Titanium ion (1+)

Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
S°gas,1 bar43.879cal/mol*KReviewChase, 1998Data last reviewed in March, 1984

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Titanium ion (1+) + Benzene = (Titanium ion (1+) • Benzene)

By formula: Ti+ + C6H6 = (Ti+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°50.9kcal/molRAKGapeev and Dunbar, 2002RCD
ΔrH°61.9 ± 2.2kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
61.8 (+2.1,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

Titanium ion (1+) + Water = (Titanium ion (1+) • Water)

By formula: Ti+ + H2O = (Ti+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°38. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
36.8 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • Benzene) + Benzene = (Titanium ion (1+) • 2Benzene)

By formula: (Ti+ • C6H6) + C6H6 = (Ti+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°60.5 ± 4.3kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
60.4 (+4.4,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

Titanium ion (1+) + Ethylene = (Titanium ion (1+) • Ethylene)

By formula: Ti+ + C2H4 = (Ti+ • C2H4)

Quantity Value Units Method Reference Comment
ΔrH°34.9 ± 2.6kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
28.4 CIDArmentrout and Kickel, 1994gas phase; ΔrH>=, guided ion beam CID; M

(Titanium ion (1+) • 2Water) + Water = (Titanium ion (1+) • 3Water)

By formula: (Ti+ • 2H2O) + H2O = (Ti+ • 3H2O)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.0 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 3Water) + Water = (Titanium ion (1+) • 4Water)

By formula: (Ti+ • 3H2O) + H2O = (Ti+ • 4H2O)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
20.0 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • Water) + Water = (Titanium ion (1+) • 2Water)

By formula: (Ti+ • H2O) + H2O = (Ti+ • 2H2O)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
32.5 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 11titanium) + titanium = (Titanium ion (1+) • 12titanium)

By formula: (Ti+ • 11Ti) + Ti = (Ti+ • 12Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
112.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 17titanium) + titanium = (Titanium ion (1+) • 18titanium)

By formula: (Ti+ • 17Ti) + Ti = (Ti+ • 18Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
107.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 10titanium) + titanium = (Titanium ion (1+) • 11titanium)

By formula: (Ti+ • 10Ti) + Ti = (Ti+ • 11Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
97.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 12titanium) + titanium = (Titanium ion (1+) • 13titanium)

By formula: (Ti+ • 12Ti) + Ti = (Ti+ • 13Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
76.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 13titanium) + titanium = (Titanium ion (1+) • 14titanium)

By formula: (Ti+ • 13Ti) + Ti = (Ti+ • 14Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
95.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 14titanium) + titanium = (Titanium ion (1+) • 15titanium)

By formula: (Ti+ • 14Ti) + Ti = (Ti+ • 15Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
86.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 15titanium) + titanium = (Titanium ion (1+) • 16titanium)

By formula: (Ti+ • 15Ti) + Ti = (Ti+ • 16Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
82.2 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 16titanium) + titanium = (Titanium ion (1+) • 17titanium)

By formula: (Ti+ • 16Ti) + Ti = (Ti+ • 17Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
76.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 18titanium) + titanium = (Titanium ion (1+) • 19titanium)

By formula: (Ti+ • 18Ti) + Ti = (Ti+ • 19Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
97.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 19titanium) + titanium = (Titanium ion (1+) • 20titanium)

By formula: (Ti+ • 19Ti) + Ti = (Ti+ • 20Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
94.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 20titanium) + titanium = (Titanium ion (1+) • 21titanium)

By formula: (Ti+ • 20Ti) + Ti = (Ti+ • 21Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
98.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 9titanium) + titanium = (Titanium ion (1+) • 10titanium)

By formula: (Ti+ • 9Ti) + Ti = (Ti+ • 10Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
82.2 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 2titanium) + titanium = (Titanium ion (1+) • 3titanium)

By formula: (Ti+ • 2Ti) + Ti = (Ti+ • 3Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
80.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 3titanium) + titanium = (Titanium ion (1+) • 4titanium)

By formula: (Ti+ • 3Ti) + Ti = (Ti+ • 4Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
81.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 4titanium) + titanium = (Titanium ion (1+) • 5titanium)

By formula: (Ti+ • 4Ti) + Ti = (Ti+ • 5Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
84.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 5titanium) + titanium = (Titanium ion (1+) • 6titanium)

By formula: (Ti+ • 5Ti) + Ti = (Ti+ • 6Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
95.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 6titanium) + titanium = (Titanium ion (1+) • 7titanium)

By formula: (Ti+ • 6Ti) + Ti = (Ti+ • 7Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
66.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 7titanium) + titanium = (Titanium ion (1+) • 8titanium)

By formula: (Ti+ • 7Ti) + Ti = (Ti+ • 8Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
82.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 8titanium) + titanium = (Titanium ion (1+) • 9titanium)

By formula: (Ti+ • 8Ti) + Ti = (Ti+ • 9Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
80.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • titanium) + titanium = (Titanium ion (1+) • 2titanium)

By formula: (Ti+ • Ti) + Ti = (Ti+ • 2Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
55.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Titanium ion (1+) + Acetylene = (Titanium ion (1+) • Acetylene)

By formula: Ti+ + C2H2 = (Ti+ • C2H2)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
60.5 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Titanium ion (1+) + titanium = (Titanium ion (1+) • titanium)

By formula: Ti+ + Ti = (Ti+ • Ti)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
58.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 2Ammonia) + Ammonia = (Titanium ion (1+) • 3Ammonia)

By formula: (Ti+ • 2H3N) + H3N = (Ti+ • 3H3N)

Quantity Value Units Method Reference Comment
ΔrH°42.1 ± 3.6kcal/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) • 3Ammonia) + Ammonia = (Titanium ion (1+) • 4Ammonia)

By formula: (Ti+ • 3H3N) + H3N = (Ti+ • 4H3N)

Quantity Value Units Method Reference Comment
ΔrH°37.3 ± 2.4kcal/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) • Ammonia) + Ammonia = (Titanium ion (1+) • 2Ammonia)

By formula: (Ti+ • H3N) + H3N = (Ti+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°41.8 ± 3.6kcal/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 3Carbon monoxide)

By formula: (Ti+ • 2CO) + CO = (Ti+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°23.9 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 4Carbon monoxide)

By formula: (Ti+ • 3CO) + CO = (Ti+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°20.8 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 5Carbon monoxide)

By formula: (Ti+ • 4CO) + CO = (Ti+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°16.7 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 5Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 6Carbon monoxide)

By formula: (Ti+ • 5CO) + CO = (Ti+ • 6CO)

Quantity Value Units Method Reference Comment
ΔrH°17.7 ± 0.7kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 6Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 7Carbon monoxide)

By formula: (Ti+ • 6CO) + CO = (Ti+ • 7CO)

Quantity Value Units Method Reference Comment
ΔrH°12.4 ± 1.7kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 2Carbon monoxide)

By formula: (Ti+ • CO) + CO = (Ti+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°27.0 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

Titanium ion (1+) + Adenine = (Titanium ion (1+) • Adenine)

By formula: Ti+ + C5H5N5 = (Ti+ • C5H5N5)

Quantity Value Units Method Reference Comment
ΔrH°≤81.1 ± 3.5kcal/molCIDTRodgers and Armentrout, 2002RCD

Titanium ion (1+) + Ammonia = (Titanium ion (1+) • Ammonia)

By formula: Ti+ + H3N = (Ti+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°46.6 ± 1.7kcal/molCIDTWalter and Armentrout, 1998RCD

Titanium ion (1+) + Pyridine = (Titanium ion (1+) • Pyridine)

By formula: Ti+ + C5H5N = (Ti+ • C5H5N)

Quantity Value Units Method Reference Comment
ΔrH°51.9 ± 2.3kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) • Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ • CS)

Quantity Value Units Method Reference Comment
ΔrH°36.8 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Titanium ion (1+) + 1,3-Diazine = (Titanium ion (1+) • 1,3-Diazine)

By formula: Ti+ + C4H4N2 = (Ti+ • C4H4N2)

Quantity Value Units Method Reference Comment
ΔrH°51.1 ± 2.5kcal/molCIDTAmunugama and Rodgers, 2001RCD

Titanium ion (1+) + Carbon monoxide = (Titanium ion (1+) • Carbon monoxide)

By formula: Ti+ + CO = (Ti+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°28.2 ± 1.4kcal/molCIDTMeyer and Armentrout, 1996RCD

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Gapeev and Dunbar, 2002
Gapeev, A.; Dunbar, R.C., Reactivity and Binding Energies of Transition Metal Halide Ions with Benzene, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Meyer and Armentrout, 1996
Meyer, F.; Armentrout, P.B., Sequential Bond Energies of Ti(CO)x+, x=1-7, Molec. Phys., 1996, 88, 187. [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References