bromopentacarbonylrhenium


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-204.9 ± 1.8kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-226.9 ± 1.7kcal/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub22.0 ± 0.5kcal/molHAL-HFCAl-Takhin, Connor, et al., 1983 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.07 ± 0.02EIJunk, Svec, et al., 1968RDSH
8.83PEHigginson, Lloyd, et al., 1975Vertical value; LLK
8.80PEHall, 1975Vertical value; LLK
8.86PECeasar, Milazzo, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ReBr+19.515COEIJunk, Svec, et al., 1968RDSH
COBrRe+16.944COEIJunk, Svec, et al., 1968RDSH
C2O2BrRe+15.023COEIJunk, Svec, et al., 1968RDSH
C3O3BrRe+11.972COEIJunk, Svec, et al., 1968RDSH
C3O3Re+15.51?EIJunk, Svec, et al., 1968RDSH
C4O4BrRe+10.50COEIJunk, Svec, et al., 1968RDSH
Re+>23.?EIJunk, Svec, et al., 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A., J. Organomet. Chem., 1983, 259, 313. [all data]

Junk, Svec, et al., 1968
Junk, G.A.; Svec, H.J.; Angelici, R.J., Electron impact studies of manganese and rhenium pentacarbonyl halides, J. Am. Chem. Soc., 1968, 90, 5758. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Hall, 1975
Hall, M.B., The use of spin-orbit coupling in the interpretation of photoelectron spectra. I. Application to substituted rhenium pentacarbonyls, J. Am. Chem. Soc., 1975, 97, 2057. [all data]

Ceasar, Milazzo, et al., 1974
Ceasar, G.P.; Milazzo, P.; Cihonski, J.L.; Levenson, R.A., Photoelectron spectra of osmium and ruthenium tetroxide, J. Am. Chem. Soc., 1974, 13, 3035. [all data]


Notes

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