Calcium, doubly charged positive ion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Ca+2 • 10Water) + Water = (Ca+2 • 11Water)

By formula: (Ca+2 • 10H2O) + H2O = (Ca+2 • 11H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

(Ca+2 • 11Water) + Water = (Ca+2 • 12Water)

By formula: (Ca+2 • 11H2O) + H2O = (Ca+2 • 12H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
29.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

(Ca+2 • 9Water) + Water = (Ca+2 • 10Water)

By formula: (Ca+2 • 9H2O) + H2O = (Ca+2 • 10H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

(Ca+2 • 8Water) + Water = (Ca+2 • 9Water)

By formula: (Ca+2 • 8H2O) + H2O = (Ca+2 • 9H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

(Ca+2 • 4Carbon dioxide • Calcium carbonate (precipitated)) + Carbon dioxide = (Ca+2 • 5Carbon dioxide • Calcium carbonate (precipitated))

By formula: (Ca+2 • 4CO2 • CCaO3) + CO2 = (Ca+2 • 5CO2 • CCaO3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.296.FASpears and Fehsenfeld, 1972gas phase

(Ca+2 • 5Carbon dioxide) + Carbon dioxide = (Ca+2 • 6Carbon dioxide)

By formula: (Ca+2 • 5CO2) + CO2 = (Ca+2 • 6CO2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.296.FASpears and Fehsenfeld, 1972gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(Ca+2 • 4Carbon dioxide • Calcium carbonate (precipitated)) + Carbon dioxide = (Ca+2 • 5Carbon dioxide • Calcium carbonate (precipitated))

By formula: (Ca+2 • 4CO2 • CCaO3) + CO2 = (Ca+2 • 5CO2 • CCaO3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.296.FASpears and Fehsenfeld, 1972gas phase

(Ca+2 • 5Carbon dioxide) + Carbon dioxide = (Ca+2 • 6Carbon dioxide)

By formula: (Ca+2 • 5CO2) + CO2 = (Ca+2 • 6CO2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.296.FASpears and Fehsenfeld, 1972gas phase

(Ca+2 • 8Water) + Water = (Ca+2 • 9Water)

By formula: (Ca+2 • 8H2O) + H2O = (Ca+2 • 9H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

(Ca+2 • 9Water) + Water = (Ca+2 • 10Water)

By formula: (Ca+2 • 9H2O) + H2O = (Ca+2 • 10H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

(Ca+2 • 10Water) + Water = (Ca+2 • 11Water)

By formula: (Ca+2 • 10H2O) + H2O = (Ca+2 • 11H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

(Ca+2 • 11Water) + Water = (Ca+2 • 12Water)

By formula: (Ca+2 • 11H2O) + H2O = (Ca+2 • 12H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
29.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Jayaweera, et al., 1990
Blades, A.T.; Jayaweera, P.; Ikonomou, M.G.; Kebarle, P., Studies of Alkaline - Earth and Transition - Metal M++ Gas - Phase Ion Chemistry, J. Chem. Phys., 1990, 92, 10, 5900, https://doi.org/10.1063/1.458360 . [all data]

Spears and Fehsenfeld, 1972
Spears, K.G.; Fehsenfeld, F.C., Termolecular Association Reactions of Mg, Ca, and Ba Ions, J. Chem. Phys., 1972, 56, 11, 5698, https://doi.org/10.1063/1.1677091 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References