Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Diphenyl sulfide

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil569.2KN/AWeast and Grasselli, 1989BS
Tboil569.65KN/APerkin, 1896Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus399.4KN/AHauptmann and Wladislaw, 1950Uncertainty assigned by TRC = 8. K; TRC
Tfus409.KN/AHauptmann and Wladislaw, 1950Uncertainty assigned by TRC = 4. K; TRC
Tfus438.KN/AHauptmann and Wladislaw, 1950Uncertainty assigned by TRC = 10. K; TRC
Tfus247.25KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Deltavap68. ± 2.kJ/molCMackle and Mayrick, 1962ALS
Deltavap68.2kJ/molN/AMackle and Mayrick, 1962DRB

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
60.5384.N/ADykyj, Svoboda, et al., 1999Based on data from 369. - 566. K.; AC
67.3 ± 0.3360.EB,IPSteele, Chirico, et al., 1995Based on data from 345. - 611. K.; AC
64.3 ± 0.3400.EB,IPSteele, Chirico, et al., 1995Based on data from 345. - 611. K.; AC
61.3 ± 0.3440.EB,IPSteele, Chirico, et al., 1995Based on data from 345. - 611. K.; AC
58.3 ± 0.3480.EB,IPSteele, Chirico, et al., 1995Based on data from 345. - 611. K.; AC
55.3 ± 0.3520.EB,IPSteele, Chirico, et al., 1995Based on data from 345. - 611. K.; AC
52.0 ± 0.3560.EB,IPSteele, Chirico, et al., 1995Based on data from 345. - 611. K.; AC
58.2384.AStephenson and Malanowski, 1987Based on data from 369. - 566. K. See also Kretschmer and Wiebe, 1949.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
369.3 - 565.74.806112519.224-41.188Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
13.98258.ACSteele, Chirico, et al., 1995Based on data from 5. - 440. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Perkin, 1896
Perkin, W.H., LXIX. On Magnetic Rotatory Power, especially of Aromatic Compounds, J. Chem. Soc., 1896, 69, 1025-1257. [all data]

Hauptmann and Wladislaw, 1950
Hauptmann, H.; Wladislaw, B., The Action of Raney Nickel on SUlfur Compounds III. Aromatic Thioesters, J. Am. Chem. Soc., 1950, 72, 710. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Mackle and Mayrick, 1962
Mackle, H.; Mayrick, R.G., Studies in thermochemistry of organic sulphides. Part 3.-The gas-phase heats of formation of diphenyl sulphide, dibenzyl sulphide, diphenyl disulphide,4-thia-1-hexene and 4-thia-5,5-dimethyl-1-hexene, Trans. Faraday Soc., 1962, 58, 238-243. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Steele, Chirico, et al., 1995
Steele, W.V.; Chirico, R.D.; Cowell, A.B.; Nguyen, A.; Knipmeyer, S.E., Possible precursors and products of deep hydrodesulfurization of distillate fuels, The Journal of Chemical Thermodynamics, 1995, 27, 12, 1407-1428, https://doi.org/10.1006/jcht.1995.0149 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kretschmer and Wiebe, 1949
Kretschmer, Carl B.; Wiebe, Richard., Liquid-Vapor Equilibrium of Ethanol--Toluene Solutions, J. Am. Chem. Soc., 1949, 71, 5, 1793-1797, https://doi.org/10.1021/ja01173a076 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

Go To: Top, Phase change data, References