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Hexanoic acid

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-581.8 ± 1.1kJ/molCcbFenwick, Harrop, et al., 1978ALS
Deltafliquid-583.58 ± 0.75kJ/molCcbAdriaanse, Dekker, et al., 1965Heat of formation derived by Cox and Pilcher, 1970; ALS
Deltafliquid-585.68 ± 0.54kJ/molCcbLebedeva, 1964ALS
Quantity Value Units Method Reference Comment
Deltacliquid-3494.29 ± 0.66kJ/molCcbFenwick, Harrop, et al., 1978Corresponding «DELTA»fliquid = -581.75 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3492.4 ± 0.6kJ/molCcbAdriaanse, Dekker, et al., 1965Corresponding «DELTA»fliquid = -583.6 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3490.4 ± 0.54kJ/molCcbLebedeva, 1964Corresponding «DELTA»fliquid = -585.63 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3518.kJ/molCcbFischer and Wrede, 1904Heat of combustion corrected for pressure; Corresponding «DELTA»fliquid = -558.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
Deltacsolid-3522.8kJ/molCcbLemoult, 1904Corresponding «DELTA»fsolid = -553.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
225.1298.von Reis, 1881T = 292 to 483 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fenwick, Harrop, et al., 1978
Fenwick, J.O.; Harrop, D.; Head, A.J., Thermodynamic properties of organic oxygen compounds. 46. Enthalpies of formation of ethyl acetate and 1-hexanoix acid, J. Chem. Thermodyn., 1978, 10, 687-690. [all data]

Adriaanse, Dekker, et al., 1965
Adriaanse, N.; Dekker, H.; Coops, J., Heats of combustion of normal saturated fatty acids and their methyl esters, Rec. Trav. Chim. Pays/Bas, 1965, 84, 393-407. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Lebedeva, 1964
Lebedeva, N.D., Heats of combustion of monocarboxylic acids, Russ. J. Phys. Chem. (Engl. Transl.), 1964, 38, 1435-1437. [all data]

Fischer and Wrede, 1904
Fischer, E.; Wrede, F., Uber die Verbrennungswarme einiger organischer Verbindungen, Sitzungsber. Dtsch. Akad. Wiss. Berlin Kl. Math. Phys. Tech., 1904, 687-715. [all data]

Lemoult, 1904
Lemoult, M.P., Remarques sur une serie recenie de determinations calorimetriques, Compt. Rend., 1904, 663-635. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]


Notes

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