Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Palladium(II) acetylacetonate


Phase change data

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub122.7 ± 8.6kJ/molN/AMalkerova, Alikhanyan, et al., 1991Based on data from 330. - 394. K.
Deltasub132. ± 17.kJ/molN/ABurkinshaw and Mortimer, 1984 

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
121.5 ± 1.5402. - 452.N/AZharkova, Stabnikov, et al., 2005 
130.1 ± 2.8347. - 416.MEZharkova, Stabnikov, et al., 2000 
128. ± 17.378.MEBurkinshaw and Mortimer, 1984Based on data from 363. - 393. K.

Gas phase ion energetics data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.79PEFragala, Costanzo, et al., 1980Vertical value

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-IW-2411
NIST MS number 236117

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Malkerova, Alikhanyan, et al., 1991
Malkerova, I.P.; Alikhanyan, A.S.; Filatov, I.Yu.; Kazanskaya, I.L.; Sevast'yanov, V.G., Volatility and structure of copper(II), palladium(II) and rhodium(II) acetylacetonates and copper(II) propionylacetonate, Zh. Neorg. Khim., 1991, 36, 12, 3112. [all data]

Burkinshaw and Mortimer, 1984
Burkinshaw, Philip M.; Mortimer, Colin T., Enthalpies of sublimation of transition metal complexes, J. Chem. Soc., Dalton Trans., 1984, 1, 75, https://doi.org/10.1039/dt9840000075 . [all data]

Zharkova, Stabnikov, et al., 2005
Zharkova, G.I.; Stabnikov, P.A.; Sysoev, S.A.; Igumenov, I.K., Volatility and crystal lattice energy of palladium(II) chelates, J Struct Chem, 2005, 46, 2, 320-327, https://doi.org/10.1007/s10947-006-0047-8 . [all data]

Zharkova, Stabnikov, et al., 2000
Zharkova, G.I.; Stabnikov, P.A.; Grankin, V.M.; Semyannikov, P.P.; Igumenov, I.K., Russ. J. Coord. Chem., 2000, 26, 8, 576. [all data]

Fragala, Costanzo, et al., 1980
Fragala, I.; Costanzo, L.L.; Ciliberto, E.; Condorelli, G.; D'Arrigo, C., He-I and He-II excited photoelectron spectra of tetracoordinated complexes of transition metal ions with «beta»-diketonate ligands, Inorg. Chim. Acta, 1980, 40, 15. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References