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Manganese ion (1+)


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar41.826cal/mol*KReviewChase, 1998Data last reviewed in June, 1984

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Manganese ion (1+) + manganese = (Manganese ion (1+) bullet manganese)

By formula: Mn+ + Mn = (Mn+ bullet Mn)

Quantity Value Units Method Reference Comment
Deltar48. ± 6.9kcal/molICRCDHouriet and Vulpius, 1989gas phase; M
Deltar32.kcal/molPDissJarrold, Illies, et al., 1985gas phase; «DELTA»rH>; M
Deltar20.kcal/molKC-MSErvin, Loh, et al., 1983gas phase; obtained using D(Mn)2 = 7.3+-6.9 kcal/mol; M

Manganese ion (1+) + Water = (Manganese ion (1+) bullet Water)

By formula: Mn+ + H2O = (Mn+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar33. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M
Deltar26.5kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.4 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Manganese ion (1+) + Benzene = (Manganese ion (1+) bullet Benzene)

By formula: Mn+ + C6H6 = (Mn+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar34.4kcal/molMIDLin, Chen, et al., 1997RCD
Deltar31.8 ± 2.2kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
31.8 (+2.1,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) bullet 2Carbon monoxide)

By formula: (Mn+ bullet CO) + CO = (Mn+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar25.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; «DELTA»rH<; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
15.1 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) bullet 3Carbon monoxide)

By formula: (Mn+ bullet 2CO) + CO = (Mn+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar31. ± 6.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
17.7 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) bullet 4Carbon monoxide)

By formula: (Mn+ bullet 3CO) + CO = (Mn+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar20. ± 3.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
15.5 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 4Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) bullet 5Carbon monoxide)

By formula: (Mn+ bullet 4CO) + CO = (Mn+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar16. ± 3.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.9 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 5Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) bullet 6Carbon monoxide)

By formula: (Mn+ bullet 5CO) + CO = (Mn+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar32. ± 5.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
34.0 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet Water) + Water = (Manganese ion (1+) bullet 2Water)

By formula: (Mn+ bullet H2O) + H2O = (Mn+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar17.8kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
21.5 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Manganese ion (1+) + Carbon monoxide = (Manganese ion (1+) bullet Carbon monoxide)

By formula: Mn+ + CO = (Mn+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar7.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; «DELTA»rH>; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
6.0 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet Benzene) + Benzene = (Manganese ion (1+) bullet 2Benzene)

By formula: (Mn+ bullet C6H6) + C6H6 = (Mn+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar48.5 ± 3.8kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
48.4 (+3.9,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 2Ammonia) + Ammonia = (Manganese ion (1+) bullet 3Ammonia)

By formula: (Mn+ bullet 2H3N) + H3N = (Mn+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar15.3 ± 2.2kcal/molCIDTWalter and Armentrout, 1998RCD
Deltar11.8kcal/molCIDMarinelli and Squires, 1989gas phase; M

(Manganese ion (1+) bullet Ammonia) + Ammonia = (Manganese ion (1+) bullet 2Ammonia)

By formula: (Mn+ bullet H3N) + H3N = (Mn+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar36.3 ± 2.9kcal/molCIDTWalter and Armentrout, 1998RCD
Deltar34.1kcal/molCIDMarinelli and Squires, 1989gas phase; M

Manganese ion (1+) + Ammonia = (Manganese ion (1+) bullet Ammonia)

By formula: Mn+ + H3N = (Mn+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar35.1 ± 1.9kcal/molCIDTWalter and Armentrout, 1998RCD
Deltar36.9kcal/molCIDMarinelli and Squires, 1989gas phase; M

Manganese ion (1+) + Carbon monosulfide = (Manganese ion (1+) bullet Carbon monosulfide)

By formula: Mn+ + CS = (Mn+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar19.1 ± 5.1kcal/molCIDTRue, Armentrout, et al., 2001RCD
Deltar18.6 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000RCD

(Manganese ion (1+) bullet 2Water) + Water = (Manganese ion (1+) bullet 3Water)

By formula: (Mn+ bullet 2H2O) + H2O = (Mn+ bullet 3H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
25.8 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 3Water) + Water = (Manganese ion (1+) bullet 4Water)

By formula: (Mn+ bullet 3H2O) + H2O = (Mn+ bullet 4H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
12.0 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet 3Ammonia) + Ammonia = (Manganese ion (1+) bullet 4Ammonia)

By formula: (Mn+ bullet 3H3N) + H3N = (Mn+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar8.6 ± 1.4kcal/molCIDTWalter and Armentrout, 1998RCD

(Manganese ion (1+) bullet Ethylene) + Ethylene = (Manganese ion (1+) bullet 2Ethylene)

By formula: (Mn+ bullet C2H4) + C2H4 = (Mn+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar21.0 ± 3.3kcal/molCIDTSievers, Jarvis, et al., 1998RCD

(Manganese ion (1+) bullet Pyrrole) + Pyrrole = (Manganese ion (1+) bullet 2Pyrrole)

By formula: (Mn+ bullet C4H5N) + C4H5N = (Mn+ bullet 2C4H5N)

Quantity Value Units Method Reference Comment
Deltar27.0kcal/molRAKGapeev and Yang, 2000RCD

Manganese ion (1+) + Pyridine = (Manganese ion (1+) bullet Pyridine)

By formula: Mn+ + C5H5N = (Mn+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar43.4 ± 2.1kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Manganese ion (1+) + Methyl radical = (Manganese ion (1+) bullet Methyl radical)

By formula: Mn+ + CH3 = (Mn+ bullet CH3)

Quantity Value Units Method Reference Comment
Deltar51.5 ± 3.9kcal/molCIDTGeorgiadis and Armentrout, 1989RCD

Manganese ion (1+) + Acetone-D6 = (Manganese ion (1+) bullet Acetone-D6)

By formula: Mn+ + C3D6O = (Mn+ bullet C3D6O)

Quantity Value Units Method Reference Comment
Deltar34.4 ± 3.3kcal/molRAK,EJLin, Chen, et al., 1997, 2RCD

Manganese ion (1+) + 1,3-Diazine = (Manganese ion (1+) bullet 1,3-Diazine)

By formula: Mn+ + C4H4N2 = (Mn+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar38.0 ± 2.3kcal/molCIDTAmunugama and Rodgers, 2001RCD

Manganese ion (1+) + Adenine = (Manganese ion (1+) bullet Adenine)

By formula: Mn+ + C5H5N5 = (Mn+ bullet C5H5N5)

Quantity Value Units Method Reference Comment
Deltar51.6 ± 1.8kcal/molCIDTRodgers and Armentrout, 2002RCD

Manganese ion (1+) + Ethylene = (Manganese ion (1+) bullet Ethylene)

By formula: Mn+ + C2H4 = (Mn+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar21.7 ± 2.9kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Manganese ion (1+) + Acetone = (Manganese ion (1+) bullet Acetone)

By formula: Mn+ + C3H6O = (Mn+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar38.0 ± 3.3kcal/molRAKLin, Chen, et al., 1997, 2RCD

Manganese ion (1+) + Pyrrole = (Manganese ion (1+) bullet Pyrrole)

By formula: Mn+ + C4H5N = (Mn+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar42.3kcal/molRAKGapeev and Yang, 2000RCD

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Houriet and Vulpius, 1989
Houriet, R.; Vulpius, T., Formation of Metal Cluster Ions by Gas - Phase Ion - Molecule Reactions: the Bond Energies of Cr2+ and Mn2+, Chem. Phys. Lett., 1989, 154, 5, 454, https://doi.org/10.1016/0009-2614(89)87130-1 . [all data]

Jarrold, Illies, et al., 1985
Jarrold, M.F.; Illies, A.J.; Wagner-Redeker, W.; Bowers, M.T., Photodissociation of Weakly Bound Ion - Molecule Clusters: The Kr.CO2+ Cluster, J. Phys. Chem., 1985, 89, 15, 3269, https://doi.org/10.1021/j100261a020 . [all data]

Ervin, Loh, et al., 1983
Ervin, K.; Loh, S.K.; Aristov, N.; Armentrout, P.B., Metal cluster ions: The bond energy of Mn2+, J. Phys. Chem., 1983, 87, 3593. [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Lin, Chen, et al., 1997
Lin, C.-Y.; Chen, Q.; Chen, H.; Freiser, B.S., Observing Unimolecular Dissociation of Metastable Ions in FT-ICR: A Novel Application of the Continuous Ejection Technique, J. Phys. Chem. A, 1997, 101, 34, 6023, https://doi.org/10.1021/jp970446a . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Dearden, Hayashibara, et al., 1989
Dearden, D.V.; Hayashibara, K.; Beauchamp, J.L.; Kirschner, N.J.; Van Koppen, P.A.M.; Bowers, M.T., Fundamental Studies of the Energetics and Dynamics of Ligand Dissociation and Exchange Processes at Transition - Metal Centers in the Gas Phase: Mn(COx)+, x = 1 - 6, J. Am. Chem. Soc., 1989, 111, 7, 2401, https://doi.org/10.1021/ja00189a005 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS, Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Georgiadis and Armentrout, 1989
Georgiadis, R.; Armentrout, P.B., Translational and Electronic Energy Dependence of the Reaction of Mn+ with Ethane, Int. J. Mass Spectrom. Ion Proc., 1989, 91, 2, 123, https://doi.org/10.1016/0168-1176(89)83003-4 . [all data]

Lin, Chen, et al., 1997, 2
Lin, C.-Y.; Chen, Q.; Chen, H.; Freiser, B.S., Bond Dissociation Energy Determinations for MOC(CH3)2+ and MOC(CD3)2+ (M=Cr, Mn) Using Continuous Ejection and Radiative Association Methods, Int. J. Mass Spectrom. Ion Proc., 1997, 167/168, 713, https://doi.org/10.1016/S0168-1176(97)00131-6 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References