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HypoFluorous acid

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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
J - Marilyn E. Jacox
Shim - Takehiko Shimanouchi

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 26300 U gas Elliott, 1983
Appelman, Downs, et al., 1989

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 OH stretch 3577.93 gas IR Appelman and Kim, 1972
Burger, Pawelke, et al., 1989
1 OH stretch 3572 m s Ar IR Appelman, Downs, et al., 1989
1 OH stretch 3537.1 s N2 IR Goleb, Claassen, et al., 1972
Appelman, Downs, et al., 1989
1 OH stretch 3550 s O2 IR Appelman, Downs, et al., 1989
2 Bend 1353.40 gas IR Appelman and Kim, 1972
Burger, Pawelke, et al., 1988
2 Bend 1350 vs Ar IR Appelman, Downs, et al., 1989
2 Bend 1359.0 vs N2 IR Goleb, Claassen, et al., 1972
Appelman, Downs, et al., 1989
2 Bend 1350 vs O2 IR Appelman, Downs, et al., 1989
3 OF stretch 889.08 gas IR Appelman and Kim, 1972
Burger, Pawelke, et al., 1988
3 OF stretch 888 m s Ar IR Appelman, Downs, et al., 1989
3 OF stretch 886.0 w m N2 IR Noble and Pimentel, 1968
Goleb, Claassen, et al., 1972
Appelman, Downs, et al., 1989
3 OF stretch 884 m s O2 IR Appelman, Downs, et al., 1989

Additional references: Jacox, 1994, page 51; Kim, Pearson, et al., 1972; Pearson and Kim, 1972; Burger, Pawelke, et al., 1989, 2

Notes

wWeak
mMedium
sStrong
vsVery strong
UUpper bound
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Elliott, 1983
Elliott, S., Atmos. Environ, 1983, 17, 759. [all data]

Appelman, Downs, et al., 1989
Appelman, E.H.; Downs, A.J.; Gardner, C.J., Matrix photochemistry of hypofluorous acid, HOF: oxygen atom transfer and other reactions, J. Phys. Chem., 1989, 93, 2, 598, https://doi.org/10.1021/j100339a021 . [all data]

Appelman and Kim, 1972
Appelman, E.H.; Kim, H., Gas-Phase Infrared Spectra of HOF and DOF, J. Chem. Phys., 1972, 57, 8, 3272, https://doi.org/10.1063/1.1678752 . [all data]

Burger, Pawelke, et al., 1989
Burger, H.; Pawelke, G.; Rahner, A.; Appelman, E.H.; Halonen, L., The high-resolution infrared spectrum of HOF: The interacting «nu»1 and 2«nu»2 + «nu»3 states, J. Mol. Spectrosc., 1989, 138, 2, 346, https://doi.org/10.1016/0022-2852(89)90003-9 . [all data]

Goleb, Claassen, et al., 1972
Goleb, J.A.; Claassen, H.H.; Studier, M.H.; Appelman, E.H., Spectrochim. Acta, 1972, 28A, 65. [all data]

Burger, Pawelke, et al., 1988
Burger, H.; Pawelke, G.; Rahner, A.; Appelman, E.H.; Mills, I.M., The infrared spectrum of the «nu»2 and «nu»3 bands of H16OF, H18OF, and D16OF, J. Mol. Spectrosc., 1988, 128, 1, 278, https://doi.org/10.1016/0022-2852(88)90224-X . [all data]

Noble and Pimentel, 1968
Noble, P.N.; Pimentel, G.C., Spectrochim. Acta, 1968, 24A, 7907. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Kim, Pearson, et al., 1972
Kim, H.; Pearson, E.F.; Appelman, E.H., Millimeter-Wave Spectrum and Structure of Hypofluorous Acid: HOF and DOF, J. Chem. Phys., 1972, 56, 1, 1, https://doi.org/10.1063/1.1676830 . [all data]

Pearson and Kim, 1972
Pearson, E.F.; Kim, H., Centrifugal Distortion Analysis of Hypofluorous Acid: HOF and DOF, J. Chem. Phys., 1972, 57, 10, 4230, https://doi.org/10.1063/1.1678053 . [all data]

Burger, Pawelke, et al., 1989, 2
Burger, H.; Pawelke, G.; Sommer, S.; Rahner, A.; Appelman, E.H.; Mills, I.M., The high-resolution infrared spectrum of HOF near 2700 cm-1: The ground and 2«nu»2 states, J. Mol. Spectrosc., 1989, 136, 1, 197, https://doi.org/10.1016/0022-2852(89)90232-4 . [all data]


Notes

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