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germanium(4+) ethanolate


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltavap13.6kcal/molN/APangrác, Fulem, et al., 2008Based on data from 259. - 303. K.; AC
Deltavap10.3 ± 0.1kcal/molCC-SBShaulov, Fedorov, et al., 1970Another value for the enthalpy of vaporization has been reported: 12.9 ± 0.07 kcal/mol Grinberg, Chernaya, et al., 1988.; MS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Reference Comment
12.9389.Grinberg, Chernaya, et al., 1988, 2See also Pangrác, Fulem, et al., 2008.; AC
12.8406.Balanevskaya, Rudnev, et al., 1977See also Pangrác, Fulem, et al., 2008.; AC
11.4371.Bradley, Kay, et al., 1958Based on data from 328. - 414. K.; AC
11.1403.Johnson and Fritz, 1953See also Pangrác, Fulem, et al., 2008.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pangrác, Fulem, et al., 2008
Pangrác, J.; Fulem, M.; Hulicius, E.; Melichar, K.; Simecek, T.; Ruzicka, K.; Morávek, P.; Ruzicka, V.; Rushworth, S.A., Vapor pressure of germanium precursors, Journal of Crystal Growth, 2008, 310, 23, 4720-4723, https://doi.org/10.1016/j.jcrysgro.2008.06.063 . [all data]

Shaulov, Fedorov, et al., 1970
Shaulov, Yu.Kh.; Fedorov, A.K.; Zueva, G.Ya.; Borisyuk, G.V.; Genchel, V.G., Russ. J. Phys. Chem., 1970, 44, 1181. [all data]

Grinberg, Chernaya, et al., 1988
Grinberg, E.E.; Chernaya, N.G.; Efremov, A.A., Vysokochist. Veshchestva, 1988, 180.. [all data]

Grinberg, Chernaya, et al., 1988, 2
Grinberg, E.E.; Chernaya, N.G.; Efremov, A.A., Physicochemical properties of some Group III-V element alcoholates, Vysokochist. Veshchestva, 1988, 3, 180. [all data]

Balanevskaya, Rudnev, et al., 1977
Balanevskaya, T.S.; Rudnev, V.V.; Klishina, N.G.; Efremov, A.A., Tr. VNII Khim. Reakt. Osobo Chist. Khim. Veshehestv, 1977, 98. [all data]

Bradley, Kay, et al., 1958
Bradley, D.C.; Kay, L.J.; Swanwick, J.D.; Wardlaw, W., 732. Germanium esters. Part II. Intermolecular forces and liquid structure, J. Chem. Soc., 1958, 3656, https://doi.org/10.1039/jr9580003656 . [all data]

Johnson and Fritz, 1953
Johnson, Otto H.; Fritz, H.E., Tetraalkoxygermanes 1, J. Am. Chem. Soc., 1953, 75, 3, 718-720, https://doi.org/10.1021/ja01099a061 . [all data]


Notes

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