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Titanium ion (1+)


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Titanium ion (1+) + Carbon monoxide = (Titanium ion (1+) bullet Carbon monoxide)

By formula: Ti+ + CO = (Ti+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar28.2 ± 1.4kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 2Carbon monoxide)

By formula: (Ti+ bullet CO) + CO = (Ti+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar27.0 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 3Carbon monoxide)

By formula: (Ti+ bullet 2CO) + CO = (Ti+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar23.9 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 4Carbon monoxide)

By formula: (Ti+ bullet 3CO) + CO = (Ti+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar20.8 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 4Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 5Carbon monoxide)

By formula: (Ti+ bullet 4CO) + CO = (Ti+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 5Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 6Carbon monoxide)

By formula: (Ti+ bullet 5CO) + CO = (Ti+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar17.7 ± 0.7kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 6Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 7Carbon monoxide)

By formula: (Ti+ bullet 6CO) + CO = (Ti+ bullet 7CO)

Quantity Value Units Method Reference Comment
Deltar12.4 ± 1.7kcal/molCIDTMeyer and Armentrout, 1996RCD

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) bullet Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Titanium ion (1+) + Acetylene = (Titanium ion (1+) bullet Acetylene)

By formula: Ti+ + C2H2 = (Ti+ bullet C2H2)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
60.5 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Titanium ion (1+) + Ethylene = (Titanium ion (1+) bullet Ethylene)

By formula: Ti+ + C2H4 = (Ti+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar34.9 ± 2.6kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.4 CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

Titanium ion (1+) + 1,3-Diazine = (Titanium ion (1+) bullet 1,3-Diazine)

By formula: Ti+ + C4H4N2 = (Ti+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar51.1 ± 2.5kcal/molCIDTAmunugama and Rodgers, 2001RCD

Titanium ion (1+) + Pyridine = (Titanium ion (1+) bullet Pyridine)

By formula: Ti+ + C5H5N = (Ti+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar51.9 ± 2.3kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Titanium ion (1+) + Adenine = (Titanium ion (1+) bullet Adenine)

By formula: Ti+ + C5H5N5 = (Ti+ bullet C5H5N5)

Quantity Value Units Method Reference Comment
Deltar<=81.1 ± 3.5kcal/molCIDTRodgers and Armentrout, 2002RCD

Titanium ion (1+) + Benzene = (Titanium ion (1+) bullet Benzene)

By formula: Ti+ + C6H6 = (Ti+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar50.9kcal/molRAKGapeev and Dunbar, 2002RCD
Deltar61.9 ± 2.2kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
61.8 (+2.1,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet Benzene) + Benzene = (Titanium ion (1+) bullet 2Benzene)

By formula: (Ti+ bullet C6H6) + C6H6 = (Ti+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar60.5 ± 4.3kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
60.4 (+4.4,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

Titanium ion (1+) + Water = (Titanium ion (1+) bullet Water)

By formula: Ti+ + H2O = (Ti+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar38. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
36.8 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet Water) + Water = (Titanium ion (1+) bullet 2Water)

By formula: (Ti+ bullet H2O) + H2O = (Ti+ bullet 2H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
32.5 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 2Water) + Water = (Titanium ion (1+) bullet 3Water)

By formula: (Ti+ bullet 2H2O) + H2O = (Ti+ bullet 3H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
16.0 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 3Water) + Water = (Titanium ion (1+) bullet 4Water)

By formula: (Ti+ bullet 3H2O) + H2O = (Ti+ bullet 4H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
20.0 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Titanium ion (1+) + Ammonia = (Titanium ion (1+) bullet Ammonia)

By formula: Ti+ + H3N = (Ti+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar46.6 ± 1.7kcal/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) bullet Ammonia) + Ammonia = (Titanium ion (1+) bullet 2Ammonia)

By formula: (Ti+ bullet H3N) + H3N = (Ti+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar41.8 ± 3.6kcal/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) bullet 2Ammonia) + Ammonia = (Titanium ion (1+) bullet 3Ammonia)

By formula: (Ti+ bullet 2H3N) + H3N = (Ti+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar42.1 ± 3.6kcal/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) bullet 3Ammonia) + Ammonia = (Titanium ion (1+) bullet 4Ammonia)

By formula: (Ti+ bullet 3H3N) + H3N = (Ti+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar37.3 ± 2.4kcal/molCIDTWalter and Armentrout, 1998RCD

Titanium ion (1+) + titanium = (Titanium ion (1+) bullet titanium)

By formula: Ti+ + Ti = (Ti+ bullet Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
58.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet titanium) + titanium = (Titanium ion (1+) bullet 2titanium)

By formula: (Ti+ bullet Ti) + Ti = (Ti+ bullet 2Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
55.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 2titanium) + titanium = (Titanium ion (1+) bullet 3titanium)

By formula: (Ti+ bullet 2Ti) + Ti = (Ti+ bullet 3Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
80.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 3titanium) + titanium = (Titanium ion (1+) bullet 4titanium)

By formula: (Ti+ bullet 3Ti) + Ti = (Ti+ bullet 4Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
81.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 4titanium) + titanium = (Titanium ion (1+) bullet 5titanium)

By formula: (Ti+ bullet 4Ti) + Ti = (Ti+ bullet 5Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
84.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 5titanium) + titanium = (Titanium ion (1+) bullet 6titanium)

By formula: (Ti+ bullet 5Ti) + Ti = (Ti+ bullet 6Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
95.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 6titanium) + titanium = (Titanium ion (1+) bullet 7titanium)

By formula: (Ti+ bullet 6Ti) + Ti = (Ti+ bullet 7Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
66.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 7titanium) + titanium = (Titanium ion (1+) bullet 8titanium)

By formula: (Ti+ bullet 7Ti) + Ti = (Ti+ bullet 8Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
82.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 8titanium) + titanium = (Titanium ion (1+) bullet 9titanium)

By formula: (Ti+ bullet 8Ti) + Ti = (Ti+ bullet 9Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
80.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 9titanium) + titanium = (Titanium ion (1+) bullet 10titanium)

By formula: (Ti+ bullet 9Ti) + Ti = (Ti+ bullet 10Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
82.2 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 10titanium) + titanium = (Titanium ion (1+) bullet 11titanium)

By formula: (Ti+ bullet 10Ti) + Ti = (Ti+ bullet 11Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
97.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 11titanium) + titanium = (Titanium ion (1+) bullet 12titanium)

By formula: (Ti+ bullet 11Ti) + Ti = (Ti+ bullet 12Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
112.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 12titanium) + titanium = (Titanium ion (1+) bullet 13titanium)

By formula: (Ti+ bullet 12Ti) + Ti = (Ti+ bullet 13Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
76.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 13titanium) + titanium = (Titanium ion (1+) bullet 14titanium)

By formula: (Ti+ bullet 13Ti) + Ti = (Ti+ bullet 14Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
95.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 14titanium) + titanium = (Titanium ion (1+) bullet 15titanium)

By formula: (Ti+ bullet 14Ti) + Ti = (Ti+ bullet 15Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
86.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 15titanium) + titanium = (Titanium ion (1+) bullet 16titanium)

By formula: (Ti+ bullet 15Ti) + Ti = (Ti+ bullet 16Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
82.2 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 16titanium) + titanium = (Titanium ion (1+) bullet 17titanium)

By formula: (Ti+ bullet 16Ti) + Ti = (Ti+ bullet 17Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
76.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 17titanium) + titanium = (Titanium ion (1+) bullet 18titanium)

By formula: (Ti+ bullet 17Ti) + Ti = (Ti+ bullet 18Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
107.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 18titanium) + titanium = (Titanium ion (1+) bullet 19titanium)

By formula: (Ti+ bullet 18Ti) + Ti = (Ti+ bullet 19Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
97.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 19titanium) + titanium = (Titanium ion (1+) bullet 20titanium)

By formula: (Ti+ bullet 19Ti) + Ti = (Ti+ bullet 20Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
94.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 20titanium) + titanium = (Titanium ion (1+) bullet 21titanium)

By formula: (Ti+ bullet 20Ti) + Ti = (Ti+ bullet 21Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
98.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meyer and Armentrout, 1996
Meyer, F.; Armentrout, P.B., Sequential Bond Energies of Ti(CO)x+, x=1-7, Molec. Phys., 1996, 88, 187. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Gapeev and Dunbar, 2002
Gapeev, A.; Dunbar, R.C., Reactivity and Binding Energies of Transition Metal Halide Ions with Benzene, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]


Notes

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