Cyclopentene

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Normal alkane RI, non-polar column, custom temperature program

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualanePONAMethyl SiliconeDB-5 MS
Column length (m)   100. 30.
Carrier gas     Helium
Substrate      
Column diameter (mm)     0.25
Phase thickness (μm)   0.50 1.0
Program not specifiednot specifiednot specifiednot specifiednot specified
I 558.560.557.581.569.
ReferenceChen, 2008Chen, 2008Perkin Elmer Instruments, 2002N/ALuo and Agnew, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryPacked
Active phase Methyl SiliconeMethyl SiliconeDB-1OV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.SE-30
Column length (m)   60.50.6.1
Carrier gas    HydrogenN2
Substrate     Chromosorb W
Column diameter (mm)   0.320.32 
Phase thickness (μm)   0.25  
Program not specifiednot specifiednot specifiednot specified50C910min) => 20C/min => 90(6min) => 10C/min => 150C(hold)
I 555.554.540.558.555.
ReferenceZenkevich, 2000Spieksma, 1999Ciccioli, Cecinato, et al., 1994Waggott and Davies, 1984Robinson and Odell, 1971
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPacked
Active phase SqualaneSE-30Squalane
Column length (m) 3.06.13.0
Carrier gas N2  
Substrate EmbacelChrom WEmbacel
Column diameter (mm)    
Phase thickness (μm)    
Program 25C(5min) => 2C/min => 35 => 4C/min => 95C(hold)50C(10min) => 20C/min(2min) => 90C(6min) => 10C/min(6min) => (hold at 150C)25C(5min) => 2C/min(5min) => 4C/min(15min) => (hold at 95C)
I 547.555.547.
ReferenceRobinson and Odell, 1971Robinson and Odell, 1971, 2Robinson and Odell, 1971, 2
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chen, 2008
Chen, H.-F., Quantitative prediction of gas chromatography retention indices with support vector machines, radial basis neutral networks and multiple linear regression, Anal. Chim. Acta, 2008, 609, 1, 24-36, https://doi.org/10.1016/j.aca.2008.01.003 . [all data]

Perkin Elmer Instruments, 2002
Perkin Elmer Instruments, Detailed hydrocarbon analysis (DHAX) Model 4015, 2002, retrieved from http://www.perkinelmer.com/instruments. [all data]

Luo and Agnew, 2001
Luo, J.; Agnew, M.P., Gas characteristics before and after biofiltration treating odorous emissions from animal rendering processes, Environ. Technol., 2001, 22, 9, 1091-1103, https://doi.org/10.1080/09593332208618220 . [all data]

Zenkevich, 2000
Zenkevich, I.G., Mutual Correlation between Gas Chromatographic Retention Indices of Unsaturated and Saturated Hydrocarbons found by Molecular Dynamics, Z. Anal. Chem., 2000, 55, 10, 1091-1097. [all data]

Spieksma, 1999
Spieksma, W., Determination of vapor liquid equilibrium from the Kovats retention index on dimethylsilicone using the Wilson mixing tool, J. Hi. Res. Chromatogr., 1999, 22, 10, 565-588, https://doi.org/10.1002/(SICI)1521-4168(19991001)22:10<565::AID-JHRC565>3.0.CO;2-2 . [all data]

Ciccioli, Cecinato, et al., 1994
Ciccioli, P.; Cecinato, A.; Brancaleoni, E.; Brachetti, A.; Frattoni, M.; Sparapani, R., Composition and Distribution of Polar and Non-Polar VOCs in Urban, Rural, Forest and Remote Areas, Eur Commission EUR, 1994, 549-568. [all data]

Waggott and Davies, 1984
Waggott, A.; Davies, I.W., Identification of organic pollutants using linear temperature programmed retention indices (LTPRIs) - Part II, 1984, retrieved from http://dwi.defra.gov.uk/research/completed-research/reports/dwi0383.pdf. [all data]

Robinson and Odell, 1971
Robinson, P.G.; Odell, A.L., A system of standard retention indices and its uses. The characterisation of stationary phases and the prediction of retention indices, J. Chromatogr., 1971, 57, 1-10, https://doi.org/10.1016/0021-9673(71)80001-8 . [all data]

Robinson and Odell, 1971, 2
Robinson, P.G.; Odell, A.L., Comparison of isothermal and non-linear temperature programmed gas chromatography. The temperature dependence of the retention indices of a number of hydrocarbons on squalane and SE-30, J. Chromatogr., 1971, 57, 11-17, https://doi.org/10.1016/0021-9673(71)80002-X . [all data]


Notes

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