Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Manganese, phenyl pentacarbonyl


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-587. ± 18.kJ/molReviewMartinho SimõesThe enthalpy of formation is the average of the results for five iodination reaction enthalpies
Deltafgas-588.9 ± 7.0kJ/molReviewMartinho SimõesSelected data

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid-672. ± 17.kJ/molReviewMartinho SimõesThe enthalpy of formation is the average of the results for five iodination reaction enthalpies
Deltafsolid-673.8 ± 5.5kJ/molReviewMartinho SimõesSelected data

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub84.9 ± 4.4kJ/molHAL-HFCConnor, Zafarani-Moattar, et al., 1982MS
Deltasub84.9 ± 4.4kJ/molCConnor, Zafarani-Moattar, et al., 1982, 2AC

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C11H5MnO5 (solution) + Carbon monoxide (solution) = C12H5MnO6 (solution)

By formula: C11H5MnO5 (solution) + CO (solution) = C12H5MnO6 (solution)

Quantity Value Units Method Reference Comment
Deltar-45.2kJ/molEqSCalderazzo, 1977solvent: 2,2'-diethoxydiethyl ether

C12H5MnO6 (cr) = C11H5MnO5 (g) + Carbon monoxide (g)

By formula: C12H5MnO6 (cr) = C11H5MnO5 (g) + CO (g)

Quantity Value Units Method Reference Comment
Deltar148. ± 3.kJ/molTD-HFCConnor, Zafarani-Moattar, et al., 1982 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Connor, Zafarani-Moattar, et al., 1982, 2
Connor, Joseph A.; Zafarani-Moattar, Mohamed T.; Bickerton, James; El Saied, Nabila I.; Suradi, Sukiman; Carson, Ronald; Al Takhin, Ghassan; Skinner, Henry A., Enthalpy of formation of acyl-, alkyl- and hydridopentacarbonyl-manganese complexes. The enthalpy contributions of manganese-hydrogen and manganese-carbon bonds in these molecules. Thermochemical aspects of models in Fischer-Tropsch reactions, Organometallics, 1982, 1, 9, 1166-1174, https://doi.org/10.1021/om00069a011 . [all data]

Calderazzo, 1977
Calderazzo, F., Angew. Chem. Int. Ed. Engl., 1977, 16, 299. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References