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Ruthenium, tris(2,4-pentanedionato)-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
1.756 ± 0.065IMRBSharpe, Alameddin, et al., 1994Revised version of Sharpe, Eyler, et al., 1990. EA is actually «DELTA»Gattachment at 350K
1.674 ± 0.022IMRESharpe, Eyler, et al., 1990EA given is actually -«DELTA»Gea(350 K)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sharpe, Alameddin, et al., 1994
Sharpe, P.; Alameddin, N.G.; Richardson, D.E., Alkyl Substituent Effects in the Redox Thermochemistry of Coordination Compounds: Oxidation and Reduction Energetics for Ruthenium tris(b-diketonate) Complexes, J. Am. Chem. Soc., 1994, 116, 24, 11098, https://doi.org/10.1021/ja00103a027 . [all data]

Sharpe, Eyler, et al., 1990
Sharpe, P.; Eyler, J.R.; Richardson, D.E., Free Energies of Electron Attachment to Tris(acetylacetonate) and Tris(hexafluoroacetylacetonate) Transition-Metal Complexes in the Gas Phase: Experimental Results and Ligand Field Analysis, Inorg. Chem., 1990, 29, 15, 2779, https://doi.org/10.1021/ic00340a014 . [all data]


Notes

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