sodium formate

• Formula: CHNaO₂
• Molecular weight: 68.0072
• IUPAC Standard InChI: InChI=1S/CH2O2.Na/c2-1-3;/h1H,(H,2,3);/q;+1/p-1 Copy

  
• IUPAC Standard InChIKey: HLBBKKJFGFRGMU-UHFFFAOYSA-M Copy
• CAS Registry Number: 141-53-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Species with the same structure:
  • Formic acid, sodium salt
• Other names: Sodium methanoate
• Information on this page:
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • References
  • Notes
• Options:
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of phase transition

Entropy of phase transition

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2 +  =  + 2 + 2

By formula: 2HNaO + C₂H₆O₄ = H₂ + 2CHNaO₂ + 2H₂O

 +  =  + 

By formula: C₂HBr₃O + HNaO = CHNaO₂ + CHBr₃

 +  =  + 

By formula: HNaO + C₂HCl₃O = CHNaO₂ + CHCl₃

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Franzosini, Plautz, et al., 1983
Franzosini, P.; Plautz, W.A.; Westrum, E.F., Jr., Thermophysics of metal alkanoates. I. Heat capacities and thermodynamic properties of sodium methanoate and ethanoate, J. Chem. Thermodynam., 1983, 15, 445-456. [all data]

Westrum, Chang, et al., 1960
Westrum, E.F., Jr.; Chang, S-S.; Levitin, N.E., The heat capacity and thermodynamic properties of sodium formate from 5 to 350K, J. Phys. Chem., 1960, 64, 1553-1554. [all data]

Ferloni, Sanesi, et al., 1975
Ferloni, P.; Sanesi, M.; Franzosini, P.; C4 alkanoates, Phase transitions in the alkali C1-n., Z. Naturforsch. 30a, 1975, 1447-1454. [all data]

Franzosini, Plautz, et al., 1983, 2
Franzosini, P.; Plautz, W.A.; Westrum, E.F., Thermophysics of metal alkanoates. I. Heat capacities and thermodynamic properties of sodium methanoate and ethanoate, J. Chem. Thermodyn., 1983, 15, 445. [all data]

Jenkins and Style, 1953
Jenkins, A.D.; Style, D.W.G., The thermochemistry and pyrolysis of bishydroxymethyl, J. Chem. Soc., 1953, 2337-23. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Pritchard and Skinner, 1950
Pritchard, H.O.; Skinner, H.A., The heats of hydrolysis of chloral and bromal, and the C-C bond dissociation energies in chloral and bromal, J. Am. Chem. Soc., 1950, 1928-1931. [all data]

Notes

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• Symbols used in this document:
  

  Cp,solid	Constant pressure heat capacity of solid
  S°solid,1 bar	Entropy of solid at standard conditions (1 bar)
  Ttriple	Triple point temperature
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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