Palladium(II) acetylacetonate
- Formula: C10H14O4Pd
- Molecular weight: 304.64
- IUPAC Standard InChI: InChI=1S/2C5H8O2.Pd/c2*1-3-5(7)4(2)6;/h2*3,7H,1-2H3;/q;;+2/p-2/b5-3+;5-3-;
- IUPAC Standard InChIKey: RRNUJVZFAXSIII-LIQZFWKRSA-L
- CAS Registry Number: 14024-61-4
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Palladium(II) 2,4-pentanedionate; Palladium acetylacetonate; Palladium, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-; Bis(acetylacetonato)palladium; Bis(2,4-pentanedionato)palladium; Palladium bis(acetoacetonate); Palladium bis(acetylacetonate); Palladium bis(2,4-pentanedionate); Palladium diacetylacetonate; Palladium, bis(2,4-pentanedionato)-; palladium (II) di(4-oxopent-2-en-2-oate)
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 122.7 ± 8.6 | kJ/mol | N/A | Malkerova, Alikhanyan, et al., 1991 | Based on data from 330. - 394. K. |
| ΔsubH° | 132. ± 17. | kJ/mol | N/A | Burkinshaw and Mortimer, 1984 |
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 121.5 ± 1.5 | 402. - 452. | N/A | Zharkova, Stabnikov, et al., 2005 | |
| 130.1 ± 2.8 | 347. - 416. | ME | Zharkova, Stabnikov, et al., 2000 | |
| 128. ± 17. | 378. | ME | Burkinshaw and Mortimer, 1984 | Based on data from 363. - 393. K. |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Malkerova, Alikhanyan, et al., 1991
Malkerova, I.P.; Alikhanyan, A.S.; Filatov, I.Yu.; Kazanskaya, I.L.; Sevast'yanov, V.G.,
Volatility and structure of copper(II), palladium(II) and rhodium(II) acetylacetonates and copper(II) propionylacetonate,
Zh. Neorg. Khim., 1991, 36, 12, 3112. [all data]
Burkinshaw and Mortimer, 1984
Burkinshaw, Philip M.; Mortimer, Colin T.,
Enthalpies of sublimation of transition metal complexes,
J. Chem. Soc., Dalton Trans., 1984, 1, 75, https://doi.org/10.1039/dt9840000075
. [all data]
Zharkova, Stabnikov, et al., 2005
Zharkova, G.I.; Stabnikov, P.A.; Sysoev, S.A.; Igumenov, I.K.,
Volatility and crystal lattice energy of palladium(II) chelates,
J Struct Chem, 2005, 46, 2, 320-327, https://doi.org/10.1007/s10947-006-0047-8
. [all data]
Zharkova, Stabnikov, et al., 2000
Zharkova, G.I.; Stabnikov, P.A.; Grankin, V.M.; Semyannikov, P.P.; Igumenov, I.K.,
Russ. J. Coord. Chem., 2000, 26, 8, 576. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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