Manganese, pentacarbonyl(trifluoroacetyl)-


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-1505.0 ± 7.0kJ/molReviewMartinho SimõesThe enthalpy formation relies on -1382.7 ± 4.8 kJ/mol for the enthalpy of formation of Mn(CO)5(CF3)(g)
Δfgas-1503.2 ± 6.5kJ/molReviewMartinho Simões 
Δfgas-1504.1 ± 5.9kJ/molReviewMartinho SimõesSelected data. Average of the values from Connor, Zafarani-Moattar, et al., 1982

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-1584.0 ± 4.9kJ/molReviewMartinho SimõesThe enthalpy formation relies on -1382.7 ± 4.8 kJ/mol for the enthalpy of formation of Mn(CO)5(CF3)(g)
Δfsolid-1582.2 ± 4.1kJ/molReviewMartinho Simões 
Δfsolid-1583.1 ± 3.2kJ/molReviewMartinho SimõesSelected data. Average of the values from Connor, Zafarani-Moattar, et al., 1982

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub79. ± 5.kJ/molTD-HFCConnor, Zafarani-Moattar, et al., 1982MS
Δsub79. ± 5.kJ/molCConnor, Zafarani-Moattar, et al., 1982, 2AC

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C7F3MnO6 (cr) + 1.5Bromine (g) = manganese dibromide (cr) + 6Carbon monoxide (g) + Bromotrifluoromethane (g)

By formula: C7F3MnO6 (cr) + 1.5Br2 (g) = Br2Mn (cr) + 6CO (g) + CBrF3 (g)

Quantity Value Units Method Reference Comment
Δr-161. ± 2.kJ/molHAL-HFCConnor, Zafarani-Moattar, et al., 1982 

C7F3MnO6 (cr) = C6F3MnO5 (g) + Carbon monoxide (g)

By formula: C7F3MnO6 (cr) = C6F3MnO5 (g) + CO (g)

Quantity Value Units Method Reference Comment
Δr90.8 ± 0.9kJ/molTD-HFCConnor, Zafarani-Moattar, et al., 1982 

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.0PEEvans, Green, et al., 1969Vertical value; RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Connor, Zafarani-Moattar, et al., 1982, 2
Connor, Joseph A.; Zafarani-Moattar, Mohamed T.; Bickerton, James; El Saied, Nabila I.; Suradi, Sukiman; Carson, Ronald; Al Takhin, Ghassan; Skinner, Henry A., Enthalpy of formation of acyl-, alkyl- and hydridopentacarbonyl-manganese complexes. The enthalpy contributions of manganese-hydrogen and manganese-carbon bonds in these molecules. Thermochemical aspects of models in Fischer-Tropsch reactions, Organometallics, 1982, 1, 9, 1166-1174, https://doi.org/10.1021/om00069a011 . [all data]

Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W., Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References