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Manganese ion (1+)


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Manganese ion (1+) + Methyl radical = (Manganese ion (1+) bullet Methyl radical)

By formula: Mn+ + CH3 = (Mn+ bullet CH3)

Quantity Value Units Method Reference Comment
Deltar51.5 ± 3.9kcal/molCIDTGeorgiadis and Armentrout, 1989RCD

Manganese ion (1+) + Carbon monoxide = (Manganese ion (1+) bullet Carbon monoxide)

By formula: Mn+ + CO = (Mn+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar7.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; «DELTA»rH>; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
6.0 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) bullet 2Carbon monoxide)

By formula: (Mn+ bullet CO) + CO = (Mn+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar25.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; «DELTA»rH<; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
15.1 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) bullet 3Carbon monoxide)

By formula: (Mn+ bullet 2CO) + CO = (Mn+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar31. ± 6.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
17.7 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) bullet 4Carbon monoxide)

By formula: (Mn+ bullet 3CO) + CO = (Mn+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar20. ± 3.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
15.5 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 4Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) bullet 5Carbon monoxide)

By formula: (Mn+ bullet 4CO) + CO = (Mn+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar16. ± 3.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.9 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 5Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) bullet 6Carbon monoxide)

By formula: (Mn+ bullet 5CO) + CO = (Mn+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar32. ± 5.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
34.0 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Manganese ion (1+) + Carbon monosulfide = (Manganese ion (1+) bullet Carbon monosulfide)

By formula: Mn+ + CS = (Mn+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar19.1 ± 5.1kcal/molCIDTRue, Armentrout, et al., 2001RCD
Deltar18.6 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000RCD

Manganese ion (1+) + Ethylene = (Manganese ion (1+) bullet Ethylene)

By formula: Mn+ + C2H4 = (Mn+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar21.7 ± 2.9kcal/molCIDTSievers, Jarvis, et al., 1998RCD

(Manganese ion (1+) bullet Ethylene) + Ethylene = (Manganese ion (1+) bullet 2Ethylene)

By formula: (Mn+ bullet C2H4) + C2H4 = (Mn+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar21.0 ± 3.3kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Manganese ion (1+) + Acetone-D6 = (Manganese ion (1+) bullet Acetone-D6)

By formula: Mn+ + C3D6O = (Mn+ bullet C3D6O)

Quantity Value Units Method Reference Comment
Deltar34.4 ± 3.3kcal/molRAK,EJLin, Chen, et al., 1997RCD

Manganese ion (1+) + Acetone = (Manganese ion (1+) bullet Acetone)

By formula: Mn+ + C3H6O = (Mn+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar38.0 ± 3.3kcal/molRAKLin, Chen, et al., 1997RCD

Manganese ion (1+) + 1,3-Diazine = (Manganese ion (1+) bullet 1,3-Diazine)

By formula: Mn+ + C4H4N2 = (Mn+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar38.0 ± 2.3kcal/molCIDTAmunugama and Rodgers, 2001RCD

Manganese ion (1+) + Pyrrole = (Manganese ion (1+) bullet Pyrrole)

By formula: Mn+ + C4H5N = (Mn+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar42.3kcal/molRAKGapeev and Yang, 2000RCD

(Manganese ion (1+) bullet Pyrrole) + Pyrrole = (Manganese ion (1+) bullet 2Pyrrole)

By formula: (Mn+ bullet C4H5N) + C4H5N = (Mn+ bullet 2C4H5N)

Quantity Value Units Method Reference Comment
Deltar27.0kcal/molRAKGapeev and Yang, 2000RCD

Manganese ion (1+) + Pyridine = (Manganese ion (1+) bullet Pyridine)

By formula: Mn+ + C5H5N = (Mn+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar43.4 ± 2.1kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Manganese ion (1+) + Adenine = (Manganese ion (1+) bullet Adenine)

By formula: Mn+ + C5H5N5 = (Mn+ bullet C5H5N5)

Quantity Value Units Method Reference Comment
Deltar51.6 ± 1.8kcal/molCIDTRodgers and Armentrout, 2002RCD

Manganese ion (1+) + Benzene = (Manganese ion (1+) bullet Benzene)

By formula: Mn+ + C6H6 = (Mn+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar34.4kcal/molMIDLin, Chen, et al., 1997, 2RCD
Deltar31.8 ± 2.2kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
31.8 (+2.1,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet Benzene) + Benzene = (Manganese ion (1+) bullet 2Benzene)

By formula: (Mn+ bullet C6H6) + C6H6 = (Mn+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar48.5 ± 3.8kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
48.4 (+3.9,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

Manganese ion (1+) + Water = (Manganese ion (1+) bullet Water)

By formula: Mn+ + H2O = (Mn+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar33. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M
Deltar26.5kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.4 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet Water) + Water = (Manganese ion (1+) bullet 2Water)

By formula: (Mn+ bullet H2O) + H2O = (Mn+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar17.8kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
21.5 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 2Water) + Water = (Manganese ion (1+) bullet 3Water)

By formula: (Mn+ bullet 2H2O) + H2O = (Mn+ bullet 3H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
25.8 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 3Water) + Water = (Manganese ion (1+) bullet 4Water)

By formula: (Mn+ bullet 3H2O) + H2O = (Mn+ bullet 4H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
12.0 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Manganese ion (1+) + Ammonia = (Manganese ion (1+) bullet Ammonia)

By formula: Mn+ + H3N = (Mn+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar35.1 ± 1.9kcal/molCIDTWalter and Armentrout, 1998RCD
Deltar36.9kcal/molCIDMarinelli and Squires, 1989gas phase; M

(Manganese ion (1+) bullet Ammonia) + Ammonia = (Manganese ion (1+) bullet 2Ammonia)

By formula: (Mn+ bullet H3N) + H3N = (Mn+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar36.3 ± 2.9kcal/molCIDTWalter and Armentrout, 1998RCD
Deltar34.1kcal/molCIDMarinelli and Squires, 1989gas phase; M

(Manganese ion (1+) bullet 2Ammonia) + Ammonia = (Manganese ion (1+) bullet 3Ammonia)

By formula: (Mn+ bullet 2H3N) + H3N = (Mn+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar15.3 ± 2.2kcal/molCIDTWalter and Armentrout, 1998RCD
Deltar11.8kcal/molCIDMarinelli and Squires, 1989gas phase; M

(Manganese ion (1+) bullet 3Ammonia) + Ammonia = (Manganese ion (1+) bullet 4Ammonia)

By formula: (Mn+ bullet 3H3N) + H3N = (Mn+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar8.6 ± 1.4kcal/molCIDTWalter and Armentrout, 1998RCD

Manganese ion (1+) + manganese = (Manganese ion (1+) bullet manganese)

By formula: Mn+ + Mn = (Mn+ bullet Mn)

Quantity Value Units Method Reference Comment
Deltar48. ± 6.9kcal/molICRCDHouriet and Vulpius, 1989gas phase; M
Deltar32.kcal/molPDissJarrold, Illies, et al., 1985gas phase; «DELTA»rH>; M
Deltar20.kcal/molKC-MSErvin, Loh, et al., 1983gas phase; obtained using D(Mn)2 = 7.3+-6.9 kcal/mol; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Georgiadis and Armentrout, 1989
Georgiadis, R.; Armentrout, P.B., Translational and Electronic Energy Dependence of the Reaction of Mn+ with Ethane, Int. J. Mass Spectrom. Ion Proc., 1989, 91, 2, 123, https://doi.org/10.1016/0168-1176(89)83003-4 . [all data]

Dearden, Hayashibara, et al., 1989
Dearden, D.V.; Hayashibara, K.; Beauchamp, J.L.; Kirschner, N.J.; Van Koppen, P.A.M.; Bowers, M.T., Fundamental Studies of the Energetics and Dynamics of Ligand Dissociation and Exchange Processes at Transition - Metal Centers in the Gas Phase: Mn(COx)+, x = 1 - 6, J. Am. Chem. Soc., 1989, 111, 7, 2401, https://doi.org/10.1021/ja00189a005 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS, Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Lin, Chen, et al., 1997
Lin, C.-Y.; Chen, Q.; Chen, H.; Freiser, B.S., Bond Dissociation Energy Determinations for MOC(CH3)2+ and MOC(CD3)2+ (M=Cr, Mn) Using Continuous Ejection and Radiative Association Methods, Int. J. Mass Spectrom. Ion Proc., 1997, 167/168, 713, https://doi.org/10.1016/S0168-1176(97)00131-6 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Lin, Chen, et al., 1997, 2
Lin, C.-Y.; Chen, Q.; Chen, H.; Freiser, B.S., Observing Unimolecular Dissociation of Metastable Ions in FT-ICR: A Novel Application of the Continuous Ejection Technique, J. Phys. Chem. A, 1997, 101, 34, 6023, https://doi.org/10.1021/jp970446a . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Houriet and Vulpius, 1989
Houriet, R.; Vulpius, T., Formation of Metal Cluster Ions by Gas - Phase Ion - Molecule Reactions: the Bond Energies of Cr2+ and Mn2+, Chem. Phys. Lett., 1989, 154, 5, 454, https://doi.org/10.1016/0009-2614(89)87130-1 . [all data]

Jarrold, Illies, et al., 1985
Jarrold, M.F.; Illies, A.J.; Wagner-Redeker, W.; Bowers, M.T., Photodissociation of Weakly Bound Ion - Molecule Clusters: The Kr.CO2+ Cluster, J. Phys. Chem., 1985, 89, 15, 3269, https://doi.org/10.1021/j100261a020 . [all data]

Ervin, Loh, et al., 1983
Ervin, K.; Loh, S.K.; Aristov, N.; Armentrout, P.B., Metal cluster ions: The bond energy of Mn2+, J. Phys. Chem., 1983, 87, 3593. [all data]


Notes

Go To: Top, Ion clustering data, References