sodium formate

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2Sodium hydroxide + Dioxybismethanol = Hydrogen + 2sodium formate + 2Water

By formula: 2HNaO + C2H6O4 = H2 + 2CHNaO2 + 2H2O

Quantity Value Units Method Reference Comment
Δr-293.3 ± 5.0kJ/molCmJenkins and Style, 1953solid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -292. kJ/mol

Acetaldehyde, tribromo- + Sodium hydroxide = sodium formate + Methane, tribromo-

By formula: C2HBr3O + HNaO = CHNaO2 + CHBr3

Quantity Value Units Method Reference Comment
Δr-93.72kJ/molCmPritchard and Skinner, 1950liquid phase; Heat of hydrolysis

Sodium hydroxide + Chloral = sodium formate + Trichloromethane

By formula: HNaO + C2HCl3O = CHNaO2 + CHCl3

Quantity Value Units Method Reference Comment
Δr-102.8kJ/molCmPritchard and Skinner, 1950liquid phase; Heat of hydrolysis

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jenkins and Style, 1953
Jenkins, A.D.; Style, D.W.G., The thermochemistry and pyrolysis of bishydroxymethyl, J. Chem. Soc., 1953, 2337-23. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Pritchard and Skinner, 1950
Pritchard, H.O.; Skinner, H.A., The heats of hydrolysis of chloral and bromal, and the C-C bond dissociation energies in chloral and bromal, J. Am. Chem. Soc., 1950, 1928-1931. [all data]


Notes

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