
Deltafsolid-1645.0 ± 6.1kJ/molReviewMartinho Simões 
Deltafsolid-1657.6 ± 3.4kJ/molReviewMartinho Simões 
Deltafsolid-1661. ± 14.kJ/molReviewMartinho Simões 
Deltafsolid-1655.3 ± 7.0kJ/molReviewMartinho SimõesSelected data. Average of the values from Chernova, Sheiman, et al., 1973, Connor, Skinner, et al., 1973, and Al-Takhin, Connor, et al., 1983
Quantity Value Units Method Reference Comment
Deltacsolid-3589.5 ± 2.5kJ/molCC-SBChernova, Sheiman, et al., 1973Please also see Tel'noi and Rabinovich, 1977.

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub101. ± 2.kJ/molCC-SBAl-Takhin, Connor, et al., 1983Another literature value for the enthalpy of sublimation has been reported: 93.3 ± 4.2 kJ/mol Brown, Connor, et al., 1974 Baev, Dem'yanchuk, et al., 1971 Lemoine, Gross, et al., 1975; MS
Deltasub101. ± 2.kJ/molN/AAl-Takhin, Connor, et al., 1983, 2AC
Deltasub93.3 ± 4.2kJ/molN/APilcher and Skinner, 1983See also Lalage, Brown, et al., 1974.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
68.7468.Baev, Dem'yanchuk, et al., 1971Based on data from 454. - 483. K.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
77.6406.MMBaev, Dem'yanchuk, et al., 1971Based on data from 363. - 450. K.; AC

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Dimanganese decacarbonyl (solution) + Dirhenium decacarbonyl (solution) = 2C10MnO10Re (solution)

By formula: C10Mn2O10 (solution) + C10O10Re2 (solution) = 2C10MnO10Re (solution)

Quantity Value Units Method Reference Comment
Deltar121. ± 31.kJ/molPCHarel and Adamson, 1986solvent: Cyclohexane; The reaction enthalpy was calculated from the enthalpies of the following reactions: Mn2(CO)10(solution) + I2(solution) = 2Mn(CO)5(I)(solution), -187.9 ± 8.4 kJ/mol, Re2(CO)10(solution) + I2(solution) = 2Re(CO)5(I)(solution), -157. ± 16. kJ/mol, and MnRe(CO)10(solution) + I2(solution) = Mn(CO)5(I)(solution) + Re(CO)5(I)(solution), -233. ± 13. kJ/mol
Deltar34.4 ± 1.3kJ/molEqSMarcomini and Poë, 1984solvent: Decalin; Temperature range: 443-463 K

Dirhenium decacarbonyl (solution) = 2C5O5Re (solution)

By formula: C10O10Re2 (solution) = 2C5O5Re (solution)

Quantity Value Units Method Reference Comment
Deltar>166.kJ/molKinSMarcomini and Poë, 1984solvent: Decalin; Please also see Poë, 1981. The reaction enthalpy was derived from the enthalpy of activation, 165.5 ± 0.8 kJ/mol Poë, 1981, by assuming a negligible barrier for the radical recombination. This procedure was later considered to yield a low limit of the reaction enthalpy Poë, 1983 Marcomini and Poë, 1984 Marcomini and Poë, 1983 Coville, Stolzenberg, et al., 1983. See also Schmidt, Trogler, et al., 1984

Dirhenium decacarbonyl (cr) + Iodine (cr) = 2Rhenium, pentacarbonyliodo- (cr)

By formula: C10O10Re2 (cr) + I2 (cr) = 2C5IO5Re (cr)

Quantity Value Units Method Reference Comment
Deltar-172. ± 18.kJ/molPCHarel and Adamson, 1986The reaction enthalpy was calculated from the enthalpy of the same reaction in cyclohexane, -157. ± 16. kJ/mol, and from the solution enthalpies of Re2(CO)10(cr), 34.3 ± 2.1 kJ/mol, I2(cr), 20.5 ± 0.4 kJ/mol, and Re(CO)5(I)(cr), 34.7 ± 4.2 kJ/mol Harel and Adamson, 1986

Dirhenium decacarbonyl (solution) + Iodine (solution) = 2Rhenium, pentacarbonyliodo- (solution)

By formula: C10O10Re2 (solution) + I2 (solution) = 2C5IO5Re (solution)

Quantity Value Units Method Reference Comment
Deltar-157. ± 16.kJ/molPCHarel and Adamson, 1986solvent: Cyclohexane; Please also see Adamson, Vogler, et al., 1978.

Dirhenium decacarbonyl (cr) = 10Carbon monoxide (g) + 2rhenium (cr)

By formula: C10O10Re2 (cr) = 10CO (g) + 2Re (cr)

Quantity Value Units Method Reference Comment
Deltar539.7 ± 5.9kJ/molTD-HFCConnor, Skinner, et al., 1973 
Deltar552.3 ± 3.0kJ/molHAL-HFCConnor, Skinner, et al., 1973 

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 154911

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Chernova, Sheiman, et al., 1973
Chernova, V.I.; Sheiman, M.S.; Rabinovich, I.B.; Syrkin, V.G., Trudy Khim. Khim. Tekhnol., Gorky, 1973, No. 2, 43. [all data]

Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y., High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir, Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018 . [all data]

Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A., J. Organomet. Chem., 1983, 259, 313. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E., Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]

Lemoine, Gross, et al., 1975
Lemoine, P.; Gross, M.; Bousquet, J.; Letoffe, J.M.; Diot, M., J. Chem. Thermodyn., 1975, 7, 913. [all data]

Al-Takhin, Connor, et al., 1983, 2
Al-Takhin, Ghassan; Connor, Joseph A.; Skinner, Henry A., Enthalpies of formation of decacarbonyldirhenium and some pentacarbonylrhenium derivatives, Journal of Organometallic Chemistry, 1983, 259, 3, 313-320, https://doi.org/10.1016/0022-328X(83)87182-4 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Lalage, Brown, et al., 1974
Lalage, D.; Brown, S.; Connor, Joseph A.; Skinner, Henry A., The enthalpies of formation of CH3Mn(CO)5 and of CH3Re(CO)5, and the strengths of the CH3«58872»Mn and CH3«58872»Re bonds, Journal of Organometallic Chemistry, 1974, 81, 3, 403-409, https://doi.org/10.1016/S0022-328X(00)88209-1 . [all data]

Harel and Adamson, 1986
Harel, Y.; Adamson, A.W., J. Phys. Chem., 1986, 90, 6693. [all data]

Marcomini and Poë, 1984
Marcomini, A.; Poë, A., J. Chem. Soc., Dalton Trans., 1984, 95.. [all data]

Poë, 1981
Poë, A., ACS Symp. Ser., 1981, No. 155, 135. [all data]

Poë, 1983
Poë, A., Chem. Brit., 1983, 19, 997. [all data]

Marcomini and Poë, 1983
Marcomini, A.; Poë, A., J. Am. Chem. Soc., 1983, 105, 6952. [all data]

Coville, Stolzenberg, et al., 1983
Coville, N.J.; Stolzenberg, A.M.; Muetterties, E.L., J. Am. Chem. Soc., 1983, 105, 2499. [all data]

Schmidt, Trogler, et al., 1984
Schmidt, S.P.; Trogler, W.C.; Basolo, F., J. Am. Chem. Soc., 1984, 106, 1308. [all data]

Adamson, Vogler, et al., 1978
Adamson, A.W.; Vogler, A.; Kunkely, H.; Wachter, R., J. Am. Chem. Soc., 1978, 100, 1298. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References