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Titanium ion (1+)


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar43.879cal/mol*KReviewChase, 1998Data last reviewed in March, 1984

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Titanium ion (1+) + Benzene = (Titanium ion (1+) bullet Benzene)

By formula: Ti+ + C6H6 = (Ti+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar50.9kcal/molRAKGapeev and Dunbar, 2002RCD
Deltar61.9 ± 2.2kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
61.8 (+2.1,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

Titanium ion (1+) + Water = (Titanium ion (1+) bullet Water)

By formula: Ti+ + H2O = (Ti+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar38. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
36.8 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet Benzene) + Benzene = (Titanium ion (1+) bullet 2Benzene)

By formula: (Ti+ bullet C6H6) + C6H6 = (Ti+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar60.5 ± 4.3kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
60.4 (+4.4,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

Titanium ion (1+) + Ethylene = (Titanium ion (1+) bullet Ethylene)

By formula: Ti+ + C2H4 = (Ti+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar34.9 ± 2.6kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.4 CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Titanium ion (1+) bullet 2Water) + Water = (Titanium ion (1+) bullet 3Water)

By formula: (Ti+ bullet 2H2O) + H2O = (Ti+ bullet 3H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
16.0 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 3Water) + Water = (Titanium ion (1+) bullet 4Water)

By formula: (Ti+ bullet 3H2O) + H2O = (Ti+ bullet 4H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
20.0 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet Water) + Water = (Titanium ion (1+) bullet 2Water)

By formula: (Ti+ bullet H2O) + H2O = (Ti+ bullet 2H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
32.5 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 11titanium) + titanium = (Titanium ion (1+) bullet 12titanium)

By formula: (Ti+ bullet 11Ti) + Ti = (Ti+ bullet 12Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
112.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 17titanium) + titanium = (Titanium ion (1+) bullet 18titanium)

By formula: (Ti+ bullet 17Ti) + Ti = (Ti+ bullet 18Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
107.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 10titanium) + titanium = (Titanium ion (1+) bullet 11titanium)

By formula: (Ti+ bullet 10Ti) + Ti = (Ti+ bullet 11Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
97.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 12titanium) + titanium = (Titanium ion (1+) bullet 13titanium)

By formula: (Ti+ bullet 12Ti) + Ti = (Ti+ bullet 13Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
76.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 13titanium) + titanium = (Titanium ion (1+) bullet 14titanium)

By formula: (Ti+ bullet 13Ti) + Ti = (Ti+ bullet 14Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
95.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 14titanium) + titanium = (Titanium ion (1+) bullet 15titanium)

By formula: (Ti+ bullet 14Ti) + Ti = (Ti+ bullet 15Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
86.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 15titanium) + titanium = (Titanium ion (1+) bullet 16titanium)

By formula: (Ti+ bullet 15Ti) + Ti = (Ti+ bullet 16Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
82.2 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 16titanium) + titanium = (Titanium ion (1+) bullet 17titanium)

By formula: (Ti+ bullet 16Ti) + Ti = (Ti+ bullet 17Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
76.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 18titanium) + titanium = (Titanium ion (1+) bullet 19titanium)

By formula: (Ti+ bullet 18Ti) + Ti = (Ti+ bullet 19Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
97.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 19titanium) + titanium = (Titanium ion (1+) bullet 20titanium)

By formula: (Ti+ bullet 19Ti) + Ti = (Ti+ bullet 20Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
94.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 20titanium) + titanium = (Titanium ion (1+) bullet 21titanium)

By formula: (Ti+ bullet 20Ti) + Ti = (Ti+ bullet 21Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
98.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 9titanium) + titanium = (Titanium ion (1+) bullet 10titanium)

By formula: (Ti+ bullet 9Ti) + Ti = (Ti+ bullet 10Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
82.2 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 2titanium) + titanium = (Titanium ion (1+) bullet 3titanium)

By formula: (Ti+ bullet 2Ti) + Ti = (Ti+ bullet 3Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
80.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 3titanium) + titanium = (Titanium ion (1+) bullet 4titanium)

By formula: (Ti+ bullet 3Ti) + Ti = (Ti+ bullet 4Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
81.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 4titanium) + titanium = (Titanium ion (1+) bullet 5titanium)

By formula: (Ti+ bullet 4Ti) + Ti = (Ti+ bullet 5Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
84.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 5titanium) + titanium = (Titanium ion (1+) bullet 6titanium)

By formula: (Ti+ bullet 5Ti) + Ti = (Ti+ bullet 6Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
95.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 6titanium) + titanium = (Titanium ion (1+) bullet 7titanium)

By formula: (Ti+ bullet 6Ti) + Ti = (Ti+ bullet 7Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
66.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 7titanium) + titanium = (Titanium ion (1+) bullet 8titanium)

By formula: (Ti+ bullet 7Ti) + Ti = (Ti+ bullet 8Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
82.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 8titanium) + titanium = (Titanium ion (1+) bullet 9titanium)

By formula: (Ti+ bullet 8Ti) + Ti = (Ti+ bullet 9Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
80.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet titanium) + titanium = (Titanium ion (1+) bullet 2titanium)

By formula: (Ti+ bullet Ti) + Ti = (Ti+ bullet 2Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
55.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Titanium ion (1+) + Acetylene = (Titanium ion (1+) bullet Acetylene)

By formula: Ti+ + C2H2 = (Ti+ bullet C2H2)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
60.5 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Titanium ion (1+) + titanium = (Titanium ion (1+) bullet titanium)

By formula: Ti+ + Ti = (Ti+ bullet Ti)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
58.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) bullet 2Ammonia) + Ammonia = (Titanium ion (1+) bullet 3Ammonia)

By formula: (Ti+ bullet 2H3N) + H3N = (Ti+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar42.1 ± 3.6kcal/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) bullet 3Ammonia) + Ammonia = (Titanium ion (1+) bullet 4Ammonia)

By formula: (Ti+ bullet 3H3N) + H3N = (Ti+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar37.3 ± 2.4kcal/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) bullet Ammonia) + Ammonia = (Titanium ion (1+) bullet 2Ammonia)

By formula: (Ti+ bullet H3N) + H3N = (Ti+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar41.8 ± 3.6kcal/molCIDTWalter and Armentrout, 1998RCD

(Titanium ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 3Carbon monoxide)

By formula: (Ti+ bullet 2CO) + CO = (Ti+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar23.9 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 4Carbon monoxide)

By formula: (Ti+ bullet 3CO) + CO = (Ti+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar20.8 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 4Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 5Carbon monoxide)

By formula: (Ti+ bullet 4CO) + CO = (Ti+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 5Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 6Carbon monoxide)

By formula: (Ti+ bullet 5CO) + CO = (Ti+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar17.7 ± 0.7kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet 6Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 7Carbon monoxide)

By formula: (Ti+ bullet 6CO) + CO = (Ti+ bullet 7CO)

Quantity Value Units Method Reference Comment
Deltar12.4 ± 1.7kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) bullet 2Carbon monoxide)

By formula: (Ti+ bullet CO) + CO = (Ti+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar27.0 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

Titanium ion (1+) + Adenine = (Titanium ion (1+) bullet Adenine)

By formula: Ti+ + C5H5N5 = (Ti+ bullet C5H5N5)

Quantity Value Units Method Reference Comment
Deltar<=81.1 ± 3.5kcal/molCIDTRodgers and Armentrout, 2002RCD

Titanium ion (1+) + Ammonia = (Titanium ion (1+) bullet Ammonia)

By formula: Ti+ + H3N = (Ti+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar46.6 ± 1.7kcal/molCIDTWalter and Armentrout, 1998RCD

Titanium ion (1+) + Pyridine = (Titanium ion (1+) bullet Pyridine)

By formula: Ti+ + C5H5N = (Ti+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar51.9 ± 2.3kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) bullet Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Titanium ion (1+) + 1,3-Diazine = (Titanium ion (1+) bullet 1,3-Diazine)

By formula: Ti+ + C4H4N2 = (Ti+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar51.1 ± 2.5kcal/molCIDTAmunugama and Rodgers, 2001RCD

Titanium ion (1+) + Carbon monoxide = (Titanium ion (1+) bullet Carbon monoxide)

By formula: Ti+ + CO = (Ti+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar28.2 ± 1.4kcal/molCIDTMeyer and Armentrout, 1996RCD

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Gapeev and Dunbar, 2002
Gapeev, A.; Dunbar, R.C., Reactivity and Binding Energies of Transition Metal Halide Ions with Benzene, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Meyer and Armentrout, 1996
Meyer, F.; Armentrout, P.B., Sequential Bond Energies of Ti(CO)x+, x=1-7, Molec. Phys., 1996, 88, 187. [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References