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Dirhenium decacarbonyl


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.49 ± 0.02EIMichels and Svec, 1981LLK
8.36 ± 0.03EIJunk and Svec, 1970RDSH
8.07PEHigginson, Lloyd, et al., 1975Vertical value; LLK
8.86PEHall, 1975Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CORe2+26.269COEISvec and Junk, 1967RDSH
C2O2Re2+23.558COEISvec and Junk, 1967RDSH
C3O3Re2+21.467COEISvec and Junk, 1967RDSH
C4O4Re+13.30?EISvec and Junk, 1967RDSH
C4O4Re2+19.316COEISvec and Junk, 1967RDSH
C5O5Re+10.34?EIJunk and Svec, 1970RDSH
C5O5Re2+16.715COEISvec and Junk, 1967RDSH
C6O6Re2+15.014COEISvec and Junk, 1967RDSH
C7O7Re2+13.553COEISvec and Junk, 1967RDSH
C8O8Re2+10.892COEISvec and Junk, 1967RDSH
C9O9Re2+9.57COEISvec and Junk, 1967RDSH
Re+37.55?EISvec and Junk, 1967RDSH
Re2+28.9610COEISvec and Junk, 1967RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Michels and Svec, 1981
Michels, G.D.; Svec, H.J., Characterization of MnTc(CO)10 and TcRe(CO)10, Inorg. Chem., 1981, 20, 3445. [all data]

Junk and Svec, 1970
Junk, G.A.; Svec, H.J., The mass spectra, ionization potentials, and bond energies of the group VIIA decacarbonyls, J. Chem. Soc. A, 1970, 2102. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Hall, 1975
Hall, M.B., The use of spin-orbit coupling in the interpretation of photoelectron spectra. I. Application to substituted rhenium pentacarbonyls, J. Am. Chem. Soc., 1975, 97, 2057. [all data]

Svec and Junk, 1967
Svec, H.J.; Junk, G.A., Energetics of the ionization and dissociation of Mn2(CO)10, Re2(CO)10, and ReMn(CO)10, J. Am. Chem. Soc., 1967, 89, 2836. [all data]


Notes

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