Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

H3NS


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

H2NS- + Hydrogen cation = H3NS

By formula: H2NS- + H+ = H3NS

Quantity Value Units Method Reference Comment
Deltar356.9 ± 3.1kcal/molG+TSDePuy and Bierbaum, 1981gas phase; Between CF3CH2OH and H2S, comparable to MeSH; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar350.6 ± 3.0kcal/molIMRBDePuy and Bierbaum, 1981gas phase; Between CF3CH2OH and H2S, comparable to MeSH; value altered from reference due to change in acidity scale
Deltar353.7 ± 3.0kcal/molIMRBBierbaum, Grabowski, et al., 1984gas phase; NH2- + COS ->.

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy and Bierbaum, 1981
DePuy, C.H.; Bierbaum, V.M., Gas phase sulfur anions: Synthesis and reactions of H2NS- and related ions, Tetrahedron Lett., 1981, 22, 5129. [all data]

Bierbaum, Grabowski, et al., 1984
Bierbaum, V.M.; Grabowski, J.J.; DePuy, C.H., Gas-phase synthesis and reactions of nitrogen- and sulfur-containing anions, J. Phys. Chem., 1984, 88, 1389. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References